EBK CHEMISTRY FOR CHANGING TIMES
14th Edition
ISBN: 8220100663482
Author: MCCREARY
Publisher: PEARSON
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Textbook Question
Chapter 18, Problem 10RQ
Describe a synergistic effect involving drugs.
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Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 18 Solutions
EBK CHEMISTRY FOR CHANGING TIMES
Ch. 18 - Prob. 1RQCh. 18 - Prob. 2RQCh. 18 - Prob. 3RQCh. 18 - Prob. 4RQCh. 18 - Prob. 5RQCh. 18 - Prob. 6RQCh. 18 - What are prostaglandins? How do prostaglandins...Ch. 18 - Prob. 8RQCh. 18 - Prob. 9RQCh. 18 - Describe a synergistic effect involving drugs.
Ch. 18 - Prob. 11RQCh. 18 - Prob. 12RQCh. 18 - Prob. 13RQCh. 18 - Prob. 14RQCh. 18 - Prob. 15RQCh. 18 - Prob. 16RQCh. 18 - Prob. 17PCh. 18 - Classify the following drugs as natural,...Ch. 18 - Prob. 19PCh. 18 - Prob. 20PCh. 18 - Prob. 21PCh. 18 - Prob. 22PCh. 18 - Prob. 23PCh. 18 - Prob. 24PCh. 18 - Prob. 25PCh. 18 - Prob. 26PCh. 18 - Which of the following was originally marketed as...Ch. 18 - Prob. 28PCh. 18 - Which of the following is not considered to be an...Ch. 18 - How does heroin differ from morphine in its...Ch. 18 - Prob. 31PCh. 18 - How are endorphins related to (a) the anesthetic...Ch. 18 - Prob. 33PCh. 18 - Prob. 34PCh. 18 - Prob. 35PCh. 18 - Prob. 36PCh. 18 - Prob. 37PCh. 18 - Prob. 38PCh. 18 - Prob. 39PCh. 18 - Prob. 40PCh. 18 - Prob. 41PCh. 18 - Prob. 42PCh. 18 - Prob. 43PCh. 18 - Prob. 44PCh. 18 - Prob. 45PCh. 18 - Prob. 46PCh. 18 - Give three differences between hormones and...Ch. 18 - Prob. 48PCh. 18 - Prob. 49PCh. 18 - Prob. 50PCh. 18 - Prob. 51PCh. 18 - Prob. 52PCh. 18 - Prob. 53PCh. 18 - Prob. 54PCh. 18 - Prob. 55PCh. 18 - Prob. 56PCh. 18 - Prob. 57PCh. 18 - Which of the following is often treated with...Ch. 18 - Prob. 59PCh. 18 - Prob. 60PCh. 18 - Prob. 61PCh. 18 - Prob. 62PCh. 18 - Prob. 63PCh. 18 - Prob. 64PCh. 18 - Prob. 65PCh. 18 - Prob. 66PCh. 18 - Prob. 67PCh. 18 - What is an agonist? What is an antagonist?Ch. 18 - Prob. 69PCh. 18 - Prob. 70PCh. 18 - Prob. 71PCh. 18 - What is the difference between drug abuse and drug...Ch. 18 - Review the information on structure and function...Ch. 18 - Prob. 74APCh. 18 - Prob. 75APCh. 18 - Prob. 76APCh. 18 - Prob. 77APCh. 18 - Prob. 78APCh. 18 - Prob. 79APCh. 18 - Prob. 80APCh. 18 - Prob. 81APCh. 18 - Prob. 82APCh. 18 - Prob. 83APCh. 18 - Prob. 84APCh. 18 - Prob. 85APCh. 18 - Prob. 86APCh. 18 - Prob. 87APCh. 18 - Prob. 88APCh. 18 - Prob. 89APCh. 18 - Prob. 90APCh. 18 - Prob. 91APCh. 18 - Prob. 92APCh. 18 - Prob. 93APCh. 18 - Prob. 94APCh. 18 - Prob. 95APCh. 18 - Which of the following compounds are classified as...Ch. 18 - Prob. 97APCh. 18 - Prob. 98APCh. 18 - Prob. 99APCh. 18 - Prob. 100APCh. 18 - Prob. 101APCh. 18 - Prob. 102APCh. 18 - Prob. 103APCh. 18 - Prob. 104APCh. 18 - Prob. 18.1CTECh. 18 - Prob. 18.2CTECh. 18 - Prob. 18.3CTECh. 18 - Prob. 18.4CTECh. 18 - Prob. 18.5CTECh. 18 - Prob. 18.6CTECh. 18 - Prob. 18.7CTECh. 18 - Prob. 18.8CTECh. 18 - Prob. 1CGPCh. 18 - Prob. 2CGPCh. 18 - Prob. 3CGPCh. 18 - Prob. 4CGPCh. 18 - Prob. 5CGPCh. 18 - Prob. 6CGPCh. 18 - Prob. 7CGPCh. 18 - Prob. 8CGPCh. 18 - Prob. 9CGPCh. 18 - Prob. 10CGPCh. 18 - Prob. 11CGPCh. 18 - Prob. 12CGPCh. 18 - Prob. 13CGPCh. 18 - Prob. 14CGPCh. 18 - Prob. 1CHQCh. 18 - Prob. 2CHQCh. 18 - Prob. 3CHQ
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