EBK BASIC CHEMISTRY
6th Edition
ISBN: 9780134987088
Author: Timberlake
Publisher: PEARSON CO
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Chapter 18, Problem 103CP
The following problems are related to the topics in this chapter. However, they do not all follow the chapter order, and they require you to combine concepts and skills from several sections. These problems will help you increase your critical thinking skills and prepare for your next exam.
18.103 Sunflower seed oil can be used to make margarine. A triacylglycerol in sunflower seed oil contains two linoleic acids and one oleic acid. (18.3)
a. Draw the condensed structural formulas for two isomers of the triacylglycerol in sunflower oil.
b. Using one of the isomers, write the reaction that takes place when sunflower seed oil is used to make solid margarine.
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10.
Stereochemistry. Assign R/S stereochemistry for the chiral center indicated on the
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H₂N
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R/S configurations for all stereoisomers and indicate the relationship between each as
enantiomer, diastereomer, or meso.
NH2
H
HNH,
-18
b)
8.
Indicate whether the following carbocation rearrangements are likely to occur
Please explain your rational using 10 words or less
not likely to occur
• The double bond is still in the
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+
Likely
to oc
occur
WHY?
-3
H3C
Brave
Chair Conformers. Draw the chair conformer of the following substituted
cyclohexane. Peform a RING FLIP and indicate the most stable
conformation and briefly explain why using 20 words or less.
CI
2
-cobs ??
MUST INDICATE H -2
-2
Br
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OR
AT
Br
H&
most stable
WHY?
- 4
CH
12
Conformational Analysis. Draw all 6 conformers (one above each letter) of the
compound below looking down the indicated bond. Write the letter of the
conformer with the HIGHEST and LOWEST in energies on the lines provided.
NOTE: Conformer A MUST be the specific conformer of the structure as drawn below
-4 NOT
HOH
OH
3
Conformer A:
Br
OH
A
Samo
Br H
04
Br
H
H3
CH₂
H
anti
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Br CH
clipsed
H
Brott
H
IV
H
MISSING 2
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B
C
D
E
F
X
6
Conformer with HIGHEST ENERGY:
13. (1
structure
LOWEST ENERGY:
Nomenclature. a) Give the systematic (IUPAC) name structure. b) Draw the
corresponding to this name. HINT: Do not forget to indicate stereochemistry
when applicable.
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b) (3R,4S)-3-chloro-4-ethyl-2,7-dimethyloctane
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Chapter 18 Solutions
EBK BASIC CHEMISTRY
Ch. 18.1 - Prob. 1PPCh. 18.1 - Prob. 2PPCh. 18.1 - Prob. 3PPCh. 18.1 - Prob. 4PPCh. 18.1 - Prob. 5PPCh. 18.1 - Prob. 6PPCh. 18.1 - Prob. 7PPCh. 18.1 - Prob. 8PPCh. 18.1 - Prob. 9PPCh. 18.1 - Prob. 10PP
