(a) Interpretation: Whether the given compound is aromatic is to be stated. Concept introduction: Aromatic compounds are those compounds which follow the Huckel’s rule of aromaticity and are planar with s p 2 hybridized atoms. According to Huckel’s rule, a compound is aromatic if the total number of electrons in the ring follows ( 4 n + 2 ) π electrons rule.

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Answer 1

Question

Chapter 16, Problem 16.5P

Interpretation Introduction

(a)

Interpretation:

Whether the given compound is aromatic is to be stated.

Concept introduction:

Aromatic compounds are those compounds which follow the Huckel’s rule of aromaticity and are planar with sp2 hybridized atoms. According to Huckel’s rule, a compound is aromatic if the total number of electrons in the ring follows (4n+2)π electrons rule.

Interpretation Introduction

(b)

Interpretation:

The two sets of resonances in NMR spectrum of the given compound are to be assigned. The explanation as to why there is difference in the chemical shifts is to be stated. Also, the explanation as to why one of the chemical shifts is so small is to be stated.

Concept introduction:

The number of NMR signal in a compound is equal to the number of chemically non-equivalent protons present in that compound. The more the shielded proton less will be its chemical shift value and the corresponding signal will be produced at the right-hand side or lower frequency region or vice versa.

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Record the amounts measured and calculate the percent yield for Part 2 in the table below. Dicyclopentadiene measured in volume Cyclopentadiene measured in grams 0 Measured Calculated Mol Yield Mass (g) or Volume (mL) Mass (g) or Volume (ml) 0.6 2.955 Part 2 Measurements and Results Record the amounts measured and calculate the percent yield for Part 2 in the table below. 0.588 0.0044 2.868 0.0434 N/A Table view List view Measured Calculated Mol $ Yield Melting Point (C) Mass (g) or Volume (ml) Mass (g) or Volume (ml.) Cyclopentadiene 0.1 0.08 0.001189 measured in volume Maleic Anhydride 0.196 N/A cis-norbornene-5,6-endo- dicarboxylic anhydride 0.041 0.0002467 N/A N/A N/A 0.002 N/A N/A 128

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Answer 2

Question

Chapter 16, Problem 16.5P

Interpretation Introduction

(a)

Interpretation:

Whether the given compound is aromatic is to be stated.

Concept introduction:

Aromatic compounds are those compounds which follow the Huckel’s rule of aromaticity and are planar with sp2 hybridized atoms. According to Huckel’s rule, a compound is aromatic if the total number of electrons in the ring follows (4n+2)π electrons rule.

Interpretation Introduction

(b)

Interpretation:

The two sets of resonances in NMR spectrum of the given compound are to be assigned. The explanation as to why there is difference in the chemical shifts is to be stated. Also, the explanation as to why one of the chemical shifts is so small is to be stated.

Concept introduction:

The number of NMR signal in a compound is equal to the number of chemically non-equivalent protons present in that compound. The more the shielded proton less will be its chemical shift value and the corresponding signal will be produced at the right-hand side or lower frequency region or vice versa.

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Answer 3

Question

Chapter 16, Problem 16.5P

Interpretation Introduction

(a)

Interpretation:

Whether the given compound is aromatic is to be stated.

Concept introduction:

Aromatic compounds are those compounds which follow the Huckel’s rule of aromaticity and are planar with sp2 hybridized atoms. According to Huckel’s rule, a compound is aromatic if the total number of electrons in the ring follows (4n+2)π electrons rule.

Interpretation Introduction

(b)

Interpretation:

The two sets of resonances in NMR spectrum of the given compound are to be assigned. The explanation as to why there is difference in the chemical shifts is to be stated. Also, the explanation as to why one of the chemical shifts is so small is to be stated.

Concept introduction:

The number of NMR signal in a compound is equal to the number of chemically non-equivalent protons present in that compound. The more the shielded proton less will be its chemical shift value and the corresponding signal will be produced at the right-hand side or lower frequency region or vice versa.

