Fundamentals of General, Organic, and Biological Chemistry, Books a la Carte Edition; Modified Mastering Chemistry with Pearson eText -- ValuePack ... and Biological Chemistry (4th Edition)
4th Edition
ISBN: 9780134465715
Author: John E. McMurry, David S. Ballantine
Publisher: PEARSON
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Chapter 17, Problem 17.81CP
Name the following compounds.
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2. (20 points) Consider combustion of hydrogen gas in a mixture
of hydrogen and oxygen adjacent to the metal wall of a
combustion chamber. Combustion occurs at constant
temperature and pressure according to the chemical reaction
2H₂+ O₂→ 2H₂O. Measurements under steady-state conditions
at 10 mm from the wall indicate that the molar concentrations
of hydrogen, oxygen, and water vapor are 0.10, 0.10, and 0.20
kmol/m³, respectively. The generation rate of water vapor is
0.96x102 kmol/m³s throughout the region of interest. The binary
diffusion coefficient for each of the species (H, O̟, and H₂O) in
the remaining species is 0.6 X 10-5 m²/s.
(a) Determine an expression for and make a qualitative plot
of C as a function of distance from the wall.
H2
(b) Determine the value of C2 at the wall.
H2
(c) On the same coordinates used in part (a), sketch curves
for the concentrations of oxygen and water vapor. This will
require you to calculate Co, and C.
02
H20
(d) What is the molar flux of water…
4. (15 points) Consider a spherical organism of radius ro within
which respiration occurs at a uniform volumetric rate of That is,
oxygen (species A) consumption is governed by a first- order
reaction, homogeneous chemical reaction.
a. If a molar concentration of CA(ro) = CA,o is maintained at
the surface of the organism, obtain an expression for the
radial distribution of oxygen, CA(r), within the organism.
Hint: To simplify solution of the species diffusion equation,
invoke the transformation y = rCA.
b. Obtain an expression for the rate of oxygen consumption
within the organism.
c. Consider an organism of radius ro = 0.10 mm and a
diffusion coefficient of DAB = 108 m2/s. If CA, o = 5 x105
kmol/m3 and k1 20 s1, estimate the corresponding value
of the molar concentration at the center of the organism.
What is the rate of oxygen consumption by the organism?
3. (15 points) Living cells homogeneously distributed
(immobilized) with an agarose gel require glucose to survive.
An important aspect of the biochemical system design is the
effective diffusion coefficient of glucose (A) into the cell-
immobilized gel. Consider the experiment shows below where
a slab of the cell-immobilized gel of 1.0cm thickness is placed
within a well-mixed aqueous solution of glucose maintained at
a concentration of 50 mmol/L. The glucose consumption
within the cell-immobilized gel proceeds by a zero-order
process given by R₁ = -0.05 mmol/(L min). The solubilities of
glucose in both the water and the gel are the same; that is, the
concentration of the glucose on the water side of the water-gel
interface is equal to the concentration of the glucose on the gel
side of the water gel interface. A syringe is mounted at the
center of the gel carefully excises a tiny sample of the gel for
glucose analysis.
A
Well mixed solution
Constant
concentration
50nmol/L
Living…
Chapter 17 Solutions
Fundamentals of General, Organic, and Biological Chemistry, Books a la Carte Edition; Modified Mastering Chemistry with Pearson eText -- ValuePack ... and Biological Chemistry (4th Edition)
Ch. 17.1 - Identify the following molecules as a carboxylic...Ch. 17.1 - Prob. 17.2PCh. 17.1 - Prob. 17.3PCh. 17.1 - Prob. 17.4PCh. 17.1 - Prob. 17.5PCh. 17.1 - Prob. 17.6PCh. 17.1 - In the following pairs of compounds, which would...Ch. 17.1 - Write both condensed and line structures for (a)...Ch. 17.1 - Prob. 17.9PCh. 17.1 - Draw structures corresponding to these names: (a)...
