EBK BASIC CHEMISTRY
6th Edition
ISBN: 9780134987088
Author: Timberlake
Publisher: PEARSON CO
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Chapter 17, Problem 107CP
The following problems are related to the topics in this chapter. However, they do not all follow the chapter order, and they require you to combine concepts and skills from several sections. These problems will help you increase your critical thinking skills and prepare for your next exam.
| 17.107 The insect repellent DEET can be made from an amidation reaction of 3 -methylbenzoic acid and diethylamine. Draw the line-angle formula for DEET. (17.7)Many insect repellents contain DEET, which is an amide. |  |
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4. Provide a clear arrow-pushing mechanism for the following reactions. Do not skip proton
transfers, do not combine steps, and make sure your arrows are clear enough to be interpreted
without ambiguity.
a)
NHBoc
⚫OBn
HO.
H3C
CO2CH3
-OBn
H3C
H3C.
H3C.
NHBOC
CI
CO2CH3
Draw structures of the following compounds and identify their role:
mCPBA
(MCPBA)
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Py
9-BBN
LAH
Sia₂BH
TsCI
PCC
t-BuOK
LDA
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n-BuLi
DMSO
DMF
Sodium Borohydride
Lithium DiisopropylAmide
2
Using Luther's rule, calculate the reference potential of the Hg2+/Hg redox electrode.
DATA: Electrode potentials E° = 0,854 V y E 0,788 V
Hg2+/Hg
2+
Hg2/Hg
Chapter 17 Solutions
EBK BASIC CHEMISTRY
Ch. 17.1 - Prob. 1PPCh. 17.1 - Prob. 2PPCh. 17.1 - Prob. 3PPCh. 17.1 - Prob. 4PPCh. 17.1 - Prob. 5PPCh. 17.1 - Prob. 6PPCh. 17.1 - Prob. 7PPCh. 17.1 - Prob. 8PPCh. 17.1 - Prob. 9PPCh. 17.1 - Prob. 10PP
Ch. 17.1 - Prob. 11PPCh. 17.1 - Draw the condensed structural formula for each of...Ch. 17.1 - Prob. 13PPCh. 17.1 - Prob. 14PPCh. 17.1 - Prob. 15PPCh. 17.1 - Prob. 16PPCh. 17.1 - Prob. 17PPCh. 17.1 - Prob. 18PPCh. 17.2 - Prob. 19PPCh. 17.2 - Identify each of the following as an alkane,...Ch. 17.2 - Prob. 21PPCh. 17.2 - Prob. 22PPCh. 17.2 - Prob. 23PPCh. 17.2 - Prob. 24PPCh. 17.2 - Draw the condensed structural formula for the...Ch. 17.2 - Prob. 26PPCh. 17.2 - Prob. 27PPCh. 17.2 - Prob. 28PPCh. 17.2 - Prob. 29PPCh. 17.2 - Prob. 30PPCh. 17.2 - Prob. 31PPCh. 17.2 - Prob. 32PPCh. 17.3 - Prob. 33PPCh. 17.3 - Prob. 34PPCh. 17.3 - Prob. 35PPCh. 17.3 - Draw the line-angle formula for each of the...Ch. 17.4 - Prob. 37PPCh. 17.4 - Prob. 38PPCh. 17.4 - Prob. 39PPCh. 17.4 - Write the common name for each of the following:...Ch. 17.4 - Draw the condensed structural and line-angle...Ch. 17.4 - Draw the condensed structural and line-angle...Ch. 17.5 - Write the common name for each of the following:Ch. 17.5 - Write the common name for each of the following:Ch. 17.5 - Prob. 45PPCh. 17.5 - Prob. 46PPCh. 17.5 - Prob. 47PPCh. 17.5 - Draw the condensed structural formula for a and b...Ch. 17.6 - Prob. 49PPCh. 17.6 - Write the IUPAC and common name (if any) for each...Ch. 17.6 - Prob. 51PPCh. 17.6 - Prob. 52PPCh. 17.6 - Prob. 53PPCh. 17.6 - Prob. 54PPCh. 17.6 - Prob. 55PPCh. 17.6 - Prob. 56PPCh. 17.6 - Prob. 57PPCh. 17.6 - Write the IUPAC and common names, if any, for each...Ch. 17.6 - Draw the condensed structural formulas for a and b...Ch. 17.6 - Draw the condensed structural formulas for a and b...Ch. 17.7 - Write the common name for each of the following:...Ch. 17.7 - Prob. 62PPCh. 17.7 - Prob. 63PPCh. 17.7 - Prob. 64PPCh. 17.7 - Prob. 65PPCh. 17.7 - Prob. 66PPCh. 17.7 - Prob. 67PPCh. 17.7 - Prob. 68PPCh. 17.7 - Prob. 69PPCh. 17.7 - Prob. 70PPCh. 17.7 - Prob. 71PPCh. 17.7 - Prob. 72PPCh. 17 - The chapter sections to review are shown in...Ch. 17 - The chapter sections to review are shown in...Ch. 17 - Prob. 75UTCCh. 17 - Prob. 76UTCCh. 17 - Prob. 77APPCh. 17 - Prob. 78APPCh. 17 - Prob. 79APPCh. 17 - Prob. 80APPCh. 17 - Prob. 81APPCh. 17 - Prob. 82APPCh. 17 - Prob. 83APPCh. 17 - Prob. 84APPCh. 17 - Classify each of the following according to its...Ch. 17 - Classify each of the following according to its...Ch. 17 - Name each of the following aromatic compounds:...Ch. 17 - Prob. 88APPCh. 17 - Prob. 89APPCh. 17 - Draw the structural formula for each of the...Ch. 17 - Prob. 91APPCh. 17 - Prob. 92APPCh. 17 - Draw the condensed structural formula for each of...Ch. 17 - Draw the condensed structural formula for each of...Ch. 17 - Write the IUPAC name for each of the following:...Ch. 17 - Write the IUPAC name for each of the following:...Ch. 17 - Draw the condensed structural formulas for a and b...Ch. 17 - Prob. 98APPCh. 17 - Prob. 99APPCh. 17 - Prob. 100APPCh. 17 - Prob. 101APPCh. 17 - Draw the condensed structural formula for each of...Ch. 17 - Prob. 103APPCh. 17 - Prob. 104APPCh. 17 - Prob. 105CPCh. 17 - Prob. 106CPCh. 17 - The following problems are related to the topics...Ch. 17 - Prob. 108CPCh. 17 - The following problems are related to the topics...Ch. 17 - Prob. 110CP
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- For the following compound: HO -H Draw a mechanism for the tautomerization process under BASIC conditions: Mechanism A: H-O: H-OH H-O HH H-OO Mechanism B: H-Q Mechanism C: Θ OH H-O: Mechanism D: H-O H- H-OO C H-OO H- H- H-OO HH OH -H - HON H :OH H-Harrow_forwardidentify the product (or multiple products) for each of the following reactions: CI 1) NaNH2 (excess) ठ Cl 2) H₂O Hz H₂SO₂, H₂O HgSO Lindlar's catalyst 1) n-BuLi 2) 1)9-BBN 2) H₂O, NaOH ? Br H A B C afó gó H OA B O c OD E OF D E F H H Na, NHarrow_forwardIdentify the product (or multiple products) for each of the following reactions: ? or CI CI 1) NaNHz (excess) 2) H₂O OA OB O C OD OE OF H₂SO₂, H₂O Hq50. 1) n-BuLi 2) Br 1) 9-BBN 2) H₂O₂, NaOH A B H H متته D E H H H H C H H F H H H₂ Lindlar's catalyst Na NHarrow_forward
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