(a) Interpretation: The diene that has the larger heat of hydrogenation is to be identified. Concept introduction: Diene is a hydrocarbon that contains two C = C double bonds in a compound. Conjugated diene consists of two double bonds that are separated by a single bond, whereas isolated diene also consists of two double bond but they are separated by two more carbon atoms. The example that shows the basic difference between conjugated diene and isolated diene is shown below. Figure 1 The stability of conjugated diene is more than isolated diene. Due to which the heat of hydrogenation is smaller for conjugated diene, whereas heat of hydrogenation for isolated diene is larger.

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Answer 1

Question

Chapter 16, Problem 16.13P

Interpretation Introduction

(a)

Interpretation: The diene that has the larger heat of hydrogenation is to be identified.

Concept introduction: Diene is a hydrocarbon that contains two C=C double bonds in a compound.

Conjugated diene consists of two double bonds that are separated by a single bond, whereas isolated diene also consists of two double bond but they are separated by two more carbon atoms.

The example that shows the basic difference between conjugated diene and isolated diene is shown below.

Figure 1

The stability of conjugated diene is more than isolated diene. Due to which the heat of hydrogenation is smaller for conjugated diene, whereas heat of hydrogenation for isolated diene is larger.

Interpretation Introduction

(b)

Interpretation: The diene that has the larger heat of hydrogenation is to be identified.

Concept introduction: Diene is a hydrocarbon that contains two C=C double bonds in a compound.

Conjugated diene consists of two double bonds that are separated by a single bond, whereas isolated diene also consists of two double bond but they are separated by two more carbon atoms.

The example that shows the basic difference between conjugated diene and isolated diene is shown below.

Figure 1

The stability of conjugated diene is more than isolated diene. Due to which the heat of hydrogenation is smaller for conjugated diene, whereas heat of hydrogenation for isolated diene is larger.

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Label each diene as reactive or unreactive in a Diels–Alder reaction.

What diene and dienophile are needed to prepare each Diels–Alder product?

Which compound would be the least likely to react as a diene in a Diels- Alder Reaction? A. B. C. D.

Answer 2

Question

Chapter 16, Problem 16.13P

Interpretation Introduction

(a)

Interpretation: The diene that has the larger heat of hydrogenation is to be identified.

Concept introduction: Diene is a hydrocarbon that contains two C=C double bonds in a compound.

Conjugated diene consists of two double bonds that are separated by a single bond, whereas isolated diene also consists of two double bond but they are separated by two more carbon atoms.

The example that shows the basic difference between conjugated diene and isolated diene is shown below.

Figure 1

The stability of conjugated diene is more than isolated diene. Due to which the heat of hydrogenation is smaller for conjugated diene, whereas heat of hydrogenation for isolated diene is larger.

Interpretation Introduction

(b)

Interpretation: The diene that has the larger heat of hydrogenation is to be identified.

Concept introduction: Diene is a hydrocarbon that contains two C=C double bonds in a compound.

Conjugated diene consists of two double bonds that are separated by a single bond, whereas isolated diene also consists of two double bond but they are separated by two more carbon atoms.

The example that shows the basic difference between conjugated diene and isolated diene is shown below.

Figure 1

The stability of conjugated diene is more than isolated diene. Due to which the heat of hydrogenation is smaller for conjugated diene, whereas heat of hydrogenation for isolated diene is larger.

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Answer 3

Question

Chapter 16, Problem 16.13P

Interpretation Introduction

(a)

Interpretation: The diene that has the larger heat of hydrogenation is to be identified.

Concept introduction: Diene is a hydrocarbon that contains two C=C double bonds in a compound.

Conjugated diene consists of two double bonds that are separated by a single bond, whereas isolated diene also consists of two double bond but they are separated by two more carbon atoms.

The example that shows the basic difference between conjugated diene and isolated diene is shown below.

Figure 1

The stability of conjugated diene is more than isolated diene. Due to which the heat of hydrogenation is smaller for conjugated diene, whereas heat of hydrogenation for isolated diene is larger.

Interpretation Introduction

(b)

Interpretation: The diene that has the larger heat of hydrogenation is to be identified.

Concept introduction: Diene is a hydrocarbon that contains two C=C double bonds in a compound.

Conjugated diene consists of two double bonds that are separated by a single bond, whereas isolated diene also consists of two double bond but they are separated by two more carbon atoms.

The example that shows the basic difference between conjugated diene and isolated diene is shown below.

Figure 1

The stability of conjugated diene is more than isolated diene. Due to which the heat of hydrogenation is smaller for conjugated diene, whereas heat of hydrogenation for isolated diene is larger.

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Answer 4

Question

Chapter 16, Problem 16.13P

Interpretation Introduction

(a)

Interpretation: The diene that has the larger heat of hydrogenation is to be identified.

Concept introduction: Diene is a hydrocarbon that contains two C=C double bonds in a compound.

