Chemistry
4th Edition
ISBN: 9780078021527
Author: Julia Burdge
Publisher: McGraw-Hill Education
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Chapter 16, Problem 170AP
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The reason for the statement that is the lemon juice on fish can greatly reduce odor is to be explained.
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Chapter 16 Solutions
Chemistry
Ch. 16.1 - Practice Problem ATTEMPT What is (a) the conjugate...Ch. 16.1 - Practice Problem BUILD HSO 3 − is the conjugate...Ch. 16.1 - Practice Problem CONCEPTUALIZE Which of the models...Ch. 16.1 - 16.1.1 Which of the following pairs of species are...Ch. 16.1 - Which of the following species does not have a...Ch. 16.2 - Practice Problem ATTEMPT Identify and label the...Ch. 16.2 - Practice Problem BUILD
(a) Write an equation in...Ch. 16.2 - Practice Problem CONCEPTUALIZE Write the formula...Ch. 16.2 - Calculate [ OH − ] in a solution in which [ H 3 O...Ch. 16.2 - Calculate [ H 3 O − ] in a solution in which [ OH...
Ch. 16.3 - Prob. 1PPACh. 16.3 - Practice Problem BUILD
The value of at normal...Ch. 16.3 - Prob. 1PPCCh. 16.3 - Determine the pH of a solution at 25°C in which [...Ch. 16.3 - 16.3.2 Determine in a solution at...Ch. 16.3 - Determine the pOH of a solution at 25°C in which [...Ch. 16.3 - Determine [ OH − ] in a solution at 25°C if pH =...Ch. 16.4 - Practice ProblemATTEMPT Determine the pH of a...Ch. 16.4 - Practice Problem BUILD
Determine the pH of a...Ch. 16.4 - Practice Problem CONCEPTUALIZE
Strong acid is...Ch. 16.4 - Calculate the pH of a 0.075–-M solution of...Ch. 16.4 - 16.4.2 What is the concentration of in a solution...Ch. 16.4 - 16.4.3 What is the of a solution at that is...Ch. 16.4 - What is the concentration of KOH in a solution at...Ch. 16.4 - What is the pH of a solution at 25°C that is...Ch. 16.4 - What is the concentration of Ca ( OH ) 2 in a...Ch. 16.4 - Which diagram best represents a solution of...Ch. 16.5 - Practice Problem ATTEMPT Calculate the hydronium...Ch. 16.5 - Practice Problem BUILD Calculate the hydroxide ion...Ch. 16.5 - Practice Problem CONCEPTUALIZE
What is the value...Ch. 16.5 - The K a of a weak acid is 5.5 × 10 − 4 . What is...Ch. 16.5 - A 0.042-M solution of a weak acid has pH 4.01 at...Ch. 16.5 - The diagrams show solutions of three different...Ch. 16.6 - Practice ProblemATTEMPT Determine the pOH of a...Ch. 16.6 - Practice Problem BUILD Determine the pH of a...Ch. 16.6 - Prob. 1PPCCh. 16.6 - What is the pH of a 0.63-M solution of weak base...Ch. 16.6 - A 0.12-M solution of a weak base has a pH of 10.76...Ch. 16.6 - The diagrams show solutions of three different...Ch. 16.7 - Practice Problem ATTEMPT
Calculate the hydroxide...Ch. 16.7 - Practice ProblemBUILD Calculate the hydronium ion...Ch. 16.7 - Practice ProblemCONCEPTUALIZE What is the value of...Ch. 16.7 - 16.7.1 Calculate the of the cyanide ion . (See...Ch. 16.7 - Which of the anions listed is the strongest base?...Ch. 16.7 - The diagrams show solutions of three different...Ch. 16.8 - Practice Problem ATTEMPT
Calculate the pH of an...Ch. 16.8 - Practice ProblemBUILD Calculate the pOH of an...Ch. 16.8 - Practice Problem CONCEPTUALIZE
Estimate the pH of...Ch. 16.8 - Calculate the equilibrium concentration of CO 3 2...Ch. 16.8 - What is the pH of a 0.40-M solution of phosphoric...Ch. 16.8 - List the molecular and ionic species in order of...Ch. 16.8 - Which is true for any polyprotic acid? a) K a2 > K...Ch. 16.9 - Practice Problem ATTEMPT Calculate the...Ch. 16.9 - Practice Problem BUILD Calculate the concentration...Ch. 16.9 - Practice Problem CONCEPTUALIZE
