The mechanism for the given reaction is to be drawn and the major product is to be predicted. Concept introduction: Sodium hydride is a strong base but a poor nucleophile. So, it will deprotonate the alpha carbon of the carbonyl compound. This will generate a strong nucleophile as well as a strong base, the enolate ion, which can abstract the hydrogen in water or deuterium in deuterated water. Deuterium is an isotope of the hydrogen and has similar properties as hydrogen.

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Answer 1

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 17, Problem 17.44P

Interpretation Introduction

Interpretation:

The mechanism for the given reaction is to be drawn and the major product is to be predicted.

Concept introduction:

Sodium hydride is a strong base but a poor nucleophile. So, it will deprotonate the alpha carbon of the carbonyl compound. This will generate a strong nucleophile as well as a strong base, the enolate ion, which can abstract the hydrogen in water or deuterium in deuterated water. Deuterium is an isotope of the hydrogen and has similar properties as hydrogen.

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Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 17, Problem 17.44P

Interpretation Introduction

Interpretation:

The mechanism for the given reaction is to be drawn and the major product is to be predicted.

Concept introduction:

Sodium hydride is a strong base but a poor nucleophile. So, it will deprotonate the alpha carbon of the carbonyl compound. This will generate a strong nucleophile as well as a strong base, the enolate ion, which can abstract the hydrogen in water or deuterium in deuterated water. Deuterium is an isotope of the hydrogen and has similar properties as hydrogen.

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Answer 3

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 17, Problem 17.44P

Interpretation Introduction

Interpretation:

The mechanism for the given reaction is to be drawn and the major product is to be predicted.

Concept introduction:

Sodium hydride is a strong base but a poor nucleophile. So, it will deprotonate the alpha carbon of the carbonyl compound. This will generate a strong nucleophile as well as a strong base, the enolate ion, which can abstract the hydrogen in water or deuterium in deuterated water. Deuterium is an isotope of the hydrogen and has similar properties as hydrogen.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 17, Problem 17.44P

Interpretation Introduction