
Chemistry for Today: General, Organic, and Biochemistry
9th Edition
ISBN: 9781305960060
Author: Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher: Cengage Learning
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Question
Chapter 16, Problem 16.5E
Interpretation Introduction
Interpretation:
The structural formulas of all
Concept introduction:
Amines are nitrogen-containing organic compounds. The general formula of amines is
In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.
In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.
In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.
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Identify the missing organic reactant in the following reaction:
x + x
O OH
H*
+ ☑-
X
H+
O O
Х
Note: This chemical equation only focuses on the important organic molecules in the reaction. Additional inorganic or small-molecule reactants or products
(like H₂O) are not shown.
In the drawing area below, draw the skeletal ("line") structure of the missing organic reactant X.
Click and drag to start drawing a
structure.
C
CH3O
OH
OH
O hemiacetal
O acetal
O neither
O
0
O hemiacetal
acetal
neither
OH
hemiacetal
O acetal
O neither
CH2 O-CH2-CH3
CH3-C-OH
O hemiacetal
O acetal
CH3-CH2-CH2-0-c-O-CH2-CH2-CH3 O neither
HO-CH2
?
000
Ar
B
What would be the best choices for the missing reagents 1 and 3 in this synthesis?
1. PPh3
2
2. n-BuLi
3
Draw the missing reagents in the drawing area below. You can draw them in any arrangement you like.
• Do not draw the missing reagent 2. If you draw 1 correctly, we'll know what it is.
• Note: if one of your reagents needs to contain a halogen, use bromine.
Explanation
Check
Click and drag to start drawing a structure.
Chapter 16 Solutions
Chemistry for Today: General, Organic, and Biochemistry
Ch. 16 - Prob. 16.1ECh. 16 - Prob. 16.2ECh. 16 - Prob. 16.3ECh. 16 - Prob. 16.4ECh. 16 - Prob. 16.5ECh. 16 - Prob. 16.6ECh. 16 - Prob. 16.7ECh. 16 - Prob. 16.8ECh. 16 - Give each of the following amines an IUPAC name:...Ch. 16 - Give each of the following amines an IUPAC name....
Ch. 16 - Prob. 16.11ECh. 16 - Prob. 16.12ECh. 16 - Prob. 16.13ECh. 16 - Prob. 16.14ECh. 16 - Prob. 16.15ECh. 16 - Prob. 16.16ECh. 16 - Prob. 16.17ECh. 16 - Prob. 16.18ECh. 16 - Prob. 16.19ECh. 16 - Draw diagrams similar to Figure 16.1 to illustrate...Ch. 16 - Prob. 16.21ECh. 16 - Prob. 16.22ECh. 16 - Prob. 16.23ECh. 16 - Prob. 16.24ECh. 16 - Prob. 16.25ECh. 16 - Prob. 16.26ECh. 16 - Prob. 16.27ECh. 16 - Prob. 16.28ECh. 16 - Prob. 16.29ECh. 16 - Prob. 16.30ECh. 16 - Prob. 16.31ECh. 16 - Prob. 16.32ECh. 16 - Prob. 16.33ECh. 16 - Describe the general structure of a neuron.Ch. 16 - Name the two amino acids that are starting...Ch. 16 - Prob. 16.36ECh. 16 - Prob. 16.37ECh. 16 - Prob. 16.38ECh. 16 - Prob. 16.39ECh. 16 - Prob. 16.40ECh. 16 - Prob. 16.41ECh. 16 - Prob. 16.42ECh. 16 - Why are alkaloids weakly basic?Ch. 16 - Prob. 16.44ECh. 16 - Prob. 16.45ECh. 16 - Prob. 16.46ECh. 16 - Prob. 16.47ECh. 16 - Prob. 16.48ECh. 16 - Prob. 16.49ECh. 16 - Prob. 16.50ECh. 16 - Prob. 16.51ECh. 16 - Complete the following reactions: a. b.Ch. 16 - Complete the following reactions: a. b.Ch. 16 - Prob. 16.54ECh. 16 - What are the products of the acid hydrolysis of...Ch. 16 - Prob. 16.56ECh. 16 - Prob. 16.57ECh. 16 - Prob. 16.58ECh. 16 - Prob. 16.59ECh. 16 - Prob. 16.60ECh. 16 - Prob. 16.61ECh. 16 - Prob. 16.62ECh. 16 - Prob. 16.63ECh. 16 - Prob. 16.64ECh. 16 - Prob. 16.65ECh. 16 - Prob. 16.66ECh. 16 - Prob. 16.67ECh. 16 - Prob. 16.68ECh. 16 - Prob. 16.69ECh. 16 - Prob. 16.70ECh. 16 - Prob. 16.71ECh. 16 - The stimulant in coffee is: a. tannic acid b....Ch. 16 - What are the most likely products of a reaction...
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