Ch. 17.1 - Prob. 17.11PCh. 17.1 - Prob. 17.12PCh. 17.1 - Prob. 17.13KCPCh. 17.2 - Salsalate, which is an ester formed by the...Ch. 17.2 - Prob. 17.2CIAPCh. 17.2 - Prob. 17.3CIAPCh. 17.2 - Prob. 17.14PCh. 17.2 - Prob. 17.15PCh. 17.2 - Prob. 17.16PCh. 17.3 - Prob. 17.17PCh. 17.3 - Raspberry oil contains an ester that is made by...Ch. 17.3 - Prob. 17.19PCh. 17.3 - Prob. 17.20PCh. 17.3 - Prob. 17.21PCh. 17.4 - If a bottle of aspirin tablets has the aroma of...Ch. 17.4 - Prob. 17.23PCh. 17.4 - What carboxylic acids and amines result from...Ch. 17.5 - Prob. 17.25PCh. 17.5 - Prob. 17.26KCPCh. 17.6 - Prob. 17.27PCh. 17.6 - Prob. 17.28PCh. 17.6 - Prob. 17.4CIAPCh. 17.6 - Prob. 17.5CIAPCh. 17.6 - Prob. 17.29PCh. 17 - Prob. 17.30UKCCh. 17 - Prob. 17.31UKCCh. 17 - One phosphorylated form of glycerate is...Ch. 17 - Prob. 17.33UKCCh. 17 - Prob. 17.34UKCCh. 17 - Prob. 17.35UKCCh. 17 - Prob. 17.36UKCCh. 17 - For the following compounds, give the systematic...Ch. 17 - Write the equation for the ionization of hexanoic...Ch. 17 - Prob. 17.39APCh. 17 - Prob. 17.40APCh. 17 - Prob. 17.41APCh. 17 - Give systematic names for the following carboxylic...Ch. 17 - Give systematic names for the following carboxylic...Ch. 17 - Prob. 17.44APCh. 17 - Prob. 17.45APCh. 17 - Draw structures corresponding to the following...Ch. 17 - Draw structures corresponding to the following...Ch. 17 - Malic acid, a dicarboxylic acid found in apples,...Ch. 17 - Prob. 17.49APCh. 17 - Prob. 17.50APCh. 17 - Prob. 17.51APCh. 17 - Prob. 17.52APCh. 17 - Prob. 17.53APCh. 17 - Give systematic names for the following structures...Ch. 17 - Give systematic names for the following structures...Ch. 17 - Prob. 17.56APCh. 17 - Prob. 17.57APCh. 17 - Give systematic names for the following structures...Ch. 17 - Give systematic names for the following structures...Ch. 17 - Prob. 17.60APCh. 17 - What compounds are produced from hydrolysis of...Ch. 17 - Procaine, a local anesthetic whose hydrochloride...Ch. 17 - Prob. 17.63APCh. 17 - Lactones are cyclic esters in which the carboxylic...Ch. 17 - When both the carboxylic acid and the amine are in...Ch. 17 - LSD (lysergic acid diethylamide), a semisynthetic...Ch. 17 - Prob. 17.67APCh. 17 - Prob. 17.68APCh. 17 - Prob. 17.69APCh. 17 - Prob. 17.70APCh. 17 - Prob. 17.71APCh. 17 - Prob. 17.72APCh. 17 - Prob. 17.73APCh. 17 - Prob. 17.74APCh. 17 - Prob. 17.75APCh. 17 - Three amide isomers, N,N-dimethylformamide,...Ch. 17 - Prob. 17.77CPCh. 17 - Prob. 17.78CPCh. 17 - Mention at least two simple chemical tests by...Ch. 17 - Prob. 17.80CPCh. 17 - Name the following compounds.Ch. 17 - Each of the following materials has an ester that...Ch. 17 - Prob. 17.83GPCh. 17 - Prob. 17.84GP
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Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, biochemistry and related others by exploring similar questions and additional content below.Similar questions
- Two tetrapeptides were isolated from a possum's sweat glands. These peptides were sequenced using Edman degradation and the following 2 sequences were obtained: Gly-Asp-Ala-Leu Gly-Asp-Asp-Leu Can you please help show the titration curve for both of these peptides and calculate the PI?arrow_forwardTwo tetrapeptides were isolated from a possum's sweat glands. These peptides were sequenced using Edman degradation and the following 2 sequences were obtained: Gly-Asp-Ala-Leu Gly-Asp-Asp-Leu What is the structure of the PTH derivative produced during the last round of amino acid sequencing?arrow_forwardWhat is the primary sequence of this undecapeptide? Also, if x-ray crystallography shows a highly stable hairpin turn within the polypeptide, what about the primary sequence explains this structural feature?arrow_forward
- Draw the product of this reaction. Ignore inorganic byproducts. H H ⚫OH HO- -H H- -OH H- -OH CH2OH Ag*, NH4OH, H2O Draw Fischer Projectionarrow_forwardDraw the product of this reaction. Ignore inorganic byproducts. H₂O -OH H ⚫OH HO H HO- CH2OH Cu2+ Draw Fischer Projectionarrow_forwardDraw the product of this reaction. Ignore inorganic byproducts. H、 H -OH H ⚫OH H -OH CH2OH Fehlings' solution ⑤ Draw Fischer Projectionarrow_forward
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