Principles of General, Organic, Biological Chemistry
2nd Edition
ISBN: 9780073511191
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 17, Problem 17.78AP
Consider the following mRNA sequence: ACC UUA CGA.
- a. What amino acid sequence is coded for by this mRNA?
- b. What is the amino acid sequence if a mutation converts UUA to UCA?
- c. What is the amino acid sequence if a mutation converts CGA to AGA?
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Part II. xiao isolated a compound TAD (Ca H 10 N₂) from tobacco and obtained its IR spectrum. Xiao proposed
a chemical structure shown below:
% Transmittance
4000
3500
3000
2500 2000
Wavenumber (cm-1)
1500
1000
(a) Explain why her proposed structure is inconsistent with the IR spectrum obtained
(b) TAD exists as a tautomer of the structure xiao proposed. Draw the structure
and explain why it is more compatible with the obtained spectrum.
(C) what is the possible source for the fairly intense signal at
1621cm1
AE>AE₁ (Y/N)
AE=AE₁ (Y/N)
AE
Treatment of 2-phenylpropan-2-amine with methyl 2,4-dibromobutanoate in the presence of a nonnucleophilic base, R3N, involves two successive SN2 reactions and
gives compound A.
?
NH2
Br
Br
Propose a structural formula for compound A.
You do not have to explicitly draw H atoms.
You do not have to consider stereochemistry.
In cases where there is more than one answer, just draw one.
R3N
C14H19NO2
+ 2 R3NH*Br
A
Chapter 17 Solutions
Principles of General, Organic, Biological Chemistry
Ch. 17.1 - Prob. 17.1PCh. 17.1 - Draw the structure of guanosine. Classify the...Ch. 17.1 - Prob. 17.3PCh. 17.1 - Give the name that corresponds to each...Ch. 17.1 - Which nucleic acid (DNA or RNA) contains each of...Ch. 17.1 - Label each statement about the compound...Ch. 17.1 - Identify each component as a base, nucleoside, or...Ch. 17.2 - Draw the structure of a dinucleotide formed by...Ch. 17.2 - Label the 5' end and the 3' end in each...Ch. 17.2 - Label each statement about the polynucleotide...
Ch. 17.3 - Write the complementary strand for each of the...Ch. 17.4 - What is the sequence of a newly synthesized DNA...Ch. 17.6 - Prob. 17.13PCh. 17.6 - Prob. 17.14PCh. 17.11 - Prob. 17.24PCh. 17 - Label each statement as pertaining to DNA, RNA, or...Ch. 17 - (a) Identify the base and monosaccharide in the...Ch. 17 - (a) Identify the base and monosaccharide in the...Ch. 17 - Consider the given dinucleotide. a. Identify the...Ch. 17 - Answer Problem 17.29 for the following...Ch. 17 - Fill in the codon, anticodon, or amino acid needed...Ch. 17 - Fill in the codon, anticodon, or amino acid needed...Ch. 17 - What is the difference between a gene and a...Ch. 17 - Prob. 17.38APCh. 17 - List three structural differences between DNA and...Ch. 17 - List three structural similarities in DNA and RNA.Ch. 17 - Prob. 17.41APCh. 17 - Prob. 17.42APCh. 17 - Give the name, abbreviation, or structure of each...Ch. 17 - Give the name, abbreviation, or structure of each...Ch. 17 - Classify each molecule as a nucleoside or...Ch. 17 - Draw the structure of the deoxyribonucleotide...Ch. 17 - Draw the structure of the ribonucleotide formed by...Ch. 17 - Describe in detail the DNA double helix with...Ch. 17 - Describe in detail the DNA double helix with...Ch. 17 - Write the sequence of the complementary strand of...Ch. 17 - Write the sequence of the complementary strand of...Ch. 17 - What is the sequence of the mRNA molecule...Ch. 17 - What is the sequence of the mRNA molecule...Ch. 17 - Considering each nucleotide sequence in an mRNA...Ch. 17 - Considering each nucleotide sequence in an mRNA...Ch. 17 - What is the difference between a point mutation...Ch. 17 - Consider the following mRNA sequence: CUU CAG CAC....Ch. 17 - Consider the following mRNA sequence: ACC UUA CGA....
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