The IUPAC name of the following compound should be determined: Concept Introduction : The ring structures of the compound having uncommon stability due to delocalized pi electron density shared in between all the carbon atoms of the ring is said to be an aromatic compound. In order to give the name to the multiple substituted aromatic compounds , the following steps are followed: For single substituted aromatic compound (when the substituent contains six or fewer carbons), the name of the substituted group is written first followed by the name of the aromatic compound. For single substituted aromatic compound (when the substituent contains more than six carbons), the name of the aromatic compound is written first followed by the name of the substituted group. For single substituted aromatic compound, the numbering on the ring is done in such a way that the multiple substituents get the lowest number.

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Answer 1

Question

Chapter 17.3, Problem 34PP

(a)

Interpretation Introduction

Interpretation: The IUPAC name of the following compound should be determined:

Concept Introduction: The ring structures of the compound having uncommon stability due to delocalized pi electron density shared in between all the carbon atoms of the ring is said to be an aromatic compound.

In order to give the name to the multiple substituted aromatic compounds, the following steps are followed:

For single substituted aromatic compound (when the substituent contains six or fewer carbons), the name of the substituted group is written first followed by the name of the aromatic compound.

For single substituted aromatic compound (when the substituent contains more than six carbons), the name of the aromatic compound is written first followed by the name of the substituted group.

For single substituted aromatic compound, the numbering on the ring is done in such a way that the multiple substituents get the lowest number.

(b)

Interpretation Introduction

Interpretation: The IUPAC name of the following compound should be determined:

Concept Introduction: The ring structures of the compound having uncommon stability due to delocalized pi electron density shared in between all the carbon atoms of the ring is said to be an aromatic compound.

In order to give the name to the multiple substituted aromatic compounds, the following steps are followed:

For single substituted aromatic compound (when the substituent contains six or fewer carbons), the name of the substituted group is written first followed by the name of the aromatic compound.

For single substituted aromatic compound (when the substituent contains more than six carbons), the name of the aromatic compound is written first followed by the name of the substituted group.

For single substituted aromatic compound, the numbering on the ring is done in such a way that the multiple substituents get the lowest number.

(c)

Interpretation Introduction

Interpretation: The IUPAC name of the following compound should be determined:

Concept Introduction: The ring structures of the compound having uncommon stability due to delocalized pi electron density shared in between all the carbon atoms of the ring is said to be an aromatic compound.

In order to give the name to the multiple substituted aromatic compounds, the following steps are followed:

For single substituted aromatic compound (when the substituent contains six or fewer carbons), the name of the substituted group is written first followed by the name of the aromatic compound.

For single substituted aromatic compound (when the substituent contains more than six carbons), the name of the aromatic compound is written first followed by the name of the substituted group.

For single substituted aromatic compound, the numbering on the ring is done in such a way that the multiple substituents get the lowest number.

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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 f1 (ppm) Predicted 13C NMR Spectrum 100 f1 (ppm) 30 220 210 200 190 180 170 160 150 140 130 120 110 90 80 70 -26 60 50 40 46 30 20 115 10 1.0 0.9 0.8 0 -10

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Answer 2

Question

Chapter 17.3, Problem 34PP

(a)

Interpretation Introduction

Interpretation: The IUPAC name of the following compound should be determined:

Concept Introduction: The ring structures of the compound having uncommon stability due to delocalized pi electron density shared in between all the carbon atoms of the ring is said to be an aromatic compound.

In order to give the name to the multiple substituted aromatic compounds, the following steps are followed:

For single substituted aromatic compound (when the substituent contains six or fewer carbons), the name of the substituted group is written first followed by the name of the aromatic compound.

For single substituted aromatic compound (when the substituent contains more than six carbons), the name of the aromatic compound is written first followed by the name of the substituted group.

For single substituted aromatic compound, the numbering on the ring is done in such a way that the multiple substituents get the lowest number.

(b)

Interpretation Introduction

Interpretation: The IUPAC name of the following compound should be determined:

Concept Introduction: The ring structures of the compound having uncommon stability due to delocalized pi electron density shared in between all the carbon atoms of the ring is said to be an aromatic compound.

