General Chemistry: Principles and Modern Applications (11th Edition)
11th Edition
ISBN: 9780132931281
Author: Ralph H. Petrucci, F. Geoffrey Herring, Jeffry D. Madura, Carey Bissonnette
Publisher: PEARSON
expand_more
expand_more
format_list_bulleted
Textbook Question
Chapter 17, Problem 45E
Sketch the titration curves of the following mixtures. Indicate the initial pH and the pH corresponding to the equivalence port. Indicate the volume of titrant required to reach the equivalence point, and select a suitable indicator from Figure 17-7.
a. 250 mL of 0100 M KOH with 0200 M Hl
b. 10.0 mL of 1.00 M
Expert Solution & Answer
Learn your wayIncludes step-by-step video
schedule22:16
Chapter 17 Solutions
General Chemistry: Principles and Modern Applications (11th Edition)
Ch. 17 - For a solution that e 0.275M CH2CH2 COOH...Ch. 17 - For a solution that is 0164 U NH2 and 0.102MNH4Cl...Ch. 17 - Prob. 3ECh. 17 - In Example 16-4, we calculated the percent...Ch. 17 - Calculate [H2OOH-] in a solution that is (a)...Ch. 17 - Calculate [OH-] in a solution that is (a) 0.0062 U...Ch. 17 - What concentration of formate ion, [HCOO-], should...Ch. 17 - What concentration of ammonia. [NH2] , should be...Ch. 17 - Calculate the pH of a buffer that is a. 0.012 M...Ch. 17 - Lactic acid, CH2CH(OH)COOH , is found in sour...
Ch. 17 - Indicate which of the following aqueous solutions...Ch. 17 - The H2PO4-HPO4- combination plays a role in...Ch. 17 - What is the pH of a solution Obtained by adding...Ch. 17 - What the pH of solution prepared by dissolving...Ch. 17 - You wish to prepare a buffer solution w pH = 945...Ch. 17 - You prepare a buffer solution by dissolving 2.00 g...Ch. 17 - If 0.55 ml. of 12 M HCI is added to 0100 L of the...Ch. 17 - If 0.35 mL of 15 P.4 NH is added to 0750 L of the...Ch. 17 - You are asked to prepare e buffer solution why a...Ch. 17 - You are asked to reduce the pH of the 03001 of...Ch. 17 - Given 1.00 L of a solution that is 0.100 hl...Ch. 17 - Given 125mL of a solution that is 0.0500 M CH2NH2...Ch. 17 - A solution of volume 750 mL contars 15.5 mmol...Ch. 17 - A solution of volume 0.500 L contains 1.68 g NH...Ch. 17 - A handbook lets various procedures for preparing...Ch. 17 - An acetic acid-sodium acetate buffer can be...Ch. 17 - A handbook lists the following data: Which of...Ch. 17 - With reference to the indicators listed in...Ch. 17 - In use of acid—base indicators, a. Why is it...Ch. 17 - The indicator methyl red has a pKHIN=4.95 . It...Ch. 17 - Phenol red indicator changes from yellow to red in...Ch. 17 - Thymol blue indicator has two pH ranges. It...Ch. 17 - In the titration of 10.00 mL of 0.04050 M HCI with...Ch. 17 - Solution (a) is 1000 mL of 0.100 N HCI and...Ch. 17 - A 25.00 mL sample of H2PO4(aq) requires 31.15 mL...Ch. 17 - A 2000 ml sample of H2PO4(aq) requires 18.67 mL...Ch. 17 - Two aqueous solutions are mixed 50.0 mL of 0.0150M...Ch. 17 - Two solutions are mixed 100.0 mL of HCI(aq) with...Ch. 17 - Calculate the pH at the points in the titration of...Ch. 17 - Calculate the pH at the points m the titration...Ch. 17 - Calculate the pH at the points in the titration of...Ch. 17 - Calculate the pH at the points lithe titration of...Ch. 17 - Explain why the volume of 0.100 M NeOH required to...Ch. 17 - Explain whether the equivalence point of each of...Ch. 17 - Sketch the titration curves of the following...Ch. 17 - Determine the blowing characteristeristics of the...Ch. 17 - In the titration of 2000 mL of 0175 M NaOH,...Ch. 17 - In the titration of 25.00mL of 0.100M CH2COOH ,...Ch. 17 - Sketch a titration curve (pH versus mL of titrant)...Ch. 17 - Sketch a titration curve (pH versus mL of titrant)...Ch. 17 - For me titration of 25.00 mL of 0.100M