(a) Interpretation: The predominant product that is obtained from the monosulfonation of m − bromotoluene is to be predicted. Concept introduction: The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

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Answer 1

Question

Chapter 16, Problem 16.30P

Interpretation Introduction

(a)

Interpretation:

The predominant product that is obtained from the monosulfonation of m−bromotoluene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

Interpretation Introduction

(b)

Interpretation:

The predominant product that is obtained from the mononitration of m−bromoiodobenzene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a nitro group takes place is known as nitration reaction. In this reaction, an aromatic compound is treated with concentrated sulfuric acid and nitric acid to form a nitro compound.

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Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)

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Answer 2

Question

Chapter 16, Problem 16.30P

Interpretation Introduction

(a)

Interpretation:

The predominant product that is obtained from the monosulfonation of m−bromotoluene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

Interpretation Introduction

(b)

Interpretation:

The predominant product that is obtained from the mononitration of m−bromoiodobenzene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a nitro group takes place is known as nitration reaction. In this reaction, an aromatic compound is treated with concentrated sulfuric acid and nitric acid to form a nitro compound.

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Answer 3

Question

Chapter 16, Problem 16.30P

Interpretation Introduction

(a)

Interpretation:

The predominant product that is obtained from the monosulfonation of m−bromotoluene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

Interpretation Introduction

(b)

Interpretation:

The predominant product that is obtained from the mononitration of m−bromoiodobenzene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a nitro group takes place is known as nitration reaction. In this reaction, an aromatic compound is treated with concentrated sulfuric acid and nitric acid to form a nitro compound.

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Answer 4

Question

Chapter 16, Problem 16.30P

Interpretation Introduction

(a)

Interpretation:

The predominant product that is obtained from the monosulfonation of m−bromotoluene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

Interpretation Introduction

(b)

Interpretation:

The predominant product that is obtained from the mononitration of m−bromoiodobenzene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a nitro group takes place is known as nitration reaction. In this reaction, an aromatic compound is treated with concentrated sulfuric acid and nitric acid to form a nitro compound.

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Answer 5

Chapter 16, Problem 16.30P

Interpretation Introduction

(a)

Interpretation:

The predominant product that is obtained from the monosulfonation of m−bromotoluene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

Interpretation Introduction

(b)

Interpretation:

The predominant product that is obtained from the mononitration of m−bromoiodobenzene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a nitro group takes place is known as nitration reaction. In this reaction, an aromatic compound is treated with concentrated sulfuric acid and nitric acid to form a nitro compound.

Answer 6

Chapter 16, Problem 16.30P

Interpretation Introduction

(a)

Interpretation:

The predominant product that is obtained from the monosulfonation of m−bromotoluene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

Answer 7

Chapter 16, Problem 16.30P

Interpretation Introduction

(a)

Interpretation:

The predominant product that is obtained from the monosulfonation of m−bromotoluene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The predominant product that is obtained from the mononitration of m−bromoiodobenzene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a nitro group takes place is known as nitration reaction. In this reaction, an aromatic compound is treated with concentrated sulfuric acid and nitric acid to form a nitro compound.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The predominant product that is obtained from the mononitration of m−bromoiodobenzene is to be predicted.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a nitro group takes place is known as nitration reaction. In this reaction, an aromatic compound is treated with concentrated sulfuric acid and nitric acid to form a nitro compound.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 16 - Prob. 16.1P Ch. 16 - Prob. 16.2P Ch. 16 - Prob. 16.3P Ch. 16 - Prob. 16.4P Ch. 16 - Prob. 16.5P Ch. 16 - Prob. 16.6P Ch. 16 - Prob. 16.7P Ch. 16 - Prob. 16.8P Ch. 16 - Prob. 16.9P Ch. 16 - Prob. 16.10P

Solution Summary: The author explains that the predominant product obtained from the monosulfonation of m-bromotoluene is to be predicted.

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Chapter 16 Solutions