(a) Interpretation: The structure of the starting compound that gives the given product on oxidation with MnO 2 , is to be stated. Concept introduction: Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO 2 . In presence of MnO 2 , primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones .

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Answer 1

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 17, Problem 17.11P

Interpretation Introduction

(a)

Interpretation:

The structure of the starting compound that gives the given product on oxidation with MnO2, is to be stated.

Concept introduction:

Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO2. In presence of MnO2, primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones.

Interpretation Introduction

(b)

Interpretation:

The structure of the starting compound that gives the given product on oxidation with MnO2, is to be stated.

Concept introduction:

Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO2. In presence of MnO2, primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones.

Interpretation Introduction

(c)

Interpretation:

The structure of the starting compound that gives the given product on oxidation with MnO2, is to be stated.

Concept introduction:

Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO2. In presence of MnO2, primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones.

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1. Predict the organic product(s) of the following reactions. Assume excess of reagents unless otherwise noted. a) &l BH3 •THF b) 1) NaOH 2) H3O+ solve d) ala 1) EtMgBr 2) H3O+ e) H2N سكر CuLi NH2 1) SOCI2 2) EtMgBr 3) H3O+ NC H3O+ Δ

There are 48 pairs of students in the following table. Each pair has quantitatively determined the mass of taurine in a 250 mL can of the popular energy drink marketed as “Munster” using High Performance Liquid Chromatography (HPLC). The class results are presented below: QUESTION: Summarise and report these results including an indication of measurement uncertainty. In both calculation samples calculate if an outlier is present, max value, number of samples, mean, standard deviation, g (suspect), g (critical) and t (critical). Mass of Taurine (mg) Mass of Taurine (mg) (Table continued) 152.01 152.23 151.87 151.45 154.11 152.64 152.98 153.24 152.88 151.45 153.49 152.48 150.68 152.33 151.52 153.63 152.48 151.68 153.17 153.40 153.77 153.67 152.34 153.16 152.57 153.02 152.86 151.50 151.23 152.57 152.72 151.54 146.47 152.38 152.44 152.54 152.53 152.54 151.32…

Indicate the rate expressions for reactions that have order 0, 1, and 2.

Answer 2

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 17, Problem 17.11P

Interpretation Introduction

(a)

Interpretation:

The structure of the starting compound that gives the given product on oxidation with MnO2, is to be stated.

Concept introduction:

Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO2. In presence of MnO2, primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones.

Interpretation Introduction

(b)

Interpretation:

The structure of the starting compound that gives the given product on oxidation with MnO2, is to be stated.

Concept introduction:

Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO2. In presence of MnO2, primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones.

Interpretation Introduction

(c)

Interpretation:

The structure of the starting compound that gives the given product on oxidation with MnO2, is to be stated.

Concept introduction:

Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO2. In presence of MnO2, primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones.

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 17, Problem 17.11P

Interpretation Introduction

(a)

Interpretation:

The structure of the starting compound that gives the given product on oxidation with MnO2, is to be stated.

Concept introduction:

Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO2. In presence of MnO2, primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones.

Interpretation Introduction

(b)

Interpretation:

The structure of the starting compound that gives the given product on oxidation with MnO2, is to be stated.

Concept introduction:

Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO2. In presence of MnO2, primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones.

Interpretation Introduction

(c)

Interpretation:

The structure of the starting compound that gives the given product on oxidation with MnO2, is to be stated.

Concept introduction:

Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO2. In presence of MnO2, primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones.

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 17, Problem 17.11P

Interpretation Introduction

(a)

Interpretation:

The structure of the starting compound that gives the given product on oxidation with MnO2, is to be stated.

Concept introduction:

Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO2. In presence of MnO2, primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones.

Interpretation Introduction

(b)

Interpretation:

The structure of the starting compound that gives the given product on oxidation with MnO2, is to be stated.

Concept introduction:

Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO2. In presence of MnO2, primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones.

Interpretation Introduction

(c)

Interpretation:

The structure of the starting compound that gives the given product on oxidation with MnO2, is to be stated.

Concept introduction:

Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO2. In presence of MnO2, primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones.

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Answer 5

Chapter 17, Problem 17.11P

Interpretation Introduction

(a)

Interpretation:

The structure of the starting compound that gives the given product on oxidation with MnO2, is to be stated.

Concept introduction:

Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO2. In presence of MnO2, primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones.

Interpretation Introduction

(b)

Interpretation:

The structure of the starting compound that gives the given product on oxidation with MnO2, is to be stated.

Concept introduction:

Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO2. In presence of MnO2, primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones.

Interpretation Introduction

(c)

Interpretation:

The structure of the starting compound that gives the given product on oxidation with MnO2, is to be stated.

Concept introduction:

Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO2. In presence of MnO2, primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones.

Answer 6

Chapter 17, Problem 17.11P

Interpretation Introduction

(a)

Interpretation:

The structure of the starting compound that gives the given product on oxidation with MnO2, is to be stated.

Concept introduction:

Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO2. In presence of MnO2, primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones.

Answer 7

Chapter 17, Problem 17.11P

Interpretation Introduction

(a)

Interpretation:

The structure of the starting compound that gives the given product on oxidation with MnO2, is to be stated.

Concept introduction:

Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO2. In presence of MnO2, primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure of the starting compound that gives the given product on oxidation with MnO2, is to be stated.

Concept introduction:

Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO2. In presence of MnO2, primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure of the starting compound that gives the given product on oxidation with MnO2, is to be stated.

Concept introduction:

Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO2. In presence of MnO2, primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structure of the starting compound that gives the given product on oxidation with MnO2, is to be stated.

Concept introduction:

Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO2. In presence of MnO2, primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structure of the starting compound that gives the given product on oxidation with MnO2, is to be stated.

Concept introduction:

Oxidation is defined as loss of electrons and addition of oxygen or removal of hydrogen. The benzylic and allylic alcohols are selectively oxidized by the MnO2. In presence of MnO2, primary allylic or benzylic alcohols are oxidized to aldehydes and secondary allylic or benzylic alcohols are oxidized to ketones.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 17 - Prob. 17.1P Ch. 17 - Prob. 17.2P Ch. 17 - Prob. 17.3P Ch. 17 - Prob. 17.4P Ch. 17 - Prob. 17.5P Ch. 17 - Prob. 17.6P Ch. 17 - Prob. 17.7P Ch. 17 - Prob. 17.8P Ch. 17 - Prob. 17.9P Ch. 17 - Prob. 17.10P

Solution Summary: The author explains the structure of the starting compound that gives the given product on oxidation with MnO_ 2.

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Chapter 17 Solutions