Introduction to General, Organic and Biochemistry
Introduction to General, Organic and Biochemistry
12th Edition
ISBN: 9780357119303
Author: Bettelheim, Frederick A., Brown, William H., Campbell, Mary K., FARRELL, Shawn O., Torres, Omar
Publisher: Cengage Learning
Question
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Chapter 16, Problem 57P
Interpretation Introduction

(a)

Interpretation:

Draw the structural formula the compound formed by the reaction of given compound with sodium borohydride.

Concept Introduction:

Aldehydes are reduced to primary alcohols and ketones are reduced in secondary alcohols. The most commonly used reagent for reduction of aldehydes and ketone is sodium borohydride NaBH4.

Expert Solution
Check Mark

Answer to Problem 57P

Introduction to General, Organic and Biochemistry, Chapter 16, Problem 57P , additional homework tip  1

Explanation of Solution

Aldehydes are reduced to primary alcohols and ketones are reduced in secondary alcohols. The most commonly used reagent for reduction of aldehydes and ketone is sodium borohydride NaBH4. In a reduction by sodium borohydride, hydride ion reacts with positive carbonyl carbon, which leaves a negative charge on the carbonyl oxygen.

Therefore, the product formed will be as follows:

Introduction to General, Organic and Biochemistry, Chapter 16, Problem 57P , additional homework tip  2

Interpretation Introduction

(b)

Interpretation:

Draw the structural formula the compound formed by the reaction of given compound with sodium borohydride.

Concept Introduction:

Aldehydes are reduced to primary alcohols and ketones are reduced in secondary alcohols. The most commonly used reagent for reduction of aldehydes and ketone is sodium borohydride NaBH4.

Expert Solution
Check Mark

Answer to Problem 57P

Introduction to General, Organic and Biochemistry, Chapter 16, Problem 57P , additional homework tip  3

Explanation of Solution

Aldehydes are reduced to primary alcohols and ketones are reduced in secondary alcohols. The most commonly used reagent for reduction of aldehydes and ketone is sodium borohydride NaBH4. In a reduction by sodium borohydride, hydride ion reacts with positive carbonyl carbon, which leaves a negative charge on the carbonyl oxygen.

Therefore, the product formed will be as follows:

Introduction to General, Organic and Biochemistry, Chapter 16, Problem 57P , additional homework tip  4

Interpretation Introduction

(c)

Interpretation:

Draw the structural formula the compound formed by the reaction of given compound with sodium borohydride.

Concept Introduction:

Aldehydes are reduced to primary alcohols and ketones are reduced in secondary alcohols. The most commonly used reagent for reduction of aldehydes and ketone is sodium borohydride NaBH4.

Expert Solution
Check Mark

Answer to Problem 57P

Introduction to General, Organic and Biochemistry, Chapter 16, Problem 57P , additional homework tip  5

Explanation of Solution

Aldehydes are reduced to primary alcohols and ketones are reduced in secondary alcohols. The most commonly used reagent for reduction of aldehydes and ketone is sodium borohydride NaBH4. In a reduction by sodium borohydride, hydride ion reacts with positive carbonyl carbon, which leaves a negative charge on the carbonyl oxygen.

Therefore, the product formed will be as follows:

Introduction to General, Organic and Biochemistry, Chapter 16, Problem 57P , additional homework tip  6

Interpretation Introduction

(d)

Interpretation:

Draw the structural formula the compound formed by the reaction of given compound with sodium borohydride.

Concept Introduction:

Aldehydes are reduced to primary alcohols and ketones are reduced in secondary alcohols. The most commonly used reagent for reduction of aldehydes and ketone is sodium borohydride NaBH4.

Expert Solution
Check Mark

Answer to Problem 57P

Introduction to General, Organic and Biochemistry, Chapter 16, Problem 57P , additional homework tip  7

Explanation of Solution

Aldehydes are reduced to primary alcohols and ketones are reduced in secondary alcohols. The most commonly used reagent for reduction of aldehydes and ketone is sodium borohydride NaBH4. In a reduction by sodium borohydride, hydride ion reacts with positive carbonyl carbon, which leaves a negative charge on the carbonyl oxygen.

Therefore, the product formed will be as follows:

Introduction to General, Organic and Biochemistry, Chapter 16, Problem 57P , additional homework tip  8

Interpretation Introduction

(e)

Interpretation:

Draw the structural formula the compound formed by the reaction of given compound with sodium borohydride.

Concept Introduction:

Aldehydes are reduced to primary alcohols and ketones are reduced in secondary alcohols. The most commonly used reagent for reduction of aldehydes and ketone is sodium borohydride NaBH4.

Expert Solution
Check Mark

Answer to Problem 57P

Introduction to General, Organic and Biochemistry, Chapter 16, Problem 57P , additional homework tip  9

Explanation of Solution

Aldehydes are reduced to primary alcohols and ketones are reduced in secondary alcohols. The most commonly used reagent for reduction of aldehydes and ketone is sodium borohydride NaBH4. In a reduction by sodium borohydride, hydride ion reacts with positive carbonyl carbon, which leaves a negative charge on the carbonyl oxygen.

