To write the product for the given reaction. Concept introduction: When a ketone reacts with a diol , the formation of cyclic ketal takes place. The reaction takes place in the presence of an acid catalyst. An acid catalyst is to activate the carbonyl group. The nucleophile attacks the carbonyl group leading to the formation of oxonium ion. The oxonium ion is again attacked by the nucleophile to form the cyclic ketal. The cyclic ketal can be five-memebered or six-memebered depending upon the diol used in the reaction.

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Answer 1

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 16, Problem 76P

(a)

Interpretation Introduction

Interpretation:

To write the product for the given reaction.

Concept introduction:

When a ketone reacts with a diol, the formation of cyclic ketal takes place. The reaction takes place in the presence of an acid catalyst. An acid catalyst is to activate the carbonyl group. The nucleophile attacks the carbonyl group leading to the formation of oxonium ion. The oxonium ion is again attacked by the nucleophile to form the cyclic ketal. The cyclic ketal can be five-memebered or six-memebered depending upon the diol used in the reaction.

(b)

Interpretation Introduction

Interpretation:

To write the product for the given reactions.

Concept introduction:

When a ketone reacts with a diol, the formation of cyclic ketal takes place. The reaction takes place in the presence of an acid catalyst. An acid catalyst is to activate the carbonyl group. The nucleophile attacks the carbonyl group leading to the formation of oxonium ion. The oxonium ion is again attacked by the nucleophile to form the cyclic ketal. The cyclic ketal can be five-memebered or six-memebered depending upon the diol used in the reaction.

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PLEASE READ!!! I DONT WANT EXAMPLES, I DONT WANT WORDS OR PARAGRAPHS FOR THE MECHANISM!!! THANKS First image: QUESTION 6. I have to show, with ARROWS and STRUCTURES, the mechanism of the reaction at the bottom. Also I have to show by mecanism why the reaction wouldn't work if the alcohol was primary. I also tried to draw the mechanism, tell me what to change. Please note that its an AMIDE thats formed not an AMINE the nitrogen has ONE hydrogen and one Phenyl-C-Phenyl. I already asked for this mechanism and got as a final product ...-NH2 not whats shown on the picture, thank you Ths second part. QUESTION 3. I just need a way to synthesize the lactone A, I already started please continue from where I left it Second image: I simply need the products, substrates or reagents, thank you

Indicate how to prepare a 10% sodium hydroxide (NaOH) solution to a slightly alkaline pH.

Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 16, Problem 76P

(a)

Interpretation Introduction

Interpretation:

To write the product for the given reaction.

Concept introduction:

When a ketone reacts with a diol, the formation of cyclic ketal takes place. The reaction takes place in the presence of an acid catalyst. An acid catalyst is to activate the carbonyl group. The nucleophile attacks the carbonyl group leading to the formation of oxonium ion. The oxonium ion is again attacked by the nucleophile to form the cyclic ketal. The cyclic ketal can be five-memebered or six-memebered depending upon the diol used in the reaction.

(b)

Interpretation Introduction

Interpretation:

To write the product for the given reactions.

Concept introduction:

When a ketone reacts with a diol, the formation of cyclic ketal takes place. The reaction takes place in the presence of an acid catalyst. An acid catalyst is to activate the carbonyl group. The nucleophile attacks the carbonyl group leading to the formation of oxonium ion. The oxonium ion is again attacked by the nucleophile to form the cyclic ketal. The cyclic ketal can be five-memebered or six-memebered depending upon the diol used in the reaction.

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 16, Problem 76P

(a)

Interpretation Introduction

Interpretation:

To write the product for the given reaction.

Concept introduction:

When a ketone reacts with a diol, the formation of cyclic ketal takes place. The reaction takes place in the presence of an acid catalyst. An acid catalyst is to activate the carbonyl group. The nucleophile attacks the carbonyl group leading to the formation of oxonium ion. The oxonium ion is again attacked by the nucleophile to form the cyclic ketal. The cyclic ketal can be five-memebered or six-memebered depending upon the diol used in the reaction.

(b)

Interpretation Introduction

Interpretation:

To write the product for the given reactions.

Concept introduction:

When a ketone reacts with a diol, the formation of cyclic ketal takes place. The reaction takes place in the presence of an acid catalyst. An acid catalyst is to activate the carbonyl group. The nucleophile attacks the carbonyl group leading to the formation of oxonium ion. The oxonium ion is again attacked by the nucleophile to form the cyclic ketal. The cyclic ketal can be five-memebered or six-memebered depending upon the diol used in the reaction.

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 16, Problem 76P

(a)

Interpretation Introduction

Interpretation:

To write the product for the given reaction.

