
Concept explainers
Interpretation:
The reagents involved in given reactions are to be determined.
Concept introduction:
Primary alcohols on oxidation with PCC form aldehyde while secondary alcohols require drastic conditions like chromic acid to form
Treatment of
Carbonyl compounds react with alcohol to form acetals. First, one molecule of alcohol reacts with carbonyl to form hemiacetal followed by another alcohol molecule to form acetals.
Acetals and hemiacetals can be cleaved through acidic hydrolysis to form carbonyl compound and alcohol.
Carbonyl compounds react with Grignard reagent followed by hydrolysis to form alcohols.
On the reaction of an alkene with ozone, carbonyl compounds are formed.
Carbonyl compounds undergo Wolff–Kishner reduction on reaction with hydrazine and then potassium hydroxide to form
Ketones react with peracids to form esters by migration of one of the alkyl or aryl group.

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Chapter 16 Solutions
EBK ORGANIC CHEMISTRY
- Question 5: Name the following compound in two ways using side chain and using prefix amine (Common name and IUPAC name both) CH3NH2 CH3CH2NHCH3 CH₂CH₂N(CH3)2 Draw the structure of diethyl methyl amine Question 6. Write the balanced combustion reaction for: a. Hexane b. Propyne c. 2-pentene Question 7: Write the following electrophilic substitution reactions of benzene: Hint: Use notes if you get confused a. Halogenation reaction: b. Nitration reaction : c. Sulphonation reaction: d. Alkylation reaction: e. Aceylation reaction:arrow_forwardQuestion 4. Name the following structures ○ CH3-C-N-H H CH3CH2-C-N-H H CH3CH2-C-N-CH3 Harrow_forwardA. Add Water to below compound which 2-methyl 2-butene (addition Reaction) H₂C CH₂ CH, + H₂O-> ? Major product? Minor product? B. Add Bromine to the compound which 2-methyl 2-butene (addition Reaction) CH₂ CH₂ + Br₂→ ? Major product and Minor product both are same in this? C. Add Hydrogen Bromide to the compound which 2-methyl 2-butene (addition Reaction) H,C CH₂ CH₂ + HBr Major product? Minor product? D. Add Hydrogen to the compound which 2-methyl 2-butene (addition Reaction) CH₂ CH₂ + H₂ Major product and Minor product both are same in this?arrow_forward
- 36) Complete the following multi-step reactions showing applications of enolate ions arising from ketones, esters, malonic ester, and keto ester, etc. (30 pts) (1) A NaOH, H₂O+ heat A NaOEt EtO OEt (11) EOH, H+ H. B LDA, H₂O+ -78°C B (i) NaOMe, Et-Br (ii) H₂O+, heat EtOOC (III) COOEt B A (i) NaOEt LiAlH 4-bromo-2-butene H₂O+ (ii) H3O+, heat Write the mechanism for Aldol Condensation (I A or B), and Claisen Condensation (II A).arrow_forward31) Complete two sets of reactions involving (R)-4-methyl-pent-2-ol producing racemic mixture of tertiary alcohols (D) and ketone derivative (C). Illustrate the mechanism of B and C or D. (25 pts) O OH 0 K2Cr2O7 Ph-CH2-Br, Mg, H2SO4 THF, H3O* (A) (D) Racemic mixture TsCl, Py (B) KCN, DMSO Ph-CH2-Br, Mg, THF, H3O+ (C) Mechanism for reactions B and C:arrow_forwardManoharan Mariappan, Ph.D., Dept. of Natur. Sci., NFC, Tallahassee, FL 33) Synthesize the aromatic compound containing para-substituted carbonyl compound starting from benzene. Illustrate the mechanism for reaction A. 1) NU (25 pts) A FeCl B (i) HNO3, H2SO4 (II) Sn, HCl(aq) NH₂ NO₂-D NH₂ (i) MeCO2Me, heat C (ii) K2Cr2O7/H2SO4 D (ii) SOCl2 (iii) 2 Et-NH2 Mechanism for reaction for the nitration of alkyl benzene (B-i): Characterize the product compound arising from the reaction D by IR and IH NMR spectral data: IR data (cm): 'H NMR data: Draw the structure and assign the chemical shift with the spin-splitting.arrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