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Answer 4

Question

Chapter 16, Problem 16.5P

Interpretation Introduction

(a)

Interpretation:

Whether the given compound is aromatic is to be stated.

Concept introduction:

Aromatic compounds are those compounds which follow the Huckel’s rule of aromaticity and are planar with sp2 hybridized atoms. According to Huckel’s rule, a compound is aromatic if the total number of electrons in the ring follows (4n+2)π electrons rule.

Interpretation Introduction

(b)

Interpretation:

The two sets of resonances in NMR spectrum of the given compound are to be assigned. The explanation as to why there is difference in the chemical shifts is to be stated. Also, the explanation as to why one of the chemical shifts is so small is to be stated.

Concept introduction:

The number of NMR signal in a compound is equal to the number of chemically non-equivalent protons present in that compound. The more the shielded proton less will be its chemical shift value and the corresponding signal will be produced at the right-hand side or lower frequency region or vice versa.

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Answer 5

Chapter 16, Problem 16.5P

Interpretation Introduction

(a)

Interpretation:

Whether the given compound is aromatic is to be stated.

Concept introduction:

Aromatic compounds are those compounds which follow the Huckel’s rule of aromaticity and are planar with sp2 hybridized atoms. According to Huckel’s rule, a compound is aromatic if the total number of electrons in the ring follows (4n+2)π electrons rule.

Interpretation Introduction

(b)

Interpretation:

The two sets of resonances in NMR spectrum of the given compound are to be assigned. The explanation as to why there is difference in the chemical shifts is to be stated. Also, the explanation as to why one of the chemical shifts is so small is to be stated.

Concept introduction:

The number of NMR signal in a compound is equal to the number of chemically non-equivalent protons present in that compound. The more the shielded proton less will be its chemical shift value and the corresponding signal will be produced at the right-hand side or lower frequency region or vice versa.

Answer 6

Chapter 16, Problem 16.5P

Interpretation Introduction

(a)

Interpretation:

Whether the given compound is aromatic is to be stated.

Concept introduction:

Aromatic compounds are those compounds which follow the Huckel’s rule of aromaticity and are planar with sp2 hybridized atoms. According to Huckel’s rule, a compound is aromatic if the total number of electrons in the ring follows (4n+2)π electrons rule.

Answer 7

Chapter 16, Problem 16.5P

Interpretation Introduction

(a)

Interpretation:

Whether the given compound is aromatic is to be stated.

Concept introduction:

Aromatic compounds are those compounds which follow the Huckel’s rule of aromaticity and are planar with sp2 hybridized atoms. According to Huckel’s rule, a compound is aromatic if the total number of electrons in the ring follows (4n+2)π electrons rule.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The two sets of resonances in NMR spectrum of the given compound are to be assigned. The explanation as to why there is difference in the chemical shifts is to be stated. Also, the explanation as to why one of the chemical shifts is so small is to be stated.

Concept introduction:

The number of NMR signal in a compound is equal to the number of chemically non-equivalent protons present in that compound. The more the shielded proton less will be its chemical shift value and the corresponding signal will be produced at the right-hand side or lower frequency region or vice versa.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The two sets of resonances in NMR spectrum of the given compound are to be assigned. The explanation as to why there is difference in the chemical shifts is to be stated. Also, the explanation as to why one of the chemical shifts is so small is to be stated.

Concept introduction:

The number of NMR signal in a compound is equal to the number of chemically non-equivalent protons present in that compound. The more the shielded proton less will be its chemical shift value and the corresponding signal will be produced at the right-hand side or lower frequency region or vice versa.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 16 - Prob. 16.1P Ch. 16 - Prob. 16.2P Ch. 16 - Prob. 16.3P Ch. 16 - Prob. 16.4P Ch. 16 - Prob. 16.5P Ch. 16 - Prob. 16.6P Ch. 16 - Prob. 16.7P Ch. 16 - Prob. 16.8P Ch. 16 - Prob. 16.9P Ch. 16 - Prob. 16.10P

Solution Summary: The author explains that aromatic compounds follow the Huckel's rule of aromaticity and are planar with sp2 hybridized atoms.

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