The chemical conditions to remove the acetyl group from N-Acetylglucosamide have to be determined. Concept introduction: Carboxylic acid : One − O H group is attached to the carbonyl carbon atom of the compound. It is represented as R C O O H Amide: One − N H 2 , − N H R ' or − N R ' 2 group is attached to the carbonyl carbon atom of the compound. It is represented as R C O N R ' 2 . Amide Formation: Amide is formed when a carboxylic acid reacts with an amine or ammonia. Primary amide is produce when a carboxylic acid reacts with ammonia. Secondary and tertiary amide is produce when a carboxylic acid reacts with primary and secondary amine respectively. Ammonium salt is formed when tertiary amine and a carboxylic acid reacts forming an ionic compound with a carboxylate acid anion and a trialkyl ammonium cation since there is no hydrogen atom in trialkyl amine Amide Hydrolysis: In presence of base or acid with continuous heating, amide reacts with water to form the corresponding amine and carboxylic acid. Carboxylic acid and amine salt are obtained when amide hydrolysis takes place in presence of acid. Carboxylate anion and amine are obtained when amide hydrolysis takes place in presence of base.

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Answer 1

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 17, Problem 17.31UKC

(a)

Interpretation Introduction

Interpretation:

The chemical conditions to remove the acetyl group from N-Acetylglucosamide have to be determined.

Concept introduction:

Carboxylic acid: One −OH group is attached to the carbonyl carbon atom of the compound. It is represented as RCOOH

Amide: One −NH2, −NHR' or −NR'2 group is attached to the carbonyl carbon atom of the compound. It is represented as RCONR'2.

Amide Formation: Amide is formed when a carboxylic acid reacts with an amine or ammonia.

Primary amide is produce when a carboxylic acid reacts with ammonia.

Secondary and tertiary amide is produce when a carboxylic acid reacts with primary and secondary amine respectively.

Ammonium salt is formed when tertiary amine and a carboxylic acid reacts forming an ionic compound with a carboxylate acid anion and a trialkyl ammonium cation since there is no hydrogen atom in trialkyl amine

Amide Hydrolysis: In presence of base or acid with continuous heating, amide reacts with water to form the corresponding amine and carboxylic acid.

Carboxylic acid and amine salt are obtained when amide hydrolysis takes place in presence of acid.

Carboxylate anion and amine are obtained when amide hydrolysis takes place in presence of base.

(b)

Interpretation Introduction

Interpretation:

The structure of products formed during the acid hydrolysis of N-Acetylglucosamide has to be drawn.

Concept introduction:

Carboxylic acid: One −OH group is attached to the carbonyl carbon atom of the compound. It is represented as RCOOH

Amide: One −NH2, −NHR' or −NR'2 group is attached to the carbonyl carbon atom of the compound. It is represented as RCONR'2.

Amide Formation: Amide is formed when a carboxylic acid reacts with an amine or ammonia.

Primary amide is produce when a carboxylic acid reacts with ammonia.

Secondary and tertiary amide is produce when a carboxylic acid reacts with primary and secondary amine respectively.

Ammonium salt is formed when tertiary amine and a carboxylic acid reacts forming an ionic compound with a carboxylate acid anion and a trialkyl ammonium cation since there is no hydrogen atom in trialkyl amine

Amide Hydrolysis: In presence of base or acid with continuous heating, amide reacts with water to form the corresponding amine and carboxylic acid.

Carboxylic acid and amine salt are obtained when amide hydrolysis takes place in presence of acid.

Carboxylate anion and amine are obtained when amide hydrolysis takes place in presence of base.

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Answer 2

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Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 17, Problem 17.31UKC

(a)

Interpretation Introduction

Interpretation:

The chemical conditions to remove the acetyl group from N-Acetylglucosamide have to be determined.

Concept introduction:

Carboxylic acid: One −OH group is attached to the carbonyl carbon atom of the compound. It is represented as RCOOH

Amide: One −NH2, −NHR' or −NR'2 group is attached to the carbonyl carbon atom of the compound. It is represented as RCONR'2.

Amide Formation: Amide is formed when a carboxylic acid reacts with an amine or ammonia.

Primary amide is produce when a carboxylic acid reacts with ammonia.

Secondary and tertiary amide is produce when a carboxylic acid reacts with primary and secondary amine respectively.

Ammonium salt is formed when tertiary amine and a carboxylic acid reacts forming an ionic compound with a carboxylate acid anion and a trialkyl ammonium cation since there is no hydrogen atom in trialkyl amine

Amide Hydrolysis: In presence of base or acid with continuous heating, amide reacts with water to form the corresponding amine and carboxylic acid.