Therefore, the product formed will be as follows:

Introduction to General, Organic and Biochemistry, Chapter 16, Problem 57P , additional homework tip  10

Interpretation Introduction

(f)

Interpretation:

Draw the structural formula the compound formed by the reaction of given compound with sodium borohydride.

Concept Introduction:

Aldehydes are reduced to primary alcohols and ketones are reduced in secondary alcohols. The most commonly used reagent for reduction of aldehydes and ketone is sodium borohydride NaBH4.

Expert Solution
Check Mark

Answer to Problem 57P

Introduction to General, Organic and Biochemistry, Chapter 16, Problem 57P , additional homework tip  11

Explanation of Solution

Aldehydes are reduced to primary alcohols and ketones are reduced in secondary alcohols. The most commonly used reagent for reduction of aldehydes and ketone is sodium borohydride NaBH4. In a reduction by sodium borohydride, hydride ion reacts with positive carbonyl carbon, which leaves a negative charge on the carbonyl oxygen.

Therefore, the product formed will be as follows:

Introduction to General, Organic and Biochemistry, Chapter 16, Problem 57P , additional homework tip  12

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Chapter 16 Solutions

Introduction to General, Organic and Biochemistry

Ch. 16 - 17-11 What is the difference in structure between...Ch. 16 - 17-12 Is it possible for the carbon atom of a...Ch. 16 - 17-13 Which compounds contain carbonyl groups?Ch. 16 - 17-14 Following are structural formulas for two...Ch. 16 - 17-15 Draw structural formulas for the four...Ch. 16 - Prob. 8PCh. 16 - Prob. 9PCh. 16 - 17-18 Draw structural formulas for these ketones....Ch. 16 - 17-19 Write the JUPAC names for these compounds.Ch. 16 - Prob. 12PCh. 16 - 17-2 1 Explain why each name is incorrect. Write...Ch. 16 - Prob. 14PCh. 16 - Prob. 15PCh. 16 - 17-24 In each pair of compounds, select the one...Ch. 16 - Prob. 17PCh. 16 - 17-26 Account for the fact that acetone has a...Ch. 16 - 17-27 Pentane, 1-butanol, and butanal all have...Ch. 16 - 17-28 Show how acetaldehyde can form hydrogen...Ch. 16 - 17-29 Why can’t two molecules of acetone form a...Ch. 16 - 17-30 Answer true or false. (a) The reduction of...Ch. 16 - 17-3 1 Draw a structural formula for the principal...Ch. 16 - Prob. 24PCh. 16 - 17-33 What simple chemical test could you use to...Ch. 16 - 17-34 Explain why liquid aldehydes are often...Ch. 16 - 17-35 Suppose that you take a bottle of...Ch. 16 - 17-36 Explain why the reduction of an aldehyde...Ch. 16 - Prob. 29PCh. 16 - Prob. 30PCh. 16 - Prob. 31PCh. 16 - Prob. 32PCh. 16 - Prob. 33PCh. 16 - Prob. 34PCh. 16 - Prob. 35PCh. 16 - Prob. 36PCh. 16 - Prob. 37PCh. 16 - Prob. 38PCh. 16 - 17-47 What is the characteristic structural...Ch. 16 - Prob. 40PCh. 16 - Prob. 41PCh. 16 - Prob. 42PCh. 16 - Prob. 43PCh. 16 - Prob. 44PCh. 16 - Prob. 45PCh. 16 - 17-54 Following is the structure of...Ch. 16 - Prob. 47PCh. 16 - Prob. 48PCh. 16 - Prob. 49PCh. 16 - Prob. 50PCh. 16 - Prob. 51PCh. 16 - 17-60 1-Propanol can be prepared by the reduction...Ch. 16 - Prob. 53PCh. 16 - 17-62 Show how to bring about these conversions....Ch. 16 - Prob. 55PCh. 16 - Prob. 56PCh. 16 - Prob. 57PCh. 16 - Prob. 58PCh. 16 - 17-67 Draw structural formulas for these...Ch. 16 - Prob. 60PCh. 16 - 17-69 Propanal (bp 49°C) and 1-propanol (bp 97°C)...Ch. 16 - 17-70 What simple chemical test could you use to...Ch. 16 - Prob. 63PCh. 16 - Prob. 64PCh. 16 - Prob. 65PCh. 16 - 17-72 The following molecule is an enediol; each...Ch. 16 - 17-73 Alcohols can be prepared by the...Ch. 16 - 17-74 Glucose, C6H12O6, contains an aldehyde group...Ch. 16 - Prob. 69PCh. 16 - Prob. 70PCh. 16 - Prob. 71PCh. 16 - 17-78 Complete the following equation for these...Ch. 16 - 17-79 Write an equation for each conversion. (a)...Ch. 16 - Prob. 74P
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