(a)
Interpretation: The products formed for the given Diels-Alder reaction are to be drawn.
Concept introduction: Diels-alder reaction is a cycloaddition reaction in which two molecules combine to form a new ring. In this type of reaction, syn addition takes place. It is a reaction between diene with a dienophile to yield a cyclohexene. The dienophile adds to one side of the diene, and diene adds to the one side of the dienophile. Thus, they have syn stereochemistry.
Answer to Problem 16.50P
The products formed by the given Diels-Alder reaction are shown below.
Explanation of Solution
The given reaction is shown below.
Figure 1
Diels-alder reaction is a cycloaddition reaction in which two molecules combine to form a new ring. In this type of reaction, syn addition takes place. It is a reaction between diene with a dienophile to yield a cyclohexene. The dienophile adds to one side of the diene, and diene adds to the one side of the dienophile. Thus, they have syn stereochemistry.
The products formed by the given Diels-Alder reaction are shown below
Figure 2
The products formed for the given Diels-Alder reaction is shown in Figure 2.
(b)
Interpretation: The products formed for the given Diels-Alder reaction are to be drawn.
Concept introduction: Diels-alder reaction is a cycloaddition reaction in which two molecules combine to form a new ring. In this type of reaction, syn addition takes place. It is a reaction between diene with a dienophile to yield a cyclohexene. The dienophile adds to one side of the diene, and diene adds to the one side of the dienophile. Thus, they have syn stereochemistry.
Answer to Problem 16.50P
The products formed by the given Diels-Alder reaction are shown below.
Explanation of Solution
Diels-alder reaction is a cycloaddition reaction in which two molecules combine to form a new ring. In this type of reaction, syn addition takes place. It is a reaction between diene with a dienophile to yield a cyclohexene. The dienophile adds to one side of the diene, and diene adds to the one side of the dienophile. Thus, they have syn stereochemistry.
The products formed by the given Diels-Alder reaction are shown below
Figure 4
The products formed for the given Diels-Alder reaction is shown in Figure 4.
(c)
Interpretation: The products formed for the given Diels-Alder reaction are to be drawn.
Concept introduction: Diels-alder reaction is a cycloaddition reaction in which two molecules combine to form a new ring. In this type of reaction, syn addition takes place. It is a reaction between diene with a dienophile to yield a cyclohexene.
Answer to Problem 16.50P
The products formed by the given Diels-Alder reaction are shown below.
Explanation of Solution
The given reaction is shown below.
Figure 5
Diels-alder reaction is a cycloaddition reaction in which two molecules combine to form a new ring. In this type of reaction, syn addition takes place. It is a reaction between diene with a dienophile to yield a cyclohexene. The dienophile adds to one side of the diene, and diene adds to the one side of the dienophile. Thus, they have syn stereochemistry.
Therefore, the product formed for the given Diels-Alder reaction is shown below.
Figure 6
The product formed for the given Diels-Alder reaction is shown in Figure 6.
(d)
Interpretation: The product formed for the given Diels-Alder reaction is to be drawn.
Concept introduction: Diels-alder reaction is a cycloaddition reaction in which two molecules combine to form a new ring. In this type of reaction, syn addition takes place. It is a reaction between diene with a dienophile to yield a cyclohexene. The dienophile adds to one side of the diene, and diene adds to the one side of the dienophile. Thus, they have syn stereochemistry.
Answer to Problem 16.50P
The product formed for the given Diels-Alder reaction is shown below.
Explanation of Solution
The given reaction is shown below.
Figure 7
Diels-alder reaction is a cycloaddition reaction in which two molecules combine to form a new ring. In this type of reaction, syn addition takes place. It is a reaction between diene with a dienophile to yield a cyclohexene. The dienophile adds to one side of the diene, and diene adds to the one side of the dienophile. Thus, they have syn stereochemistry.
Therefore, the product formed for the given Diels-Alder reaction is shown below.
Figure 8
The product formed for the given Diels-Alder reaction is shown in Figure 8.
(e)
Interpretation: The product formed for the given Diels-Alder reaction is to be drawn.
Concept introduction: Diels-alder reaction is a cycloaddition reaction in which two molecules combine to form a new ring. In this type of reaction, syn addition takes place. It is a reaction between diene with a dienophile to yield a cyclohexene. The dienophile adds to one side of the diene, and diene adds to the one side of the dienophile. Thus, they have syn stereochemistry.
Answer to Problem 16.50P
The product formed for the given Diels-Alder reaction is shown below.
Explanation of Solution
The given reaction is shown below.
Figure 9
Diels-alder reaction is a cycloaddition reaction in which two molecules combine to form a new ring. In this type of reaction, syn addition takes place. It is a reaction between diene with a dienophile to yield a cyclohexene. The dienophile adds to one side of the diene, and diene adds to the one side of the dienophile. Thus, they have syn stereochemistry.
The product formed for the given Diels-Alder reaction is shown below.
Figure 10
The products formed for the given Diels-Alder reaction are shown in Figure 10.
(f)
Interpretation: The product formed for the given Diels-Alder reaction is to be drawn.
Concept introduction: Diels-alder reaction is a cycloaddition reaction in which two molecules combine to form a new ring. In this type of reaction, syn addition takes place. It is a reaction between diene with a dienophile to yield a cyclohexene. The dienophile adds to one side of the diene, and diene adds to the one side of the dienophile. Thus, they have syn stereochemistry.
Answer to Problem 16.50P
The product formed for the given Diels-Alder reaction is shown below.
Explanation of Solution
The given reaction is shown below.
Figure 11
Diels-alder reaction is a cycloaddition reaction in which two molecules combine to form a new ring. In this type of reaction, syn addition takes place. It is a reaction between diene with a dienophile to yield a cyclohexene. The dienophile adds to one side of the diene, and diene adds to the one side of the dienophile. Thus, they have syn stereochemistry.
The product formed for the given Diels-Alder reaction is shown below.
Figure 12
The products formed for the given Diels-Alder reaction are shown in Figure 12.
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Chapter 16 Solutions
Organic Chemistry
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