Which of the plots...Ch. 16.10 - Practice Problem ATTEMPT Calculate the pOH of the...Ch. 16.10 - Practice Problem BUILD Calculate the pH of the...Ch. 16.10 - Practice ProblemCONCEPTUALIZE Which of the...Ch. 16.10 - Calculate the pH of a 0.075-M solution of...Ch. 16.10 - Calculate the pH of a 0.082-M solution of...Ch. 16.10 - Prob. 3CPCh. 16.10 - Prob. 4CPCh. 16.10 - The diagrams represent solutions of three salts...Ch. 16.11 - Practice Problem ATTEMPT An aqueous solution of a...Ch. 16.11 - Practice Problem BUILD An aqueous solution of a...Ch. 16.11 - Practice ProblemCONCEPTUALIZE Which of the...Ch. 16.12 - Practice Problem ATTEMPT
Calculate the pH at of a...Ch. 16.12 - Practice ProblemBUILD Calculate the pH at 25°C of...Ch. 16.12 - Practice Problem CONCEPTUALIZE The diagrams show...Ch. 16.12 - 16.12.1 Which of the following cannot act as a...Ch. 16.12 - Which of the following is a Lewis acid but not a...Ch. 16.13 - Practice Problem ATTEMPT
Determine the pH and...Ch. 16.13 - Prob. 1PPBCh. 16.13 - Practice Problem CONCEPTUALIZE
Which of the...Ch. 16.14 - Practice Problem ATTEMPT
Calculate the of a weak...Ch. 16.14 - Practice Problem BUILD
Calculate the of a weak...Ch. 16.14 - Practice Problem CONCEPTUALIZE Calculate K a...Ch. 16.15 - Practice Problem ATTEMPT
Calculate the pH at of a...Ch. 16.15 - Practice ProblemBUILD Calculate the pH at 25°C of...Ch. 16.15 - Practice Problem CONCEPTUALIZE
The diagrams...Ch. 16.16 - Practice ProblemATTEMPT Determine the K b of a...Ch. 16.16 - Practice Problem BUILD
Determine the of a weak...Ch. 16.16 - Practice Problem CONCEPTUALIZE
Determine the...Ch. 16.17 - Practice Problem ATTEMPT Determine (a) K b of the...Ch. 16.17 - Practice ProblemBUILD Determine (a) K b of the...Ch. 16.17 - Practice problemCONCEPTUALIZE Fee each week acid...Ch. 16.18 - Practice Problem ATTEMPT
Calculate the...Ch. 16.18 - Practice Problem BUILD
Calculate the...Ch. 16.18 - Practice ProblemCONCEPTURALIZE Which of the...Ch. 16.19 - Practice ProblemATTEMPT Indicate which is the...Ch. 16.19 - Practice Problem BUILD
Based on the information in...Ch. 16.19 - Prob. 1PPCCh. 16.20 - Practice ProblemATTEMPT Determine the pH of a...Ch. 16.20 - Practice ProblemBUILD Determine the concentration...Ch. 16.20 - Practice ProblemCONCEPTUALIZE Which of the...Ch. 16.21 - Practice ProblemATTEMPT Determine the pH of a...Ch. 16.21 - Practice ProblemBUILD Determine the concentration...Ch. 16.21 - Practice Problem CONCEPTUALIZE
Which of the...Ch. 16.22 - Practice Problem ATTEMPT
Predict whether a 0.10-M...Ch. 16.22 - Prob. 1PPBCh. 16.22 - Prob. 1PPCCh. 16.23 - Practice ProblemATTEMPT Identify the Lewis acid...Ch. 16.23 - Practice Problem BUILD
Write formulas for the...Ch. 16.23 - Practice Problem CONCEPTUALIZE
Which of the...Ch. 16 - Calculate the pH of a solution that is 0.22 M in...Ch. 16 - 16.2 Determine pH at the equivalence point in the...Ch. 16 - Calculate the pH of a solution that is 0.22 M in...Ch. 16 - 16.4 Determine pH at the equivalence point in the...Ch. 16 - Define Brønsted acids and bases. Give an example...Ch. 16 - For a species to act as a Brønsted base, an atom...Ch. 16 - 16.3 Classify each of the following species as a...Ch. 16 - Identify the acid-base conjugate pairs in each of...Ch. 16 - 16.5 Write the formulas of the conjugate bases of...Ch. 16 - Write the formula for the conjugate acid of each...Ch. 16 - Which of the following could represent a Brønsted...Ch. 16 - 16.8 Oxalic acid has the following structure:
An...Ch. 16 - Rite the equilibrium expression for the...Ch. 16 - 16.10 In Section 15.3 we learned that when we...Ch. 16 - 16.11 The equilibrium constant for the...Ch. 16 - 16.12 Define the term amphoteric.