NaOH with...Ch. 17 - For the titration of 25.00 mL 0.100M NH2 with...Ch. 17 - Is a solution that is 0.10 M Na2S(aq) likely to be...Ch. 17 - Is a solution of sodium dihydrogen citrate,...Ch. 17 - Sodium phosphate Na2PO4 , is made commecie1y by...Ch. 17 - Both sodium hydrogen carbonate (sodium...Ch. 17 - The pH of a solution of 19.5 g of malonic acid in...Ch. 17 - The ionization constants of ortho-phthalic acid...Ch. 17 - What stoichimetric concentration of the indicated...Ch. 17 - What stocichiometric concentration of the...Ch. 17 - Using appropriate equilibrium constants but...Ch. 17 - Prob. 62ECh. 17 - Sodium hydrogen sulfate NaHSO4 , an acidic salt...Ch. 17 - You are given 250.0mL of 0.100M CH3 CH2 COOH...Ch. 17 - Even though the carbonic acid-hydrogen carbonate...Ch. 17 - Thymol blue in its acid range is not a suitable...Ch. 17 - Rather than calculate the pH for different volumes...Ch. 17 - Use the method of Exercise 67 to determine the...Ch. 17 - A buffer solution can be prepared by starting with...Ch. 17 - You are asked to prepare a KH2PO4-Na2HPO2 solution...Ch. 17 - You are asked to bring the pH of 0.500 L of 0.500...Ch. 17 - Because an acid-base indicator a weak acid, I can...Ch. 17 - The neutralization of NaOH 2by HCl is represented...Ch. 17 - The titration of a weak acid by a weak base a not...Ch. 17 - At times a salt of a we base can be titrated by a...Ch. 17 - Sulfuric acid is a diprotic acid, strong in the...Ch. 17 - Carbonic acid is a weak diprotic acid (H2CO2) with...Ch. 17 - Prob. 78IAECh. 17 - Complete the derivation of equation (17.10)...Ch. 17 - Explain why equation (17.10) fads when applied to...Ch. 17 - Prob. 81IAECh. 17 - Prob. 82IAECh. 17 - Prob. 83IAECh. 17 - Prob. 84IAECh. 17 - Prob. 85IAECh. 17 - Calculate the pH of a solution that is 0.050 U...Ch. 17 - Prob. 87IAECh. 17 - The Henderson-Hasselbalch equation can be written...Ch. 17 - The pH of ocean water depends on the amount of...Ch. 17 - A sample of water contains 23.0 g L1 of Na+ (aq),...Ch. 17 - Prob. 91IAECh. 17 - Prob. 92FPCh. 17 - In some cases the titration curve for a mature of...Ch. 17 - Amino acids contain both an acidic carboxylic acid...Ch. 17 - In your own words, define or explain the following...Ch. 17 - Prob. 96SAECh. 17 - Explain the important distinctions between each...Ch. 17 - Write equations to show how each of the following...Ch. 17 - Sketch the titration curves that you would expect...Ch. 17 - A 2500-mL sample of 0.0100M C8C5COOH (Kg=6.3103)...Ch. 17 - Prob. 101SAECh. 17 - Prob. 102SAECh. 17 - Prob. 103SAECh. 17 - Prob. 104SAECh. 17 - Prob. 105SAECh. 17 - Calculate the pH of a 0.5 M solution of Ca(HSe)2...Ch. 17 - Prob. 107SAECh. 17 - Prob. 108SAECh. 17 - Prob. 109SAECh. 17 - Prob. 110SAECh. 17 - Prob. 111SAE
Additional Science Textbook Solutions
Find more solutions based on key concepts
16. Explain some of the reasons why the human species has been able to expand in number and distribution to a g...
Campbell Biology: Concepts & Connections (9th Edition)
5. When the phenotype of heterozygotes is intermediate between the phenotypes of the two homozygotes, this patt...
Biology: Life on Earth (11th Edition)
Endospore formation is called (a) _____. It is initiated by (b) _____. Formation of a new cell from an endospor...
Microbiology: An Introduction
Which of the following statements about the general functions of the nervous system is false?
The three primary...
Human Anatomy & Physiology (2nd Edition)
Acetobacter is necessary for only one of the steps of vitamin C manufacture. The easiest way to accomplish this...
Microbiology: An Introduction
Explain all answers clearly, with complete sentences and proper essay structure if needed. An asterisk (*) desi...
