Chemistry: An Introduction to General, Organic, and Biological Chemistry (12th Edition) - Standalone book
12th Edition
ISBN: 9780321908445
Author: Karen C. Timberlake
Publisher: PEARSON
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Chapter 16.5, Problem 16.33QAP
Why do
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Part V. Label ad match the carbons in compounds Jane and Diane
w/ the corresponding peak no.
in the
Spectra (Note: use the given peak no. To label the carbons, other peak
no are intentionally
omitted)
7 4 2
-0.13
-0.12
-0.11
-0.10
-0.08
8
CI
Jane
1
-0.09
5
210
200
190
180
170
160
150
140
130
120
110
100
-8
90
f1 (ppm)
11
8
172.4
172.0
f1 (ppr
HO
CI
NH
Diane
7
3
11
80
80
-80
-R
70
60
60
2
5
-8
50
40
8.
170
160
150
140
130
120
110
100
90
-0
80
70
20
f1 (ppm)
15
30
-20
20
-60
60
-0.07
-0.06
-0.05
-0.04
-0.03
-0.02
-0.01
-0.00
-0.01
10
-0.17
16
15
56
16
-0.16
-0.15
-0.14
-0.13
-0.12
-0.11
-0.10
-0.09
-0.08
-0.07
-0.06
-0.05
-0.04
17.8 17.6 17.4 17.2 17.0
f1 (ppm)
-0.03
-0.02
550
106
40
30
20
20
-0.01
-0.00
F-0.01
10
0
Chapter 16 Solutions
Chemistry: An Introduction to General, Organic, and Biological Chemistry (12th Edition) - Standalone book
Ch. 16.1 - Classify each of the following proteins according...Ch. 16.1 - Prob. 16.2QAPCh. 16.1 - Prob. 16.3QAPCh. 16.1 - Prob. 16.4QAPCh. 16.1 - Draw the structure for each of the following amino...Ch. 16.1 - Draw the structure for each of the following amino...Ch. 16.1 - Draw the strcture for each of the following amino...Ch. 16.1 - Prob. 16.8QAPCh. 16.1 - Prob. 16.9QAPCh. 16.1 - Prob. 16.10QAP
Ch. 16.2 - Prob. 16.11QAPCh. 16.2 - Prob. 16.12QAPCh. 16.2 - Prob. 16.13QAPCh. 16.2 - Prob. 16.14QAPCh. 16.2 - Prob. 16.15QAPCh. 16.2 - Prob. 16.16QAPCh. 16.3 - Prob. 16.17QAPCh. 16.3 - Prob. 16.18QAPCh. 16.3 - Prob. 16.19QAPCh. 16.3 - Prob. 16.20QAPCh. 16.4 - Prob. 16.21QAPCh. 16.4 - Prob. 16.22QAPCh. 16.4 - Prob. 16.23QAPCh. 16.4 - Prob. 16.24QAPCh. 16.4 - What type of interaction would you expect between...Ch. 16.4 - What type of interaction would you expect between...Ch. 16.4 - Prob. 16.27QAPCh. 16.4 - Prob. 16.28QAPCh. 16.4 - Prob. 16.29QAPCh. 16.4 - Prob. 16.30QAPCh. 16.4 - Prob. 16.31QAPCh. 16.4 - Indicate the changes in secondary and tertiary...Ch. 16.5 - Why do chemical reactions in the body require...Ch. 16.5 - Prob. 16.34QAPCh. 16.5 - Prob. 16.35QAPCh. 16.5 - Prob. 16.36QAPCh. 16.5 - Prob. 16.37QAPCh. 16.5 - Prob. 16.38QAPCh. 16.5 - Prob. 16.39QAPCh. 16.5 - 16.36 Match the terms (1) active site, (2)...Ch. 16.5 - Prob. 16.51QAPCh. 16.5 - Prob. 16.52QAPCh. 16.5 - Prob. 16.43QAPCh. 16.5 - Prob. 16.44QAPCh. 16.5 - For problems 16.39 to 16.42, see Chemistry Link to...Ch. 16.5 - Prob. 16.46QAPCh. 16.6 - Trypsin, a peptidase that hydrolyzes polypeptides,...Ch. 16.6 - pepsin, a peptidase that hydrolyzes proteins,...Ch. 16.6 - The following graph shows the activity versus pH...Ch. 16.6 - The following graph shows the activity versus pH...Ch. 16.6 - Prob. 16.47QAPCh. 16.6 - Prob. 16.48QAPCh. 16.6 - Prob. 16.49QAPCh. 16.6 - Prob. 16.50QAPCh. 16.6 - What is the chemical formula for hydroxyurea?Ch. 16.6 - What is the molar mass of hydroxyurea?Ch. 16.6 - Prob. 16.53QAPCh. 16.6 - Prob. 16.54QAPCh. 16 - Prob. 16.55UTCCh. 16 - Prob. 16.56UTCCh. 16 - Prob. 16.57UTCCh. 16 - Prob. 16.58UTCCh. 16 - Prob. 16.59UTCCh. 16 - Prob. 16.60UTCCh. 