In order to give the name to the multiple substituted aromatic compounds, the following steps are followed:

For single substituted aromatic compound (when the substituent contains six or fewer carbons), the name of the substituted group is written first followed by the name of the aromatic compound.

For single substituted aromatic compound (when the substituent contains more than six carbons), the name of the aromatic compound is written first followed by the name of the substituted group.

For single substituted aromatic compound, the numbering on the ring is done in such a way that the multiple substituents get the lowest number.

(c)

Interpretation Introduction

Interpretation: The IUPAC name of the following compound should be determined:

Concept Introduction: The ring structures of the compound having uncommon stability due to delocalized pi electron density shared in between all the carbon atoms of the ring is said to be an aromatic compound.

In order to give the name to the multiple substituted aromatic compounds, the following steps are followed:

For single substituted aromatic compound (when the substituent contains six or fewer carbons), the name of the substituted group is written first followed by the name of the aromatic compound.

For single substituted aromatic compound (when the substituent contains more than six carbons), the name of the aromatic compound is written first followed by the name of the substituted group.

For single substituted aromatic compound, the numbering on the ring is done in such a way that the multiple substituents get the lowest number.

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Answer 3

Question

Chapter 17.3, Problem 34PP

(a)

Interpretation Introduction

Interpretation: The IUPAC name of the following compound should be determined:

Concept Introduction: The ring structures of the compound having uncommon stability due to delocalized pi electron density shared in between all the carbon atoms of the ring is said to be an aromatic compound.

In order to give the name to the multiple substituted aromatic compounds, the following steps are followed:

For single substituted aromatic compound (when the substituent contains six or fewer carbons), the name of the substituted group is written first followed by the name of the aromatic compound.

For single substituted aromatic compound (when the substituent contains more than six carbons), the name of the aromatic compound is written first followed by the name of the substituted group.

For single substituted aromatic compound, the numbering on the ring is done in such a way that the multiple substituents get the lowest number.

(b)

Interpretation Introduction

Interpretation: The IUPAC name of the following compound should be determined:

Concept Introduction: The ring structures of the compound having uncommon stability due to delocalized pi electron density shared in between all the carbon atoms of the ring is said to be an aromatic compound.

In order to give the name to the multiple substituted aromatic compounds, the following steps are followed:

For single substituted aromatic compound (when the substituent contains six or fewer carbons), the name of the substituted group is written first followed by the name of the aromatic compound.

For single substituted aromatic compound (when the substituent contains more than six carbons), the name of the aromatic compound is written first followed by the name of the substituted group.

For single substituted aromatic compound, the numbering on the ring is done in such a way that the multiple substituents get the lowest number.

(c)

Interpretation Introduction

Interpretation: The IUPAC name of the following compound should be determined:

Concept Introduction: The ring structures of the compound having uncommon stability due to delocalized pi electron density shared in between all the carbon atoms of the ring is said to be an aromatic compound.

In order to give the name to the multiple substituted aromatic compounds, the following steps are followed:

For single substituted aromatic compound (when the substituent contains six or fewer carbons), the name of the substituted group is written first followed by the name of the aromatic compound.

For single substituted aromatic compound (when the substituent contains more than six carbons), the name of the aromatic compound is written first followed by the name of the substituted group.

For single substituted aromatic compound, the numbering on the ring is done in such a way that the multiple substituents get the lowest number.

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Answer 4

Question

Chapter 17.3, Problem 34PP

(a)

Interpretation Introduction

Interpretation: The IUPAC name of the following compound should be determined:

Concept Introduction: The ring structures of the compound having uncommon stability due to delocalized pi electron density shared in between all the carbon atoms of the ring is said to be an aromatic compound.

In order to give the name to the multiple substituted aromatic compounds, the following steps are followed:

For single substituted aromatic compound (when the substituent contains six or fewer carbons), the name of the substituted group is written first followed by the name of the aromatic compound.

For single substituted aromatic compound (when the substituent contains more than six carbons), the name of the aromatic compound is written first followed by the name of the substituted group.

For single substituted aromatic compound, the numbering on the ring is done in such a way that the multiple substituents get the lowest number.

(b)

Interpretation Introduction

Interpretation: The IUPAC name of the following compound should be determined:

Concept Introduction: The ring structures of the compound having uncommon stability due to delocalized pi electron density shared in between all the carbon atoms of the ring is said to be an aromatic compound.