Ch. 18.1 - Prob. 11PPCh. 18.1 - Prob. 12PPCh. 18.2 - Prob. 13PPCh. 18.2 - Prob. 14PPCh. 18.2 - Prob. 15PPCh. 18.2 - Prob. 16PPCh. 18.2 - Prob. 17PPCh. 18.2 - Prob. 18PPCh. 18.2 - Prob. 19PPCh. 18.2 - Prob. 20PPCh. 18.3 - Classify each of the following fatty acids as...Ch. 18.3 - Classify each of the following fatty acids as...Ch. 18.3 - Prob. 23PPCh. 18.3 - Prob. 24PPCh. 18.3 - Prob. 25PPCh. 18.3 - Olive oil is monounsaturated, whereas butter fat...Ch. 18.3 - Prob. 27PPCh. 18.3 - Use condensed structural formulas to write the...Ch. 18.3 - Prob. 29PPCh. 18.3 - Use condensed structural formulas to write the...Ch. 18.3 - Prob. 31PPCh. 18.3 - Prob. 32PPCh. 18.4 - Draw the condensed structural formula for each of...Ch. 18.4 - Draw the condensed structural formula for each of...Ch. 18.4 - Prob. 35PPCh. 18.4 - Prob. 36PPCh. 18.4 - Give the name of the amino acid represented by...Ch. 18.4 - Prob. 38PPCh. 18.4 - Draw the condensed structural formula for each of...Ch. 18.4 - Prob. 40PPCh. 18.4 - Prob. 41PPCh. 18.4 - Prob. 42PPCh. 18.4 - Peptides isolated from rapeseed that may lower...Ch. 18.4 - Prob. 44PPCh. 18.5 - Prob. 45PPCh. 18.5 - Prob. 46PPCh. 18.5 - Prob. 47PPCh. 18.5 - Prob. 48PPCh. 18.5 - Prob. 49PPCh. 18.5 - What type of interaction would you expect between...Ch. 18.5 - Prob. 51PPCh. 18.5 - Prob. 52PPCh. 18.6 - Prob. 53PPCh. 18.6 - Match the terms, (1) active site, (2) lock-and-key...Ch. 18.6 - Prob. 55PPCh. 18.6 - Prob. 56PPCh. 18.7 - Prob. 57PPCh. 18.7 - Identify each of the following bases as a...Ch. 18.7 - Prob. 59PPCh. 18.7 - Prob. 60PPCh. 18.7 - Prob. 61PPCh. 18.7 - Prob. 62PPCh. 18.7 - Prob. 63PPCh. 18.7 - Prob. 64PPCh. 18.8 - Prob. 65PPCh. 18.8 - Prob. 66PPCh. 18.8 - Prob. 67PPCh. 18.8 - Prob. 68PPCh. 18.8 - Prob. 69PPCh. 18.8 - Prob. 70PPCh. 18.8 - Prob. 71PPCh. 18.8 - Prob. 72PPCh. 18.8 - Prob. 73PPCh. 18.8 - Prob. 74PPCh. 18 - Prob. 75UTCCh. 18 - Prob. 76UTCCh. 18 - Prob. 77UTCCh. 18 - Prob. 78UTCCh. 18 - Prob. 79UTCCh. 18 - Prob. 80UTCCh. 18 - Prob. 81UTCCh. 18 - Prob. 82UTCCh. 18 - Prob. 83UTCCh. 18 - Prob. 84UTCCh. 18 - Prob. 85UTCCh. 18 - Prob. 86UTCCh. 18 - Prob. 87APPCh. 18 - Prob. 88APPCh. 18 - Prob. 89APPCh. 18 - Prob. 90APPCh. 18 - Prob. 91APPCh. 18 - Prob. 92APPCh. 18 - Prob. 93APPCh. 18 - Prob. 94APPCh. 18 - Prob. 95APPCh. 18 - Prob. 96APPCh. 18 - Prob. 97APPCh. 18 - Prob. 98APPCh. 18 - Prob. 99APPCh. 18 - Prob. 100APPCh. 18 - Prob. 101CPCh. 18 - Prob. 102CPCh. 18 - The following problems are related to the topics...Ch. 18 - Prob. 104CPCh. 18 - The following problems are related to the topics...Ch. 18 - Prob. 106CPCh. 18 - Prob. 107CPCh. 18 - Prob. 108CPCh. 18 - Prob. 109CPCh. 18 - Prob. 110CPCh. 18 - The following problems are related to the topics...Ch. 18 - Prob. 112CPCh. 18 - A compound called butylated hydroxytoluene, or...Ch. 18 - Olive oil contains a high percentage of glyceryl...Ch. 18 - A sink drain can become clogged with solid fat...Ch. 18 - Prob. 44CICh. 18 - Prob. 45CICh. 18 - Prob. 46CI
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