Ch. 16 - 16.13 Compare the magnitudes of in aqueous...Ch. 16 - Calculate the OH - concentration in an aqueous...Ch. 16 - 16.15 Calculate the concentration in an aqueous...Ch. 16 - The value of K w at 50°C is 5.48 × 10 − 14 ....Ch. 16 - The value of K w at 100°C is 5.1 × 3 10 − 13 ....Ch. 16 - Prob. 18QPCh. 16 - Prob. 19QPCh. 16 - Prob. 20QPCh. 16 - Prob. 21QPCh. 16 - Prob. 22QPCh. 16 - Calculate the concentration of OH- ions in a 1 .4...Ch. 16 - Prob. 24QPCh. 16 - 16.25 Calculate the pH of each of the following...Ch. 16 - Calculate the pH of each of the following...Ch. 16 - Prob. 27QPCh. 16 - Prob. 28QPCh. 16 - 16.29 The pOH of a solution is 9.40 at . Calculate...Ch. 16 - Prob. 30QPCh. 16 - Prob. 31QPCh. 16 - 16.32 A solution is made by dissolving 18.4 g of ...Ch. 16 - Prob. 33QPCh. 16 - Prob. 34QPCh. 16 - Prob. 35QPCh. 16 - Prob. 36QPCh. 16 - Prob. 37QPCh. 16 - Prob. 38QPCh. 16 - Prob. 39QPCh. 16 - 16.40 Calculate the concentration of in a...Ch. 16 - Calculate the concentration of HNO 3 in a solution...Ch. 16 - Prob. 42QPCh. 16 - Prob. 43QPCh. 16 - Prob. 44QPCh. 16 - Prob. 45QPCh. 16 - Explain what is meant by the strength of an acid.Ch. 16 - Prob. 47QPCh. 16 - Prob. 48QPCh. 16 - Why do we normally not quote K a values for strong...Ch. 16 - Which of the following solutions has the highest...Ch. 16 - Without referring to the text, write the formulas...Ch. 16 - In biological and medical applications, it is...Ch. 16 - 16.53 The for benzoic acid is Calculate the pH...Ch. 16 - The K a for hydrofluoric acid is 7.1 × 10 − 4 ....Ch. 16 - Calculate the pH of an aqueous solution at 25°C...Ch. 16 - Calculate the pH of an aqueous solution at 25°C...Ch. 16 - 16.57 Determine the percent ionization of the...Ch. 16 - Prob. 58QPCh. 16 - Prob. 59QPCh. 16 - Prob. 60QPCh. 16 - Calculate the K a of a weak acid if a 0.19 − M...Ch. 16 - Prob. 62QPCh. 16 - What is the original molarity of a solution of...Ch. 16 - What is the original molarity of a solution of a...Ch. 16 - 16.65 Which of the following statements are true...Ch. 16 - Prob. 66QPCh. 16 - Prob. 67QPCh. 16 - Compare the pH values for 0.10 − M solutions of...Ch. 16 - Which of the following has a higher pH: (a) 1 .0 M...Ch. 16 - Prob. 70QPCh. 16 - The pH of a 0.30-M solution of a weak base is...Ch. 16 - What is the original molarity of an aqueous...Ch. 16 - Prob. 73QPCh. 16 - Prob. 74QPCh. 16 - Prob. 75QPCh. 16 - Prob. 76QPCh. 16 - Prob. 77QPCh. 16 - Prob. 78QPCh. 16 - 16.79 Calculate for each of the following ions: ...Ch. 16 - Prob. 80QPCh. 16 - Prob. 81QPCh. 16 - Prob. 82QPCh. 16 - Prob. 83QPCh. 16 - Prob. 84QPCh. 16 - Compare the pH of a 0 .040 M HCl solution with...Ch. 16 - What are the concentrations of HSO 4, – SO 2– 4 ,...Ch. 16 - 16.87 Calculate the concentrations of