16 - 16.59 Identify the amino acids and type of...Ch. 16 - What type of interaction would you expect between...Ch. 16 - Draw the condensed structural formula for...Ch. 16 - Draw the condensed structural formula for...Ch. 16 - Seed and vegetables are often deficient in one or...Ch. 16 - 16.64 Seeds and vegetables are often deficient in...Ch. 16 - Prob. 16.67AQAPCh. 16 - Prob. 16.68AQAPCh. 16 - Prob. 16.69AQAPCh. 16 - Prob. 16.70AQAPCh. 16 - Prob. 16.71AQAPCh. 16 - Why do enzymes function only under mild...Ch. 16 - Prob. 16.73AQAPCh. 16 - Prob. 16.74AQAPCh. 16 - Prob. 16.75AQAPCh. 16 - Prob. 16.76AQAPCh. 16 - Prob. 16.77AQAPCh. 16 - Prob. 16.78AQAPCh. 16 - Prob. 16.79AQAPCh. 16 - Prob. 16.80AQAPCh. 16 - If a blood test indicates a high level of LDH and...Ch. 16 - Prob. 16.82AQAPCh. 16 - Prob. 16.83CQCh. 16 - Prob. 16.84CQCh. 16 - Prob. 16.85CQCh. 16 - Prob. 16.86CQ
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- n Feb 3 A T + 4. (2 pts) Draw the structure of the major component of the Limonene isolated. Explain how you confirmed the structure. 5. (2 pts) Draw the fragment corresponding to the base peak in the Mass spectrum of Limonene. 6. (1 pts) Predict the 1H NMR spectral data of R-Limonene. Proton NMR: 5.3 pon multiplet (H Ringarrow_forwardPart VI. Ca H 10 O is the molecular formula of compound Tom and gives the in the table below. Give a possible structure for compound Tom. 13C Signals summarized C1 C2 C3 C4 C5 C6 C7 13C shift (ppm) 23.5 27.0 33.0 35.8 127 162 205 DEPT-90 + DEPT-135 + +arrow_forward2. Using the following data to calculate the value of AvapH o of water at 298K. AvapH o of water at 373K is 40.7 kJ/mol; molar heat capacity of liquid water at constant pressure is 75.2J mol-1 K-1 and molar heat capacity of water vapor at constant pressure is 33.6 J mol-1 K-1.arrow_forward
- Part VII. Below are the 'HNMR 13 3 C-NMR, COSY 2D- NMR, and HSQC 20-NMR (Similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H13 O. Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum ли 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 1.0 0.9 0.8 f1 (ppm)arrow_forward3. Draw the expanded structural formula, the condensed structural formula, and the skeletal structural formula for 2-pentene. expanded structure: Condensed structure: Skeletal formula: 4. Draw the expanded structural formula, the condensed structural formula, and the skeletal structural formula for 2-methyl-3-heptene. expanded structure: Condensed structure: Skeletal formula: following structurearrow_forwardPart IV. Propose a plausible Structure w/ the following descriptions: a) A 5-carbon hydrocarbon w/ a single peak in its proton decoupled the DEPT-135 Spectrum shows a negative peak C-NMR spectrum where b) what cyclohexane dione isomer gives the largest no. Of 13C NMR signals? c) C5H120 (5-carbon alcohol) w/ most deshielded carbon absent in any of its DEPT Spectivaarrow_forward
- 13C NMR is good for: a) determining the molecular weight of the compound b) identifying certain functional groups. c) determining the carbon skeleton, for example methyl vs ethyl vs propyl groups d) determining how many different kinds of carbon are in the moleculearrow_forward6 D 2. (1 pt) Limonene can be isolated by performing steam distillation of orange peel. Could you have performed this experiment using hexane instead of water? Explain. 3. (2 pts) Using GCMS results, analyze and discuss the purity of the Limonene obtained from the steam distillation of orange peel.arrow_forwardPart III. Arrange the following carbons (in blue) in order of increasing chemical shift. HO B NH 2 A CIarrow_forward
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