ORGANIC CHEM +SG +SAPLING >IP<
ORGANIC CHEM +SG +SAPLING >IP<
6th Edition
ISBN: 9781319171179
Author: LOUDON
Publisher: MAC HIGHER
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Chapter 17, Problem 17.29AP
Interpretation Introduction

Interpretation:

The reactivity of the compounds, mnitrotertcumylchloride pmethoxytertcumylchloride, pfluorotertcumylchloride, and pnitrotertcumylchloride towards SN1 solvolysis reaction, is to be arranged in the increasing order.

Concept introduction:

Nucleophilic substitution reaction is a reaction where an electron rich species attacks a substrate which is electron deficient. When the solvent of the solution behaves as a nucleophile then it is known as solvolysis. Nucleophilic substitution reactions are of two types, SN1 and SN2.

The unimolecular nucleophilic substitution reaction is SN1 reaction. This type of reaction takes place in two steps; in first step a carbocation is formed. The stability of carbocation decides the feasibility of reaction. Stability of carbocation is affected by the groups attached to the ring showing +I or I effect.

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