In order to give the name to the multiple substituted aromatic compounds, the following steps are followed:

For single substituted aromatic compound (when the substituent contains six or fewer carbons), the name of the substituted group is written first followed by the name of the aromatic compound.

For single substituted aromatic compound (when the substituent contains more than six carbons), the name of the aromatic compound is written first followed by the name of the substituted group.

For single substituted aromatic compound, the numbering on the ring is done in such a way that the multiple substituents get the lowest number.

(c)

Interpretation Introduction

Interpretation: The IUPAC name of the following compound should be determined:

Concept Introduction: The ring structures of the compound having uncommon stability due to delocalized pi electron density shared in between all the carbon atoms of the ring is said to be an aromatic compound.

In order to give the name to the multiple substituted aromatic compounds, the following steps are followed:

For single substituted aromatic compound (when the substituent contains six or fewer carbons), the name of the substituted group is written first followed by the name of the aromatic compound.

For single substituted aromatic compound (when the substituent contains more than six carbons), the name of the aromatic compound is written first followed by the name of the substituted group.

For single substituted aromatic compound, the numbering on the ring is done in such a way that the multiple substituents get the lowest number.

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Answer 5

Chapter 17.3, Problem 34PP

(a)

Interpretation Introduction

Interpretation: The IUPAC name of the following compound should be determined:

Concept Introduction: The ring structures of the compound having uncommon stability due to delocalized pi electron density shared in between all the carbon atoms of the ring is said to be an aromatic compound.

In order to give the name to the multiple substituted aromatic compounds, the following steps are followed:

For single substituted aromatic compound (when the substituent contains six or fewer carbons), the name of the substituted group is written first followed by the name of the aromatic compound.

For single substituted aromatic compound (when the substituent contains more than six carbons), the name of the aromatic compound is written first followed by the name of the substituted group.

For single substituted aromatic compound, the numbering on the ring is done in such a way that the multiple substituents get the lowest number.

(b)

Interpretation Introduction

Interpretation: The IUPAC name of the following compound should be determined:

Concept Introduction: The ring structures of the compound having uncommon stability due to delocalized pi electron density shared in between all the carbon atoms of the ring is said to be an aromatic compound.

In order to give the name to the multiple substituted aromatic compounds, the following steps are followed:

For single substituted aromatic compound (when the substituent contains six or fewer carbons), the name of the substituted group is written first followed by the name of the aromatic compound.

For single substituted aromatic compound (when the substituent contains more than six carbons), the name of the aromatic compound is written first followed by the name of the substituted group.

For single substituted aromatic compound, the numbering on the ring is done in such a way that the multiple substituents get the lowest number.

(c)

Interpretation Introduction

Interpretation: The IUPAC name of the following compound should be determined:

Concept Introduction: The ring structures of the compound having uncommon stability due to delocalized pi electron density shared in between all the carbon atoms of the ring is said to be an aromatic compound.

In order to give the name to the multiple substituted aromatic compounds, the following steps are followed:

For single substituted aromatic compound (when the substituent contains six or fewer carbons), the name of the substituted group is written first followed by the name of the aromatic compound.

For single substituted aromatic compound (when the substituent contains more than six carbons), the name of the aromatic compound is written first followed by the name of the substituted group.

For single substituted aromatic compound, the numbering on the ring is done in such a way that the multiple substituents get the lowest number.

Answer 6

Chapter 17.3, Problem 34PP

(a)

Interpretation Introduction

Interpretation: The IUPAC name of the following compound should be determined:

Concept Introduction: The ring structures of the compound having uncommon stability due to delocalized pi electron density shared in between all the carbon atoms of the ring is said to be an aromatic compound.

In order to give the name to the multiple substituted aromatic compounds, the following steps are followed:

For single substituted aromatic compound (when the substituent contains six or fewer carbons), the name of the substituted group is written first followed by the name of the aromatic compound.

For single substituted aromatic compound (when the substituent contains more than six carbons), the name of the aromatic compound is written first followed by the name of the substituted group.

For single substituted aromatic compound, the numbering on the ring is done in such a way that the multiple substituents get the lowest number.

