Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
expand_more
expand_more
format_list_bulleted
Question
Chapter 16, Problem 16.34E
Interpretation Introduction
Interpretation:
Among the given species, those atoms that are the present in the radical that can be split into six lines of equal intensity are to be identified.
Concept Introduction:
The full form of ESR spectroscopy is electron-spin resonance spectroscopy. The ESR spectroscopy is used to observe those materials which contain unpaired electrons. ESR spectroscopy also works like NMR spectroscopy, but, in ESR, electron spin in spite of atomic nuclei spin gets excited.
Expert Solution & Answer
Trending nowThis is a popular solution!
Students have asked these similar questions
How can i calculate value of nuclear spin(I)?
Why 11B’s I is 3/2 ?
Compare the total Coulomb repulsion energy between protons for 4He, 40Ca, and 208Pb. Assume the protons in 4He are, on the average, a distance equal to the nuclear radius apart and use Equation for the Coulomb repulsion of the larger nuclei.
The spin quantum number of a nitrogen-14 nucleus isI= 1. What would be the nuclear magnetic resonance spectrum for a proton resonance line that was split by interactionwith (a) two. (b) three equivalent nitrogen-14 nuclei?
Chapter 16 Solutions
Physical Chemistry
Ch. 16 - Prob. 16.1ECh. 16 - Prob. 16.2ECh. 16 - Prob. 16.3ECh. 16 - Prob. 16.4ECh. 16 - Prob. 16.5ECh. 16 - Prob. 16.6ECh. 16 - Prob. 16.7ECh. 16 - Prob. 16.8ECh. 16 - Prob. 16.9ECh. 16 - Prob. 16.10E
Ch. 16 - Prob. 16.11ECh. 16 - Prob. 16.12ECh. 16 - Prob. 16.13ECh. 16 - Prob. 16.14ECh. 16 - Prob. 16.15ECh. 16 - Prob. 16.16ECh. 16 - Prob. 16.17ECh. 16 - Prob. 16.18ECh. 16 - Prob. 16.19ECh. 16 - Prob. 16.20ECh. 16 - Prob. 16.21ECh. 16 - Prob. 16.22ECh. 16 - Prob. 16.23ECh. 16 - Prob. 16.24ECh. 16 - Prob. 16.25ECh. 16 - Prob. 16.26ECh. 16 - Prob. 16.27ECh. 16 - Prob. 16.28ECh. 16 - Prob. 16.29ECh. 16 - Prob. 16.30ECh. 16 - Prob. 16.31ECh. 16 - Prob. 16.32ECh. 16 - Prob. 16.33ECh. 16 - Prob. 16.34ECh. 16 - Prob. 16.35ECh. 16 - Prob. 16.36ECh. 16 - Prob. 16.37ECh. 16 - Prob. 16.38ECh. 16 - Prob. 16.39ECh. 16 - Prob. 16.40ECh. 16 - Prob. 16.41ECh. 16 - Prob. 16.42ECh. 16 - Prob. 16.43ECh. 16 - Prob. 16.44ECh. 16 - Prob. 16.45ECh. 16 - a The structure of 2 chloroethanol is usually...Ch. 16 - Prob. 16.47ECh. 16 - Prob. 16.48ECh. 16 - Prob. 16.49ECh. 16 - Prob. 16.50ECh. 16 - Prob. 16.51ECh. 16 - Prob. 16.52ECh. 16 - Prob. 16.53ECh. 16 - Prob. 16.54ECh. 16 - Prob. 16.55ECh. 16 - Prob. 16.56ECh. 16 - A microwave oven emits radiation having a...
Knowledge Booster
Similar questions
- Differentiate between Nuclear Spin and Magnetic Resonance Imaging?arrow_forwardYou have two solutions of the same compound that are blue. one is very pale and the other is very intense. Absorbance of each solution was measured with a spectrophotometer at the same wave length at which the solution absorbs. (A) Which solution has the higher absorbance? (B) Which is the more concentrated solution?arrow_forwardThe first excited state of Ca is reached by absorption of 422.7-nm light. (a) What is the energy difference (J) between the ground and excited states? (b) The degeneracies are g*/g0 3 for Ca. Find N*/N0 at 2 500 K. (c) By what percentage will the fraction in (b) be changed by a 15-K rise in temperature? (d) Find N*/N0 at 6 000 K.arrow_forward
- Covalent bonds in a molecule absorb radiation in the IR region and vibrate at characteristic frequencies. (a) The C---O bond absorbs radiation of wavelength 9.6 mm. What frequency (in s-1) corresponds to that wavelength? (b) The H---Cl bond has a frequency of vibration of 8.652x1013 Hz. What wavelength (in mm) corresponds to that frequency?arrow_forwardA magnesium-24 ion has a positive charge that is double the charge of a proton, and a mass of 3.98 ✕ 10−26 kg. At a particular instant, it is moving with a speed of 5.00 ✕ 106 m/s through a magnetic field. At this instant, its velocity makes an angle of 58° with the direction of the magnetic field at the ion's location. The magnitude of the field is 0.190 T. (a) What is the magnitude of the magnetic force (in N) on the ion? N (b) What is the magnitude of the ion's acceleration (in m/s2) at this instant? m/s2arrow_forwardThe reaction 9Be (3H, p) 11Be is studied by bombarding 9Be with 5 MeV tritons.Protons with energies of 2.260, 1.967 and 0.620 MeV are observed at 90 ° of the incident beam due to the formation of 11Be in the ground state and in two excited states:(a) Find the atomic mass of 11Be.(b) Find the excitation energy of the excited states.arrow_forward
- In a mass spectrometer, two beams of singly ionized isotopes of uranium 23592U and 23892U are injected with velocity 1.4*105m/s into a magnetic field of strength 0.7 T normally. Compute the distance d between the two trace lines of the isotopes after they complete one semi-circle. (Given: masses of the isotopes are m235 = 3.9*10-25 kg and m238 = 3.95*10-25) a) 1.26 cm b) 0.63 cm c) 0.32 cm d) none of these.arrow_forwardAn acceleration voltage of 15.0 kV is used to accelerate ions into the 1.48 m flight tube of a time-of-flight (TOF) mass spectrometer. The frequency at which spectra can be recorded is dependent on how long it takes the slowest ion to travel from the source to the detector. If you wish to scan up to m/z 13039, at what frequency (spectra/s) could spectra be recorded if a new spectrum begins each time the slowest ion reaches the detector? frequency: spectra/sarrow_forward2. Draw a diagram of energy levels in the EPR spectrum in each of the following cases and specify the number of transfers. (A) A system with S 5/2 in the absence of zero field splitting (B) A system with S 5/2 with small zero field splitting (C) A system with S 5/2 with large zero field splitting (D) A system with S = 3/2 (for electron spin) in interaction with a nucleus with spin I 3/2arrow_forward
- According to the shell model, the spin-parity of the ground state of 0-18 (Z=8, A=15) nucleus is: O Nuclear spin: 1, parity: + Nuclear spin: 0, parity: + Nuclear spin: 2 parity: + Nuclear spin: 2 parity: - Ο Ο Ο Ο 13arrow_forwardSingly-ionized carbon atoms are accelerated through 1050 V and passed into a mass spectrometer to determine the isotopes present. The magnetic field strength in the spectrometer is 0.180 T. (a) Determine the orbital radii for the 12C and 13C isotopes as they pass through the field. cm (12C) cm (13C) (b) Show that the ratio of the radii may be written in the form m1 = V by verifying that your radii in part (a) satisfy this formula. m1 m-arrow_forwardKk78.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Principles of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning