ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
10th Edition
ISBN: 9781260028355
Author: Carey
Publisher: MCG CUSTOM
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Chapter 16.2, Problem 2P
Interpretation Introduction

Interpretation:

The structural formulae of the products of the given reactions that reflect the position of the deuterium atom in each of the product are to be determined.

Concept introduction:

The sodium borohydride (NaBH4) and lithium aluminum hydride (LiAlH4) act as a hydrogen donor compound.

The sodium borohydride (NaBH4) reduces the aldehydes and ketones to corresponding alcohols and the hydrogen atom that is bonded to carbonyl compound comes from borohydride.

The lithium aluminum hydride (LiAlH4) reduces almost all types of carbonyl compounds to their corresponding alcohols the hydrogen atom that is bonded to carbonyl compound comes from aluminum hydride

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?
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Chapter 16 Solutions

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