Answer 7

Chapter 17.3, Problem 34PP

(a)

Interpretation Introduction

Interpretation: The IUPAC name of the following compound should be determined:

Concept Introduction: The ring structures of the compound having uncommon stability due to delocalized pi electron density shared in between all the carbon atoms of the ring is said to be an aromatic compound.

In order to give the name to the multiple substituted aromatic compounds, the following steps are followed:

For single substituted aromatic compound (when the substituent contains six or fewer carbons), the name of the substituted group is written first followed by the name of the aromatic compound.

For single substituted aromatic compound (when the substituent contains more than six carbons), the name of the aromatic compound is written first followed by the name of the substituted group.

For single substituted aromatic compound, the numbering on the ring is done in such a way that the multiple substituents get the lowest number.

Answer 8

(b)

Interpretation Introduction

Interpretation: The IUPAC name of the following compound should be determined:

Concept Introduction: The ring structures of the compound having uncommon stability due to delocalized pi electron density shared in between all the carbon atoms of the ring is said to be an aromatic compound.

In order to give the name to the multiple substituted aromatic compounds, the following steps are followed:

For single substituted aromatic compound (when the substituent contains six or fewer carbons), the name of the substituted group is written first followed by the name of the aromatic compound.

For single substituted aromatic compound (when the substituent contains more than six carbons), the name of the aromatic compound is written first followed by the name of the substituted group.

For single substituted aromatic compound, the numbering on the ring is done in such a way that the multiple substituents get the lowest number.

Answer 9

(b)

Interpretation Introduction

Interpretation: The IUPAC name of the following compound should be determined:

Concept Introduction: The ring structures of the compound having uncommon stability due to delocalized pi electron density shared in between all the carbon atoms of the ring is said to be an aromatic compound.

In order to give the name to the multiple substituted aromatic compounds, the following steps are followed:

For single substituted aromatic compound (when the substituent contains six or fewer carbons), the name of the substituted group is written first followed by the name of the aromatic compound.

For single substituted aromatic compound (when the substituent contains more than six carbons), the name of the aromatic compound is written first followed by the name of the substituted group.

For single substituted aromatic compound, the numbering on the ring is done in such a way that the multiple substituents get the lowest number.

Answer 10

(c)

Interpretation Introduction

Interpretation: The IUPAC name of the following compound should be determined:

Concept Introduction: The ring structures of the compound having uncommon stability due to delocalized pi electron density shared in between all the carbon atoms of the ring is said to be an aromatic compound.

In order to give the name to the multiple substituted aromatic compounds, the following steps are followed:

For single substituted aromatic compound (when the substituent contains six or fewer carbons), the name of the substituted group is written first followed by the name of the aromatic compound.

For single substituted aromatic compound (when the substituent contains more than six carbons), the name of the aromatic compound is written first followed by the name of the substituted group.

For single substituted aromatic compound, the numbering on the ring is done in such a way that the multiple substituents get the lowest number.

Answer 11

(c)

Interpretation Introduction

Interpretation: The IUPAC name of the following compound should be determined:

Concept Introduction: The ring structures of the compound having uncommon stability due to delocalized pi electron density shared in between all the carbon atoms of the ring is said to be an aromatic compound.

In order to give the name to the multiple substituted aromatic compounds, the following steps are followed:

For single substituted aromatic compound (when the substituent contains six or fewer carbons), the name of the substituted group is written first followed by the name of the aromatic compound.

For single substituted aromatic compound (when the substituent contains more than six carbons), the name of the aromatic compound is written first followed by the name of the substituted group.

For single substituted aromatic compound, the numbering on the ring is done in such a way that the multiple substituents get the lowest number.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 17.1 - Prob. 1PP Ch. 17.1 - Prob. 2PP Ch. 17.1 - Prob. 3PP Ch. 17.1 - Prob. 4PP Ch. 17.1 - Prob. 5PP Ch. 17.1 - Prob. 6PP Ch. 17.1 - Prob. 7PP Ch. 17.1 - Prob. 8PP Ch. 17.1 - Prob. 9PP Ch. 17.1 - Prob. 10PP

Solution Summary: The author explains that the ring structures of the compound having uncommon stability due to delocalized pi electron density are an aromatic compound.

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Chapter 17 Solutions