General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Textbook Question
Chapter 17.14, Problem 17.24P
What is the overall cell reaction and cell potential for anodizing titanium if the anode half-reaction is
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10.
Stereochemistry. Assign R/S stereochemistry for the chiral center indicated on the
following compound. In order to recieve full credit, you MUST SHOW YOUR WORK!
H₂N
CI
OH
CI
カー
11. () Stereochemistry. Draw all possible stereoisomers of the following compound. Assign
R/S configurations for all stereoisomers and indicate the relationship between each as
enantiomer, diastereomer, or meso.
NH2
H
HNH,
-18
b)
8.
Indicate whether the following carbocation rearrangements are likely to occur
Please explain your rational using 10 words or less
not likely to occur
• The double bond is still in the
Same position
+
Likely
to oc
occur
WHY?
-3
H3C
Brave
Chair Conformers. Draw the chair conformer of the following substituted
cyclohexane. Peform a RING FLIP and indicate the most stable
conformation and briefly explain why using 20 words or less.
CI
2
-cobs ??
MUST INDICATE H -2
-2
Br
EQ
Cl
OR
AT
Br
H&
most stable
WHY?
- 4
CH
12
Conformational Analysis. Draw all 6 conformers (one above each letter) of the
compound below looking down the indicated bond. Write the letter of the
conformer with the HIGHEST and LOWEST in energies on the lines provided.
NOTE: Conformer A MUST be the specific conformer of the structure as drawn below
-4 NOT
HOH
OH
3
Conformer A:
Br
OH
A
Samo
Br H
04
Br
H
H3
CH₂
H
anti
stagere
Br CH
clipsed
H
Brott
H
IV
H
MISSING 2
-2
B
C
D
E
F
X
6
Conformer with HIGHEST ENERGY:
13. (1
structure
LOWEST ENERGY:
Nomenclature. a) Give the systematic (IUPAC) name structure. b) Draw the
corresponding to this name. HINT: Do not forget to indicate stereochemistry
when applicable.
a)
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Parent name (noname)
4 Bromo
Sub = 2-methylethyl-4 Bromo nonane
b) (3R,4S)-3-chloro-4-ethyl-2,7-dimethyloctane
# -2
-2
Chapter 17 Solutions
General Chemistry: Atoms First
Ch. 17.1 - Describe a galvanic cell that uses the reaction...Ch. 17.2 - Write a balanced equation for the overall cell...Ch. 17.2 - Write the shorthand notation for a galvanic cell...Ch. 17.2 - Prob. 17.4CPCh. 17.3 - The standard cell potential at 25 C is 1.21 V for...Ch. 17.4 - The standard potential for the following galvanic...Ch. 17.5 - Which is the stronger oxidizing agent, Cl2(g) or...Ch. 17.5 - Predict from Table 17.1 whether each of the...Ch. 17.5 - Consider the following table of standard reduction...Ch. 17.6 - Consider a galvanic cell that uses the reaction...
Ch. 17.6 - Consider the following galvanic cell: (a) What is...Ch. 17.7 - What is the pH of the solution in the anode...Ch. 17.8 - Use the data in Table 17.1 to calculate the...Ch. 17.8 - Prob. 17.14PCh. 17.9 - Write a balanced equation for the overall cell...Ch. 17.10 - In what ways are fuel cells and batteries similar,...Ch. 17.10 - Prob. 17.17PCh. 17.11 - Prob. 17.18PCh. 17.12 - Metallic potassium was first prepared by Humphrey...Ch. 17.12 - Predict the half-cell reactions that occur when...Ch. 17.13 - Sketch an electrolytic cell suitable for...Ch. 17.14 - How many kilograms of aluminum can be produced in...Ch. 17.14 - A layer of silver is electroplated on a coffee...Ch. 17.14 - What is the overall cell reaction and cell...Ch. 17.14 - Prob. 17.25PCh. 17 - Prob. 17.26CPCh. 17 - Prob. 17.27CPCh. 17 - Prob. 17.28CPCh. 17 - Sketch a cell with inert electrodes suitable for...Ch. 17 - Prob. 17.30CPCh. 17 - It has recently been reported that porous pellets...Ch. 17 - Consider a Daniell cell with 1.0 M ion...Ch. 17 - Consider the following galvanic cell with 0.10 M...Ch. 17 - Prob. 17.34CPCh. 17 - Consider the following table of standard reduction...Ch. 17 - Prob. 17.36SPCh. 17 - What is the function of a salt bridge in a...Ch. 17 - Prob. 17.38SPCh. 17 - Describe galvanic cells that use the following...Ch. 17 - Write the standard shorthand notation for each...Ch. 17 - Write the standard shorthand notation for each...Ch. 17 - Prob. 17.42SPCh. 17 - Write the standard shorthand notation for a...Ch. 17 - An H2/H+ half-cell (anode) and an Ag+/Ag half-cell...Ch. 17 - A galvanic cell is constructed from a Zn/Zn2+...Ch. 17 - Prob. 17.46SPCh. 17 - Prob. 17.47SPCh. 17 - Prob. 17.48SPCh. 17 - Prob. 17.49SPCh. 17 - Prob. 17.50SPCh. 17 - Prob. 17.51SPCh. 17 - Prob. 17.52SPCh. 17 - Prob. 17.53SPCh. 17 - Prob. 17.54SPCh. 17 - Prob. 17.55SPCh. 17 - Prob. 17.56SPCh. 17 - Prob. 17.57SPCh. 17 - Prob. 17.58SPCh. 17 - Prob. 17.59SPCh. 17 - Prob. 17.60SPCh. 17 - Prob. 17.61SPCh. 17 - Prob. 17.62SPCh. 17 - Prob. 17.63SPCh. 17 - Prob. 17.64SPCh. 17 - Calculate E and G (in kilojoules) for the cell...Ch. 17 - Prob. 17.66SPCh. 17 - Prob. 17.67SPCh. 17 - Use the data in Appendix D to predict whether the...Ch. 17 - Use the data in Appendix D to predict whether the...Ch. 17 - Prob. 17.70SPCh. 17 - What reaction can occur, if any, when the...Ch. 17 - Consider a galvanic cell that uses the reaction...Ch. 17 - Prob. 17.73SPCh. 17 - Prob. 17.74SPCh. 17 - Prob. 17.75SPCh. 17 - Prob. 17.76SPCh. 17 - What is the Fe2+: Sn2+ concentration ratio in the...Ch. 17 - The Nernst equation applies to both cell reactions...Ch. 17 - Prob. 17.79SPCh. 17 - Prob. 17.80SPCh. 17 - Prob. 17.81SPCh. 17 - Prob. 17.82SPCh. 17 - Prob. 17.83SPCh. 17 - Prob. 17.84SPCh. 17 - Prob. 17.85SPCh. 17 - Prob. 17.86SPCh. 17 - Prob. 17.87SPCh. 17 - Calculate the equilibrium constant at 25 C for the...Ch. 17 - Prob. 17.89SPCh. 17 - For a lead storage battery: (a) Sketch one cell...Ch. 17 - Prob. 17.91SPCh. 17 - Prob. 17.92SPCh. 17 - Prob. 17.93SPCh. 17 - Prob. 17.94SPCh. 17 - Prob. 17.95SPCh. 17 - Prob. 17.96SPCh. 17 - Prob. 17.97SPCh. 17 - Prob. 17.98SPCh. 17 - (a)Sketch a cell with inert electrodes suitable...Ch. 17 - List the anode and cathode half-reactions that...Ch. 17 - Prob. 17.101SPCh. 17 - Prob. 17.102SPCh. 17 - Predict the anode, cathode, and overall cell...Ch. 17 - Prob. 17.104SPCh. 17 - Prob. 17.105SPCh. 17 - How many hours are required to produce 1.00 103...Ch. 17 - Prob. 17.107SPCh. 17 - Prob. 17.108SPCh. 17 - Prob. 17.109SPCh. 17 - Prob. 17.110CHPCh. 17 - Prob. 17.111CHPCh. 17 - Prob. 17.112CHPCh. 17 - Prob. 17.113CHPCh. 17 - Prob. 17.114CHPCh. 17 - Prob. 17.115CHPCh. 17 - Prob. 17.116CHPCh. 17 - Prob. 17.117CHPCh. 17 - Prob. 17.118CHPCh. 17 - The sodium-sulfur battery has molybdenum...Ch. 17 - When suspected drunk drivers are tested with a...Ch. 17 - Consider the addition of the following...Ch. 17 - The following galvanic cell has a potential of...Ch. 17 - A galvanic cell has a silver electrode in contact...Ch. 17 - Prob. 17.124CHPCh. 17 - Prob. 17.125CHPCh. 17 - Prob. 17.126CHPCh. 17 - For the following half-reaction, E = 1.103 V:...Ch. 17 - Prob. 17.128CHPCh. 17 - Prob. 17.129CHPCh. 17 - Prob. 17.130MPCh. 17 - Prob. 17.131MPCh. 17 - Prob. 17.134MPCh. 17 - Prob. 17.135MPCh. 17 - Prob. 17.136MPCh. 17 - Prob. 17.137MPCh. 17 - Experimental solid-oxide fuel cells that use...Ch. 17 - The half-reactions that occur in ordinary alkaline...Ch. 17 - Gold metal is extracted from its ore by treating...Ch. 17 - Consider the redox titration of 100.0 mL of a...
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