Carboxylic acid and amine salt are obtained when amide hydrolysis takes place in presence of acid.

Carboxylate anion and amine are obtained when amide hydrolysis takes place in presence of base.

(b)

Interpretation Introduction

Interpretation:

The structure of products formed during the acid hydrolysis of N-Acetylglucosamide has to be drawn.

Concept introduction:

Carboxylic acid: One −OH group is attached to the carbonyl carbon atom of the compound. It is represented as RCOOH

Amide: One −NH2, −NHR' or −NR'2 group is attached to the carbonyl carbon atom of the compound. It is represented as RCONR'2.

Amide Formation: Amide is formed when a carboxylic acid reacts with an amine or ammonia.

Primary amide is produce when a carboxylic acid reacts with ammonia.

Secondary and tertiary amide is produce when a carboxylic acid reacts with primary and secondary amine respectively.

Ammonium salt is formed when tertiary amine and a carboxylic acid reacts forming an ionic compound with a carboxylate acid anion and a trialkyl ammonium cation since there is no hydrogen atom in trialkyl amine

Amide Hydrolysis: In presence of base or acid with continuous heating, amide reacts with water to form the corresponding amine and carboxylic acid.

Carboxylic acid and amine salt are obtained when amide hydrolysis takes place in presence of acid.

Carboxylate anion and amine are obtained when amide hydrolysis takes place in presence of base.

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Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 17, Problem 17.31UKC

(a)

Interpretation Introduction

Interpretation:

The chemical conditions to remove the acetyl group from N-Acetylglucosamide have to be determined.

Concept introduction:

Carboxylic acid: One −OH group is attached to the carbonyl carbon atom of the compound. It is represented as RCOOH

Amide: One −NH2, −NHR' or −NR'2 group is attached to the carbonyl carbon atom of the compound. It is represented as RCONR'2.

Amide Formation: Amide is formed when a carboxylic acid reacts with an amine or ammonia.

Primary amide is produce when a carboxylic acid reacts with ammonia.

Secondary and tertiary amide is produce when a carboxylic acid reacts with primary and secondary amine respectively.

Ammonium salt is formed when tertiary amine and a carboxylic acid reacts forming an ionic compound with a carboxylate acid anion and a trialkyl ammonium cation since there is no hydrogen atom in trialkyl amine

Amide Hydrolysis: In presence of base or acid with continuous heating, amide reacts with water to form the corresponding amine and carboxylic acid.

Carboxylic acid and amine salt are obtained when amide hydrolysis takes place in presence of acid.

Carboxylate anion and amine are obtained when amide hydrolysis takes place in presence of base.

(b)

Interpretation Introduction

Interpretation:

The structure of products formed during the acid hydrolysis of N-Acetylglucosamide has to be drawn.

Concept introduction:

Carboxylic acid: One −OH group is attached to the carbonyl carbon atom of the compound. It is represented as RCOOH

Amide: One −NH2, −NHR' or −NR'2 group is attached to the carbonyl carbon atom of the compound. It is represented as RCONR'2.

Amide Formation: Amide is formed when a carboxylic acid reacts with an amine or ammonia.

Primary amide is produce when a carboxylic acid reacts with ammonia.

Secondary and tertiary amide is produce when a carboxylic acid reacts with primary and secondary amine respectively.

Ammonium salt is formed when tertiary amine and a carboxylic acid reacts forming an ionic compound with a carboxylate acid anion and a trialkyl ammonium cation since there is no hydrogen atom in trialkyl amine

Amide Hydrolysis: In presence of base or acid with continuous heating, amide reacts with water to form the corresponding amine and carboxylic acid.

Carboxylic acid and amine salt are obtained when amide hydrolysis takes place in presence of acid.

Carboxylate anion and amine are obtained when amide hydrolysis takes place in presence of base.

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Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 17, Problem 17.31UKC

(a)

Interpretation Introduction

Interpretation:

The chemical conditions to remove the acetyl group from N-Acetylglucosamide have to be determined.

Concept introduction:

Carboxylic acid: One −OH group is attached to the carbonyl carbon atom of the compound. It is represented as RCOOH

Amide: One −NH2, −NHR' or −NR'2 group is attached to the carbonyl carbon atom of the compound. It is represented as RCONR'2.

Amide Formation: Amide is formed when a carboxylic acid reacts with an amine or ammonia.

Primary amide is produce when a carboxylic acid reacts with ammonia.

Secondary and tertiary amide is produce when a carboxylic acid reacts with primary and secondary amine respectively.

Ammonium salt is formed when tertiary amine and a carboxylic acid reacts forming an ionic compound with a carboxylate acid anion and a trialkyl ammonium cation since there is no hydrogen atom in trialkyl amine

Amide Hydrolysis: In presence of base or acid with continuous heating, amide reacts with water to form the corresponding amine and carboxylic acid.