Conjugated diene consists of two double bonds that are separated by a single bond, whereas isolated diene also consists of two double bond but they are separated by two more carbon atoms.

The example that shows the basic difference between conjugated diene and isolated diene is shown below.

Figure 1

The stability of conjugated diene is more than isolated diene. Due to which the heat of hydrogenation is smaller for conjugated diene, whereas heat of hydrogenation for isolated diene is larger.

Interpretation Introduction

(b)

Interpretation: The diene that has the larger heat of hydrogenation is to be identified.

Concept introduction: Diene is a hydrocarbon that contains two C=C double bonds in a compound.

Conjugated diene consists of two double bonds that are separated by a single bond, whereas isolated diene also consists of two double bond but they are separated by two more carbon atoms.

The example that shows the basic difference between conjugated diene and isolated diene is shown below.

Figure 1

The stability of conjugated diene is more than isolated diene. Due to which the heat of hydrogenation is smaller for conjugated diene, whereas heat of hydrogenation for isolated diene is larger.

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Answer 5

Chapter 16, Problem 16.13P

Interpretation Introduction

(a)

Interpretation: The diene that has the larger heat of hydrogenation is to be identified.

Concept introduction: Diene is a hydrocarbon that contains two C=C double bonds in a compound.

Conjugated diene consists of two double bonds that are separated by a single bond, whereas isolated diene also consists of two double bond but they are separated by two more carbon atoms.

The example that shows the basic difference between conjugated diene and isolated diene is shown below.

Figure 1

The stability of conjugated diene is more than isolated diene. Due to which the heat of hydrogenation is smaller for conjugated diene, whereas heat of hydrogenation for isolated diene is larger.

Interpretation Introduction

(b)

Interpretation: The diene that has the larger heat of hydrogenation is to be identified.

Concept introduction: Diene is a hydrocarbon that contains two C=C double bonds in a compound.

Conjugated diene consists of two double bonds that are separated by a single bond, whereas isolated diene also consists of two double bond but they are separated by two more carbon atoms.

The example that shows the basic difference between conjugated diene and isolated diene is shown below.

Figure 1

The stability of conjugated diene is more than isolated diene. Due to which the heat of hydrogenation is smaller for conjugated diene, whereas heat of hydrogenation for isolated diene is larger.

Answer 6

Chapter 16, Problem 16.13P

Interpretation Introduction

(a)

Interpretation: The diene that has the larger heat of hydrogenation is to be identified.

Concept introduction: Diene is a hydrocarbon that contains two C=C double bonds in a compound.

Conjugated diene consists of two double bonds that are separated by a single bond, whereas isolated diene also consists of two double bond but they are separated by two more carbon atoms.

The example that shows the basic difference between conjugated diene and isolated diene is shown below.

Figure 1

The stability of conjugated diene is more than isolated diene. Due to which the heat of hydrogenation is smaller for conjugated diene, whereas heat of hydrogenation for isolated diene is larger.

Answer 7

Chapter 16, Problem 16.13P

Interpretation Introduction

(a)

Interpretation: The diene that has the larger heat of hydrogenation is to be identified.

Concept introduction: Diene is a hydrocarbon that contains two C=C double bonds in a compound.

Conjugated diene consists of two double bonds that are separated by a single bond, whereas isolated diene also consists of two double bond but they are separated by two more carbon atoms.

The example that shows the basic difference between conjugated diene and isolated diene is shown below.

Figure 1

The stability of conjugated diene is more than isolated diene. Due to which the heat of hydrogenation is smaller for conjugated diene, whereas heat of hydrogenation for isolated diene is larger.

Answer 8

Interpretation Introduction

(b)

Interpretation: The diene that has the larger heat of hydrogenation is to be identified.

Concept introduction: Diene is a hydrocarbon that contains two C=C double bonds in a compound.

Conjugated diene consists of two double bonds that are separated by a single bond, whereas isolated diene also consists of two double bond but they are separated by two more carbon atoms.

The example that shows the basic difference between conjugated diene and isolated diene is shown below.

Figure 1

The stability of conjugated diene is more than isolated diene. Due to which the heat of hydrogenation is smaller for conjugated diene, whereas heat of hydrogenation for isolated diene is larger.

Answer 9

Interpretation Introduction

(b)

Interpretation: The diene that has the larger heat of hydrogenation is to be identified.

Concept introduction: Diene is a hydrocarbon that contains two C=C double bonds in a compound.

Conjugated diene consists of two double bonds that are separated by a single bond, whereas isolated diene also consists of two double bond but they are separated by two more carbon atoms.

The example that shows the basic difference between conjugated diene and isolated diene is shown below.

Figure 1

The stability of conjugated diene is more than isolated diene. Due to which the heat of hydrogenation is smaller for conjugated diene, whereas heat of hydrogenation for isolated diene is larger.

Answer 10

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Answer 11

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Answer 12

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Answer 13

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Solution Summary: The author explains that the diene that has the larger heat of hydrogenation is shown in Figure 4.

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