Cosmic Perspective Fundamentals
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Fifty cm3 of 1.000 M nitrous acid is titrated with 0.850 M NaOH. What is the pH of the solution (a) before any NaOH is added? (b) at half-neutralization? (c) at the equivalence point? (d) when 0.10 mL less than the volume of NaOH to reach the equivalence point is added? (e) when 0.10 mL more than the volume of NaOH to reach the equivalence point is added? (f) Use your data to construct a plot similar to that shown in Figure 14.10 (pH versus volume NaOH added).arrow_forwardThe titration curves for two acids with the same base are shown on this graph. (a) Which is the curve for the weaker acid? Explain your choice. (b) Give the approximate pH at the equivalence point for the titration of each acid. (c) Explain why the pH at the equivalence point differs for each acid. (d) Explain why the starting pH values of the two acids differ. (e) Which indicator or indicators, phenolphthalein, bromthymol blue, or methyl red, could be used for the titration of Acid 1? For the titration of Acid 2? Explain your choices.arrow_forwardRepeat the procedure in Exercise 61, but for the titration of 25.0 mL of 0.100 M pyridine with 0.100 M hydrochloric acid (Kb for pyridine is 1.7 109). Do not calculate the points at 24.9 and 25.1 mL.arrow_forward
- Calculate the pH change when 10.0 mL of 0.100-M NaOH is added to 90.0 mL pure water, and compare the pH change with that when the same amount of NaOH solution is added to 90.0 mL of a buffer consisting of 1.00-M NH3 and 1.00-M NH4Cl. Assume that the volumes are additive. Kb of NH3 = 1.8 × 10-5.arrow_forwardUsing Figure 17.11, suggest an indicator to use in each of the following titrations: (a) The weak base pyridine is titrated with HCl. (b) Formic acid is titrated with NaOH. (c) Ethylenediamine, a weak diprotic base, is titrated with HCl. Figure 17.11 Common acid-base indicators. The color changes occur over a range of pH values. Notice that o few indicators hove color changes over two different pH ranges.arrow_forwardChloropropionic acid, ClCH2CH2COOH, is a weak monoprotic acid with Ka = 7.94 105. Calculate the pH at the equivalence point in a titration of 10.00 mL of 0.100 M chloropropionic acid with 0.100 M KOH. Choose an indicator from Table 16.4 for the titration. Explain your choice. TABLE 16.5 Properties of Several Indicatorsarrow_forward
- When 40.00 mL of a weak monoprotic acid solution is titrated with 0.100-M NaOH, the equivalence point is reached when 35.00 mL base has been added. After 20.00 mL NaOH solution has been added, the titration mixture has a pH of 5.75. Calculate the ionization constant of the acid.arrow_forwardA 0.400-M solution of ammonia was titrated with hydrochloric acid to the equivalence point, where the total volume was 1.50 times the original volume. At what pH does the equivalence point occur?arrow_forwardTwo acids, each approximately 0.01 M in concentration, are titrated separately with a strong base. The adds show the following pH values at the equivalence point: HA, pH = 9.5, and HB, pH = 8.5. (a) Which is the stronger acid, HA or HB? (b) Which of the conjugate bases, A or B, is the stronger base?arrow_forward
- Consider the titration of 100.0 mL of 0.10 M H3AsO4 by 0.10 M NaOH. What are the major species present at 50.0 mL of NaOH added? How would you calculate the pH at this point? Answer the same questions for 150.0 mL of NaOH added. At what volume of NaOH added does pH = pKa1?arrow_forwardWhich of the indicators in Fig. 14-8 could be used for the titrations in Exercises 61 and 63?arrow_forwarda Draw a pH titration curve that represents the titration of 50.0 mL of 0.10 M NH3 by the addition of 0.10 M HCl from a buret. Label the axes and put a scale on each axis. Show where the equivalence point and the buffer region are on the titration curve. You should do calculations for the 0%, 30%, 50%, and 100% titration points. b Is the solution neutral, acidic, or basic at the equivalence point? Why?arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
- Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage LearningGeneral Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage Learning
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
General Chemistry - Standalone book (MindTap Cour...
Chemistry
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Cengage Learning
Acid-Base Equilibrium; Author: Bozeman Science;https://www.youtube.com/watch?v=l5fk7HPmo5g;License: Standard YouTube License, CC-BY
Introduction to Titrimetric analysis; Author: Vidya-mitra;https://www.youtube.com/watch?v=uykGVfn9q24;License: Standard Youtube License