Carboxylic acid and amine salt are obtained when amide hydrolysis takes place in presence of acid.

Carboxylate anion and amine are obtained when amide hydrolysis takes place in presence of base.

(b)

Interpretation Introduction

Interpretation:

The structure of products formed during the acid hydrolysis of N-Acetylglucosamide has to be drawn.

Concept introduction:

Carboxylic acid: One −OH group is attached to the carbonyl carbon atom of the compound. It is represented as RCOOH

Amide: One −NH2, −NHR' or −NR'2 group is attached to the carbonyl carbon atom of the compound. It is represented as RCONR'2.

Amide Formation: Amide is formed when a carboxylic acid reacts with an amine or ammonia.

Primary amide is produce when a carboxylic acid reacts with ammonia.

Secondary and tertiary amide is produce when a carboxylic acid reacts with primary and secondary amine respectively.

Ammonium salt is formed when tertiary amine and a carboxylic acid reacts forming an ionic compound with a carboxylate acid anion and a trialkyl ammonium cation since there is no hydrogen atom in trialkyl amine

Amide Hydrolysis: In presence of base or acid with continuous heating, amide reacts with water to form the corresponding amine and carboxylic acid.

Carboxylic acid and amine salt are obtained when amide hydrolysis takes place in presence of acid.

Carboxylate anion and amine are obtained when amide hydrolysis takes place in presence of base.

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Answer 5

Chapter 17, Problem 17.31UKC

(a)

Interpretation Introduction

Interpretation:

The chemical conditions to remove the acetyl group from N-Acetylglucosamide have to be determined.

Concept introduction:

Carboxylic acid: One −OH group is attached to the carbonyl carbon atom of the compound. It is represented as RCOOH

Amide: One −NH2, −NHR' or −NR'2 group is attached to the carbonyl carbon atom of the compound. It is represented as RCONR'2.

Amide Formation: Amide is formed when a carboxylic acid reacts with an amine or ammonia.

Primary amide is produce when a carboxylic acid reacts with ammonia.

Secondary and tertiary amide is produce when a carboxylic acid reacts with primary and secondary amine respectively.

Ammonium salt is formed when tertiary amine and a carboxylic acid reacts forming an ionic compound with a carboxylate acid anion and a trialkyl ammonium cation since there is no hydrogen atom in trialkyl amine

Amide Hydrolysis: In presence of base or acid with continuous heating, amide reacts with water to form the corresponding amine and carboxylic acid.

Carboxylic acid and amine salt are obtained when amide hydrolysis takes place in presence of acid.

Carboxylate anion and amine are obtained when amide hydrolysis takes place in presence of base.

(b)

Interpretation Introduction

Interpretation:

The structure of products formed during the acid hydrolysis of N-Acetylglucosamide has to be drawn.

Concept introduction:

Carboxylic acid: One −OH group is attached to the carbonyl carbon atom of the compound. It is represented as RCOOH

Amide: One −NH2, −NHR' or −NR'2 group is attached to the carbonyl carbon atom of the compound. It is represented as RCONR'2.

Amide Formation: Amide is formed when a carboxylic acid reacts with an amine or ammonia.

Primary amide is produce when a carboxylic acid reacts with ammonia.

Secondary and tertiary amide is produce when a carboxylic acid reacts with primary and secondary amine respectively.

Ammonium salt is formed when tertiary amine and a carboxylic acid reacts forming an ionic compound with a carboxylate acid anion and a trialkyl ammonium cation since there is no hydrogen atom in trialkyl amine

Amide Hydrolysis: In presence of base or acid with continuous heating, amide reacts with water to form the corresponding amine and carboxylic acid.

Carboxylic acid and amine salt are obtained when amide hydrolysis takes place in presence of acid.

Carboxylate anion and amine are obtained when amide hydrolysis takes place in presence of base.

Answer 6

Chapter 17, Problem 17.31UKC

(a)

Interpretation Introduction

Interpretation:

The chemical conditions to remove the acetyl group from N-Acetylglucosamide have to be determined.

Concept introduction:

Carboxylic acid: One −OH group is attached to the carbonyl carbon atom of the compound. It is represented as RCOOH

Amide: One −NH2, −NHR' or −NR'2 group is attached to the carbonyl carbon atom of the compound. It is represented as RCONR'2.

Amide Formation: Amide is formed when a carboxylic acid reacts with an amine or ammonia.

Primary amide is produce when a carboxylic acid reacts with ammonia.

Secondary and tertiary amide is produce when a carboxylic acid reacts with primary and secondary amine respectively.