Ch. 16 - Calculate the pH at 25°C of a 0.25 − M aqueous...Ch. 16 - 16.89 Calculate the pH at of a aqueous solution...Ch. 16 - The first and second ionization constants of a...Ch. 16 - Prob. 91QPCh. 16 - Prob. 92QPCh. 16 - Prob. 93QPCh. 16 - Prob. 94QPCh. 16 - Prob. 95QPCh. 16 - Prob. 96QPCh. 16 - Prob. 97QPCh. 16 - Define salt hydrolysis. Categorize salts according...Ch. 16 - 16.99 Explain why small, highly charged metal ions...Ch. 16 - Al 3+ is not a Brønsted acid, but Al( H 2 O ) 6 3+...Ch. 16 - Specify which of the following salts will undergo...Ch. 16 - Prob. 102QPCh. 16 - Calculate the pH of a 0 .42 M NH 4 Cl solution . (...Ch. 16 - Prob. 104QPCh. 16 - Prob. 105QPCh. 16 - Prob. 106QPCh. 16 - 16.107 Predict whether the following solutions are...Ch. 16 - A certain salt, MX (containing the M + and X -...Ch. 16 - Prob. 109QPCh. 16 - Predict whether a solution containing the salt K 2...Ch. 16 - Prob. 111QPCh. 16 - Prob. 112QPCh. 16 - Prob. 113QPCh. 16 - Prob. 114QPCh. 16 - Prob. 115QPCh. 16 - Prob. 116QPCh. 16 - Prob. 117QPCh. 16 - Prob. 118QPCh. 16 - Prob. 119QPCh. 16 - Prob. 120QPCh. 16 - Prob. 121QPCh. 16 - Prob. 122QPCh. 16 - Prob. 123QPCh. 16 - Prob. 124QPCh. 16 - Identity the Lewis acid and the Lewis base in the...Ch. 16 - Predict the direction that predominates in this...Ch. 16 - Prob. 127APCh. 16 - Prob. 128APCh. 16 - Calculate the pH and percent ionization of a 0 .88...Ch. 16 - 16.130 Calculate the pH of a 0.20 M ammonium...Ch. 16 - Prob. 131APCh. 16 - Prob. 132APCh. 16 - 16.133 Like water, liquid ammonia undergoes...Ch. 16 - Prob. 134APCh. 16 - A solution contains a weak monoprotic acid HA and...Ch. 16 - Prob. 136APCh. 16 - Prob. 137APCh. 16 - Prob. 138APCh. 16 - Prob. 139APCh. 16 - A 10.0-g sample of white phosphorus was burned in...Ch. 16 - Prob. 141APCh. 16 - Prob. 142APCh. 16 - Prob. 143APCh. 16 - Prob. 144APCh. 16 - 16.145 Give an example of (a) a weak acid that...Ch. 16 - Prob. 146APCh. 16 - Prob. 147APCh. 16 - Prob. 148APCh. 16 - When chlorine reacts with water, the resulting...Ch. 16 - Prob. 150APCh. 16 - Calculate the pH of a 2 .00 M NH 4 CN solution.Ch. 16 - Calculate the concentrations of all species in a 0...Ch. 16 - Prob. 153APCh. 16 - 16.154 Calculate the concentrations of all the...Ch. 16 - Prob. 155APCh. 16 - Calculate the pH of a solution that is 1.00 M HCN...Ch. 16 - How many grams of NaCN would you need to dissolve...Ch. 16 - A solution of formic acid ( HCOOH ) has a pH of...Ch. 16 - Calculate the pH of a 1-L solution containing...Ch. 16 - 16.160 A 1.87-g sample of Mg reacts with 80.0 mL...Ch. 16 - Prob. 161APCh. 16 - Prob. 162APCh. 16 - A 0.400 M formic acid ( HCOOH ) solution freezes...Ch. 16 - Prob. 164APCh. 16 - Prob. 165APCh. 16 - Prob. 166APCh. 16 - 16.167 Both the amide ion and the nitride ion ...Ch. 16 - Determine whether each of the following statements...Ch. 16 - Prob. 169APCh. 16 - Prob. 170APCh. 16 - Prob. 171APCh. 16 - 16.172 A typical reaction between an antacid and...Ch. 16 - Prob. 173APCh. 16 - 16.174 Hemoglobin is a blood protein that is...Ch. 16 - Tooth enamel is largely hydroxyapatite [ Ca 3 ( PO...Ch. 16 - Prob. 176APCh. 16 - Prob. 177APCh. 16 - About half of the hydrochloric acid produced...Ch. 16 - Prob. 179APCh. 16 - Prob. 180APCh. 16 - Prob. 181APCh. 16 - (a) Use VSEPR to predict the geometry of the...Ch. 16 - The following questions are not based on a...Ch. 16 - The following questions are not based on a...Ch. 16 - The following questions are not based on a...Ch. 16 - The following questions are not based on a...
