The reaction sequence for each of the given conversion required two synthetic steps with suitable reagents is to be suggested. Concept introduction: The ketone on reduction with sodium borohydride gives secondary alcohols. The alcohol on dehydration in presence of acid catalyst eliminates water molecule and forms double bond. The primary alcohols on oxidation with good oxidizing agent forms carboxylic acid . The tertiary alcohol does not undergo oxidation to form carbonyl compound. Vicinal diols on treatment with periodic acid ( HIO 4 ) undergoes cleavage of carbon-carbon bond of vicinal diol and results in two carbonyl compounds. The dihydroxylation is the addition of two hydroxyl groups to the double bond of alkene to form a 1,2 diol. The both hydroxyl groups add to double bond from same side of double bond.

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Answer 1

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Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 16, Problem 29P

Interpretation Introduction

Interpretation:

The reaction sequence for each of the given conversion required two synthetic steps with suitable reagents is to be suggested.

Concept introduction:

The ketone on reduction with sodium borohydride gives secondary alcohols.

The alcohol on dehydration in presence of acid catalyst eliminates water molecule and forms double bond.

The primary alcohols on oxidation with good oxidizing agent forms carboxylic acid.

The tertiary alcohol does not undergo oxidation to form carbonyl compound.

Vicinal diols on treatment with periodic acid (HIO4) undergoes cleavage of carbon-carbon bond of vicinal diol and results in two carbonyl compounds.

The dihydroxylation is the addition of two hydroxyl groups to the double bond of alkene to form a 1,2 diol. The both hydroxyl groups add to double bond from same side of double bond.

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SYNTHESIS REACTIONS. For the following reactions, synthesize the given products from the given reactants. Multiple reactions/steps will be needed. For the one of the steps (ie reactions) in each synthesis, write out the mechanism for that reaction and draw an energy diagram showing the correct number of hills and valleys for that step's mechanism. CI b. a. Use acetylene (ethyne) and any alkyl halide as your starting materials Br C. d. "OH OH III. OH

Answer 2

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Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 16, Problem 29P

Interpretation Introduction

Interpretation:

The reaction sequence for each of the given conversion required two synthetic steps with suitable reagents is to be suggested.

Concept introduction:

The ketone on reduction with sodium borohydride gives secondary alcohols.

The alcohol on dehydration in presence of acid catalyst eliminates water molecule and forms double bond.

The primary alcohols on oxidation with good oxidizing agent forms carboxylic acid.

The tertiary alcohol does not undergo oxidation to form carbonyl compound.

Vicinal diols on treatment with periodic acid (HIO4) undergoes cleavage of carbon-carbon bond of vicinal diol and results in two carbonyl compounds.

The dihydroxylation is the addition of two hydroxyl groups to the double bond of alkene to form a 1,2 diol. The both hydroxyl groups add to double bond from same side of double bond.

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Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 16, Problem 29P

Interpretation Introduction

Interpretation:

The reaction sequence for each of the given conversion required two synthetic steps with suitable reagents is to be suggested.

Concept introduction:

The ketone on reduction with sodium borohydride gives secondary alcohols.

The alcohol on dehydration in presence of acid catalyst eliminates water molecule and forms double bond.

The primary alcohols on oxidation with good oxidizing agent forms carboxylic acid.

The tertiary alcohol does not undergo oxidation to form carbonyl compound.

Vicinal diols on treatment with periodic acid (HIO4) undergoes cleavage of carbon-carbon bond of vicinal diol and results in two carbonyl compounds.

The dihydroxylation is the addition of two hydroxyl groups to the double bond of alkene to form a 1,2 diol. The both hydroxyl groups add to double bond from same side of double bond.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 16, Problem 29P

Interpretation Introduction