Ammonium salt is formed when tertiary amine and a carboxylic acid reacts forming an ionic compound with a carboxylate acid anion and a trialkyl ammonium cation since there is no hydrogen atom in trialkyl amine

Amide Hydrolysis: In presence of base or acid with continuous heating, amide reacts with water to form the corresponding amine and carboxylic acid.

Carboxylic acid and amine salt are obtained when amide hydrolysis takes place in presence of acid.

Carboxylate anion and amine are obtained when amide hydrolysis takes place in presence of base.

Answer 7

Chapter 17, Problem 17.31UKC

(a)

Interpretation Introduction

Interpretation:

The chemical conditions to remove the acetyl group from N-Acetylglucosamide have to be determined.

Concept introduction:

Carboxylic acid: One −OH group is attached to the carbonyl carbon atom of the compound. It is represented as RCOOH

Amide: One −NH2, −NHR' or −NR'2 group is attached to the carbonyl carbon atom of the compound. It is represented as RCONR'2.

Amide Formation: Amide is formed when a carboxylic acid reacts with an amine or ammonia.

Primary amide is produce when a carboxylic acid reacts with ammonia.

Secondary and tertiary amide is produce when a carboxylic acid reacts with primary and secondary amine respectively.

Ammonium salt is formed when tertiary amine and a carboxylic acid reacts forming an ionic compound with a carboxylate acid anion and a trialkyl ammonium cation since there is no hydrogen atom in trialkyl amine

Amide Hydrolysis: In presence of base or acid with continuous heating, amide reacts with water to form the corresponding amine and carboxylic acid.

Carboxylic acid and amine salt are obtained when amide hydrolysis takes place in presence of acid.

Carboxylate anion and amine are obtained when amide hydrolysis takes place in presence of base.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The structure of products formed during the acid hydrolysis of N-Acetylglucosamide has to be drawn.

Concept introduction:

Carboxylic acid: One −OH group is attached to the carbonyl carbon atom of the compound. It is represented as RCOOH

Amide: One −NH2, −NHR' or −NR'2 group is attached to the carbonyl carbon atom of the compound. It is represented as RCONR'2.

Amide Formation: Amide is formed when a carboxylic acid reacts with an amine or ammonia.

Primary amide is produce when a carboxylic acid reacts with ammonia.

Secondary and tertiary amide is produce when a carboxylic acid reacts with primary and secondary amine respectively.

Ammonium salt is formed when tertiary amine and a carboxylic acid reacts forming an ionic compound with a carboxylate acid anion and a trialkyl ammonium cation since there is no hydrogen atom in trialkyl amine

Amide Hydrolysis: In presence of base or acid with continuous heating, amide reacts with water to form the corresponding amine and carboxylic acid.

Carboxylic acid and amine salt are obtained when amide hydrolysis takes place in presence of acid.

Carboxylate anion and amine are obtained when amide hydrolysis takes place in presence of base.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The structure of products formed during the acid hydrolysis of N-Acetylglucosamide has to be drawn.

Concept introduction:

Carboxylic acid: One −OH group is attached to the carbonyl carbon atom of the compound. It is represented as RCOOH

Amide: One −NH2, −NHR' or −NR'2 group is attached to the carbonyl carbon atom of the compound. It is represented as RCONR'2.

Amide Formation: Amide is formed when a carboxylic acid reacts with an amine or ammonia.

Primary amide is produce when a carboxylic acid reacts with ammonia.

Secondary and tertiary amide is produce when a carboxylic acid reacts with primary and secondary amine respectively.

Ammonium salt is formed when tertiary amine and a carboxylic acid reacts forming an ionic compound with a carboxylate acid anion and a trialkyl ammonium cation since there is no hydrogen atom in trialkyl amine

Amide Hydrolysis: In presence of base or acid with continuous heating, amide reacts with water to form the corresponding amine and carboxylic acid.

Carboxylic acid and amine salt are obtained when amide hydrolysis takes place in presence of acid.

Carboxylate anion and amine are obtained when amide hydrolysis takes place in presence of base.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 17.1 - Identify the following molecules as a carboxylic...Ch. 17.1 - Prob. 17.2P Ch. 17.1 - Prob. 17.3P Ch. 17.1 - Prob. 17.4P Ch. 17.1 - Prob. 17.5P Ch. 17.1 - Prob. 17.6P Ch. 17.1 - In the following pairs of compounds, which would...Ch. 17.1 - Write both condensed and line structures for (a)...Ch. 17.1 - Prob. 17.9P Ch. 17.1 - Draw structures corresponding to these names: (a)...

Solution Summary: The author explains how N-Acetylglucosamide reacts with water to remove the acetyle group.

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