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- What is a salt? List some anions that behave as weak bases in water. List some anions that have no basic properties in water. List some cations that behave as weak acids in water. List some cations that have no acidic properties in water. Using these lists, give some formulas for salts that have only weak base properties in water. What strategy would you use to solve for the pH of these basic salt solutions? Identify some salts that have only weak acid properties in water. What strategy would you use to solve for the pH of these acidic salt solutions? Identify some salts that have no acidic or basic properties in water (produce neutral solutions). When a salt contains both a weak acid ion and a weak base ion, how do you predict whether the solution pH is acidic, basic, or neutral?arrow_forward. The concepts of acid-base equilibria were developed in this chapter for aqueous solutions (in aqueous solutions, water is the solvent and is intimately involved in the equilibria). However, the Brønsted-Lowry acid-base theory can be extended easily to other solvents. One such solvent that has been investigated in depth is liquid ammonia. NH3. a. Write a chemical equation indicating how HCl behaves as an acid in liquid ammonia. b. Write a chemical equation indicating how OH- behaves as a base in liquid ammonia.arrow_forwardAluminum chloride, AlCl3, reacts with trimethyl-amine, N(CH3)3. What would you guess to be the product of this reaction? Explain why you think so. Describe the reaction in terms of one of the acid base concepts. Write an appropriate equation to go with this description. Which substance is the acid according to this acidbase concept? Explain.arrow_forward
- Strong Acids, Weak Acids, and pH Two 0.10-mol samples of the hypothetical monoprotic acids HA(aq) and HB(aq) are used to prepare 1.0-L stock solutions of each acid. a Write the chemical reactions for these acids in water. What are the concentrations of the two acid solutions? b One of these acids is a strong acid, and one is weak. What could you measure that would tell you which acid was strong and which was weak? c Say that the HA(aq) solution has a pH of 3.7. Is this the stronger of the two acids? How did you arrive at your answer? d What is the concentration of A(aq) in the HA solution described in part c? e If HB(aq) is a strong acid, what is the hydronium-ion concentration? f In the solution of HB(aq), which of the following would you expect to be in the greatest concentration: H3O+(aq), B(aq), HB(aq), or OH(aq)? How did you decide? g In the solution of HA(aq), which of the following would you expect to be in the greatest concentration: H3O+(aq), A+(aq), HA(aq), or OH(aq)? How did you decide? h Say you add 1.0 L of pure water to a solution of HB. Would this water addition make the solution more acidic, make it less acidic, or not change the acidity of the original solution? Be sure to fully justify your answer. i You prepare a 1.0-L solution of HA. You then take a 200-mL sample of this solution and place it into a separate container. Would this 200 mL sample be more acidic, be less acidic, or have the same acidity as the original 1.0-L solution of HA(aq)? Be sure to support your answer.arrow_forwardEach