Chemistry For Today: General, Organic, And Biochemistry, Loose-leaf Version
Chemistry For Today: General, Organic, And Biochemistry, Loose-leaf Version
9th Edition
ISBN: 9781305968707
Author: Spencer L. Seager
Publisher: Brooks Cole
Question
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Chapter 16, Problem 16.1E
Interpretation Introduction

Interpretation:

The difference between primary, secondary, and tertiary amines in terms of bonding to the nitrogen atom is to be stated.

Concept introduction:

Amines are nitrogen-containing organic compounds. The general formula of amines is RNH2. Amines can be classified as primary amine, secondary amine, and tertiary amine.

Expert Solution & Answer
Check Mark

Answer to Problem 16.1E

In primary amines, nitrogen atom is attached to one alkyl or aryl group. In secondary amines, nitrogen atom is attached to two alkyl or aryl groups. In tertiary amines, nitrogen atom is attached to three alkyl or aryl groups.

Explanation of Solution

In primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group. The nitrogen atom is attached to one alkyl or aryl group in primary amine.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group. The nitrogen atom is attached to the two alkyl or aryl groups in secondary amine.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group. The nitrogen atom is attached to three alkyl or aryl groups in tertiary amine.

Conclusion

In primary amines, nitrogen atom is attached to one alkyl or aryl group. In secondary amines, nitrogen atom is attached to two alkyl or aryl groups. In tertiary amines, nitrogen atom is attached to three alkyl or aryl groups.

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Chapter 16 Solutions

Chemistry For Today: General, Organic, And Biochemistry, Loose-leaf Version

Ch. 16 - Prob. 16.11ECh. 16 - Prob. 16.12ECh. 16 - Prob. 16.13ECh. 16 - Prob. 16.14ECh. 16 - Prob. 16.15ECh. 16 - Prob. 16.16ECh. 16 - Prob. 16.17ECh. 16 - Prob. 16.18ECh. 16 - Prob. 16.19ECh. 16 - Draw diagrams similar to Figure 16.1 to illustrate...Ch. 16 - Prob. 16.21ECh. 16 - Prob. 16.22ECh. 16 - Prob. 16.23ECh. 16 - Prob. 16.24ECh. 16 - Prob. 16.25ECh. 16 - Prob. 16.26ECh. 16 - Prob. 16.27ECh. 16 - Prob. 16.28ECh. 16 - Prob. 16.29ECh. 16 - Prob. 16.30ECh. 16 - Prob. 16.31ECh. 16 - Prob. 16.32ECh. 16 - Prob. 16.33ECh. 16 - Describe the general structure of a neuron.Ch. 16 - Name the two amino acids that are starting...Ch. 16 - Prob. 16.36ECh. 16 - Prob. 16.37ECh. 16 - Prob. 16.38ECh. 16 - Prob. 16.39ECh. 16 - Prob. 16.40ECh. 16 - Prob. 16.41ECh. 16 - Prob. 16.42ECh. 16 - Why are alkaloids weakly basic?Ch. 16 - Prob. 16.44ECh. 16 - Prob. 16.45ECh. 16 - Prob. 16.46ECh. 16 - Prob. 16.47ECh. 16 - Prob. 16.48ECh. 16 - Prob. 16.49ECh. 16 - Prob. 16.50ECh. 16 - Prob. 16.51ECh. 16 - Complete the following reactions: a. b.Ch. 16 - Complete the following reactions: a. b.Ch. 16 - Prob. 16.54ECh. 16 - What are the products of the acid hydrolysis of...Ch. 16 - Prob. 16.56ECh. 16 - Prob. 16.57ECh. 16 - Prob. 16.58ECh. 16 - Prob. 16.59ECh. 16 - Prob. 16.60ECh. 16 - Prob. 16.61ECh. 16 - Prob. 16.62ECh. 16 - Prob. 16.63ECh. 16 - Prob. 16.64ECh. 16 - Prob. 16.65ECh. 16 - Prob. 16.66ECh. 16 - Prob. 16.67ECh. 16 - Prob. 16.68ECh. 16 - Prob. 16.69ECh. 16 - Prob. 16.70ECh. 16 - Prob. 16.71ECh. 16 - The stimulant in coffee is: a. tannic acid b....Ch. 16 - What are the most likely products of a reaction...
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