Chemistry for Today: General, Organic, and Biochemistry
9th Edition
ISBN: 9781305960060
Author: Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher: Cengage Learning
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Question
Chapter 16, Problem 16.51E
Interpretation Introduction
Interpretation:
The reason as to why the boiling points of disubstituted amides are lower than those of unsubstituted amides is to be stated.
Concept introduction:
The hydrogen bonding is formed between the electronegative atoms that are already bonded to hydrogen atoms. Mono and unsubstituted amides can form hydrogen bonding with other amides as they have hydrogen atom. Disubstituted amides can form hydrogen bonding only with water.
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Chapter 16 Solutions
Chemistry for Today: General, Organic, and Biochemistry
Ch. 16 - Prob. 16.1ECh. 16 - Prob. 16.2ECh. 16 - Prob. 16.3ECh. 16 - Prob. 16.4ECh. 16 - Prob. 16.5ECh. 16 - Prob. 16.6ECh. 16 - Prob. 16.7ECh. 16 - Prob. 16.8ECh. 16 - Give each of the following amines an IUPAC name:...Ch. 16 - Give each of the following amines an IUPAC name....
Ch. 16 - Prob. 16.11ECh. 16 - Prob. 16.12ECh. 16 - Prob. 16.13ECh. 16 - Prob. 16.14ECh. 16 - Prob. 16.15ECh. 16 - Prob. 16.16ECh. 16 - Prob. 16.17ECh. 16 - Prob. 16.18ECh. 16 - Prob. 16.19ECh. 16 - Draw diagrams similar to Figure 16.1 to illustrate...Ch. 16 - Prob. 16.21ECh. 16 - Prob. 16.22ECh. 16 - Prob. 16.23ECh. 16 - Prob. 16.24ECh. 16 - Prob. 16.25ECh. 16 - Prob. 16.26ECh. 16 - Prob. 16.27ECh. 16 - Prob. 16.28ECh. 16 - Prob. 16.29ECh. 16 - Prob. 16.30ECh. 16 - Prob. 16.31ECh. 16 - Prob. 16.32ECh. 16 - Prob. 16.33ECh. 16 - Describe the general structure of a neuron.Ch. 16 - Name the two amino acids that are starting...Ch. 16 - Prob. 16.36ECh. 16 - Prob. 16.37ECh. 16 - Prob. 16.38ECh. 16 - Prob. 16.39ECh. 16 - Prob. 16.40ECh. 16 - Prob. 16.41ECh. 16 - Prob. 16.42ECh. 16 - Why are alkaloids weakly basic?Ch. 16 - Prob. 16.44ECh. 16 - Prob. 16.45ECh. 16 - Prob. 16.46ECh. 16 - Prob. 16.47ECh. 16 - Prob. 16.48ECh. 16 - Prob. 16.49ECh. 16 - Prob. 16.50ECh. 16 - Prob. 16.51ECh. 16 - Complete the following reactions: a. b.Ch. 16 - Complete the following reactions: a. b.Ch. 16 - Prob. 16.54ECh. 16 - What are the products of the acid hydrolysis of...Ch. 16 - Prob. 16.56ECh. 16 - Prob. 16.57ECh. 16 - Prob. 16.58ECh. 16 - Prob. 16.59ECh. 16 - Prob. 16.60ECh. 16 - Prob. 16.61ECh. 16 - Prob. 16.62ECh. 16 - Prob. 16.63ECh. 16 - Prob. 16.64ECh. 16 - Prob. 16.65ECh. 16 - Prob. 16.66ECh. 16 - Prob. 16.67ECh. 16 - Prob. 16.68ECh. 16 - Prob. 16.69ECh. 16 - Prob. 16.70ECh. 16 - Prob. 16.71ECh. 16 - The stimulant in coffee is: a. tannic acid b....Ch. 16 - What are the most likely products of a reaction...
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- Give each of the following amines an IUPAC name: a. b. c.arrow_forwardThe presence of amides in living organisms is beneficial due its stability which results from being the least reactive carboxylic acid derivative. True or Falsearrow_forwardExplain why many amines with useful medicinal properties are sold as their ammonium saltsarrow_forward
- Account for the fact that most low-molecular-weight amines are very soluble in water, whereas low- molecular-weight hydrocarbons are not.arrow_forwardSynthadotin is a promising anticancer drug in clinical trials. (see attachment) Question: Classify any amine or amide as 1°, 2°, or 3°.arrow_forwardAlthough penicillin G has two amide functional groups, one is muchmore reactive than the other. Which amide is more reactive and why?arrow_forward
- The compound is classified as a O quaternary amine hydrated amine secondary amine tertiary amine primary amine HINarrow_forwardPrimary and secondary amines exhibit hydrogen bonding; tertiary amines do not. Explain.arrow_forwardClassify the amides in dolastatin, an anticancer compound isolated from the Indian seahare Dolabella auricularia, as 1 °, 2°, or 3°.arrow_forward
- Differentiate the physical properties of amides from aminesarrow_forwardN-Methylpyrrolidine has a boiling point of 81 °C, and piperidine has a boiling point of 106 °C. Tetrahydropyran has a boiling point of 88 °C, and cyclopentanone has a boiling point of 141 °C. These two isomershave a boiling point difference of 53 °C. Explain why the two oxygen-containing isomers have a much larger boilingpoint difference than the two amine isomersarrow_forwardClassify each amine in the following compounds as 1°, 2°, or 3°.arrow_forward
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