of the following statements concerns a 0.10 M solution of a weak organic base, B. Briefly describe why each statement is either true or false. a [B] is approximately equal to 0.10 M. b [B] is much greater than [HB+]. c [H3O+] is greater than [HB+]. d The pH is 13. e [HB+] is approximately equal to [OH]. f [OH] equals 0.10 M.arrow_forwardStudents are often surprised to learn that organic acids, such as acetic acid, contain OH groups. Actually, all oxyacids contain hydroxyl groups. Sulfuric acid, usually written as H2SO4, has the structural formula SO2(OH)2, where S is the central atom. Identify the acids whose structural formulas are shown below. Why do they behave as acids, while NaOH and KOH are bases? a. SO(OH)2 b. ClO2(OH) c. HPO(OH)2arrow_forward
- A solution is prepared from 0.150 mol of formic acid and enough water to make 0.425 L of solution. a Determine the concentrations of H3O+ and HCOO in this solution. b Determine the H3O+ concentration that would be necessary to decrease the HCOO concentration above by a factor of 10. How many milliliters of 2.00 M HCl would be required to produce this solution? Consider that the solution was made by combining the HCl, the HCOOH, and enough water to make 0.425 L of solution. c Qualitatively, how can you account for the differences in the percentage dissociation of formic acid in parts a and b of this problem?arrow_forwardEstimate the pH that results when the following two solutions are mixed. a) 50 mL of 0.3 M CH3COOH and 50 mL of 0.4 M KOH b) 100 mL of 0.3 M CH3COOH and 50 mL of 0.4 M NaOH c) 150 mL of 0.3 M CH3COOH and 100 mL of 0.3 M Ba(OH)2 d) 200 mL of 0.3 M CH3COOH and 100 mL of 0.3 M Ba(OH)2arrow_forwardFor oxyacids, how does acid strength depend on a. the strength of the bond to the acidic hydrogen atom? b. the electronegativity of the element bonded to the oxygen atom that bears the acidic hydrogen? c. the number of oxygen atoms? How does the strength of a conjugate base depend on these factors? What type of solution forms when a nonmetal oxide dissolves in water? Give an example of such an oxide. What type of solution forms when a metal oxide dissolves in water? Give an example of such an oxide.arrow_forward
- Use the same symbols as in Question 61 ( = anion, =OH) for the box below. (a) Fill in a similar box (representing one liter of the same solution) after 2 mol of H+ (2) have been added. Indicate whether the resulting solution is an acid, base, or buffer. (b) Follow the directions of part (a) for the resulting solution after 2 mol of OH- (2 ) have been added. (c) Follow the directions of part (a) for the resulting solution after 5 mol of OH- (5 ) have been added. (Hint: Write the equation for the reaction before you draw the results.)arrow_forwardExplain the difference between a strong acid and a weak acid.arrow_forwardCalculate the pH of each of the following solutions. (a) 10.0 mL of 0.300 M hydrofluoric acid plus 30.0 mL of 0.100 M sodium hydroxide (b) 100.0 mL of 0.250 M ammonia plus 50.0 mL of 0.100 M hydrochloric acid (c) 25.0 mL of 0.200 M sulfuric acid plus 50.0 mL of 0.400 M sodium hydroxidearrow_forward
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