Concept introduction:

When a ketone reacts with a diol, the formation of cyclic ketal takes place. The reaction takes place in the presence of an acid catalyst. An acid catalyst is to activate the carbonyl group. The nucleophile attacks the carbonyl group leading to the formation of oxonium ion. The oxonium ion is again attacked by the nucleophile to form the cyclic ketal. The cyclic ketal can be five-memebered or six-memebered depending upon the diol used in the reaction.

(b)

Interpretation Introduction

Interpretation:

To write the product for the given reactions.

Concept introduction:

When a ketone reacts with a diol, the formation of cyclic ketal takes place. The reaction takes place in the presence of an acid catalyst. An acid catalyst is to activate the carbonyl group. The nucleophile attacks the carbonyl group leading to the formation of oxonium ion. The oxonium ion is again attacked by the nucleophile to form the cyclic ketal. The cyclic ketal can be five-memebered or six-memebered depending upon the diol used in the reaction.

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Answer 5

Chapter 16, Problem 76P

(a)

Interpretation Introduction

Interpretation:

To write the product for the given reaction.

Concept introduction:

When a ketone reacts with a diol, the formation of cyclic ketal takes place. The reaction takes place in the presence of an acid catalyst. An acid catalyst is to activate the carbonyl group. The nucleophile attacks the carbonyl group leading to the formation of oxonium ion. The oxonium ion is again attacked by the nucleophile to form the cyclic ketal. The cyclic ketal can be five-memebered or six-memebered depending upon the diol used in the reaction.

(b)

Interpretation Introduction

Interpretation:

To write the product for the given reactions.

Concept introduction:

When a ketone reacts with a diol, the formation of cyclic ketal takes place. The reaction takes place in the presence of an acid catalyst. An acid catalyst is to activate the carbonyl group. The nucleophile attacks the carbonyl group leading to the formation of oxonium ion. The oxonium ion is again attacked by the nucleophile to form the cyclic ketal. The cyclic ketal can be five-memebered or six-memebered depending upon the diol used in the reaction.

Answer 6

Chapter 16, Problem 76P

(a)

Interpretation Introduction

Interpretation:

To write the product for the given reaction.

Concept introduction:

When a ketone reacts with a diol, the formation of cyclic ketal takes place. The reaction takes place in the presence of an acid catalyst. An acid catalyst is to activate the carbonyl group. The nucleophile attacks the carbonyl group leading to the formation of oxonium ion. The oxonium ion is again attacked by the nucleophile to form the cyclic ketal. The cyclic ketal can be five-memebered or six-memebered depending upon the diol used in the reaction.

Answer 7

Chapter 16, Problem 76P

(a)

Interpretation Introduction

Interpretation:

To write the product for the given reaction.

Concept introduction:

When a ketone reacts with a diol, the formation of cyclic ketal takes place. The reaction takes place in the presence of an acid catalyst. An acid catalyst is to activate the carbonyl group. The nucleophile attacks the carbonyl group leading to the formation of oxonium ion. The oxonium ion is again attacked by the nucleophile to form the cyclic ketal. The cyclic ketal can be five-memebered or six-memebered depending upon the diol used in the reaction.

Answer 8

(b)

Interpretation Introduction

Interpretation:

To write the product for the given reactions.

Concept introduction:

When a ketone reacts with a diol, the formation of cyclic ketal takes place. The reaction takes place in the presence of an acid catalyst. An acid catalyst is to activate the carbonyl group. The nucleophile attacks the carbonyl group leading to the formation of oxonium ion. The oxonium ion is again attacked by the nucleophile to form the cyclic ketal. The cyclic ketal can be five-memebered or six-memebered depending upon the diol used in the reaction.

Answer 9

(b)

Interpretation Introduction

Interpretation:

To write the product for the given reactions.

Concept introduction:

When a ketone reacts with a diol, the formation of cyclic ketal takes place. The reaction takes place in the presence of an acid catalyst. An acid catalyst is to activate the carbonyl group. The nucleophile attacks the carbonyl group leading to the formation of oxonium ion. The oxonium ion is again attacked by the nucleophile to form the cyclic ketal. The cyclic ketal can be five-memebered or six-memebered depending upon the diol used in the reaction.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 16.1 - Give two names for each of the following:Ch. 16.1 - Prob. 2P Ch. 16.1 - Name the following:Ch. 16.2 - Prob. 4P Ch. 16.4 - What products are formed when the following...Ch. 16.4 - We saw on the previous page that...Ch. 16.4 - a. How many stereoisomers are obtained from the...Ch. 16.4 - Prob. 9P Ch. 16.4 - Write the mechanism for the reaction of acetyl...Ch. 16.4 - Prob. 11P

Solution Summary: The author explains how ketone reacts with a diol, and the reaction is used to protect aldehydes and ketones.

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Chapter 16 Solutions