ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
10th Edition
ISBN: 9781260028355
Author: Carey
Publisher: MCG CUSTOM
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Chapter 16, Problem 30P
Interpretation Introduction

Interpretation:

An efficient synthesis of pheromone (4-methyl-3-heptanol) from alcohols of five carbon atoms or fewer is to be suggested.

Concept Introduction:

Alochol on oxidation yields a carbonyl compound. The resulting carbonyl compound is an aldehyde, ketone, or a carboxylic acid depending upon the type of alcohol that is been used.

A primary alcohol is oxidized to a carbonyl compound containing an aldehyde group.

A secondary alcohol is oxidized to a carbonyl compound containing a keto group.

Pyridinium chlorochromate (PCC) in dichloromethane, pyridinium dichromate (PDC) in dichloromethane are used in oxidizing primary and secondary alcohol to carbonyl compounds.

Phosphorous tribromide converts alcohols to alkyl bromides.

Aldehydes on reactions of Grignard reagents yield secondary alcohols.

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