
Concept explainers
(a)
Interpretation:
IUPAC name for the given compound has to be assigned.
Concept Introduction:
For naming an acid anhydride, it can be structurally viewed in a way that contains two carbonyl groups that is joined by a single oxygen atom. This can also be said as two acyl group joined by a single oxygen atom.
Rules to obtain IUPAC name and common name for an acid anhydride:
- IUPAC name and common name for Symmetric anhydride is obtained by replacing the acid present in the name of parent
carboxylic acid with the word anhydride. - IUPAC name and common name for mixed anhydride is obtained by using the names of the parent carboxylic acids arranged in alphabetical order that is followed by the word anhydride.
(b)
Interpretation:
IUPAC name for the given compound has to be assigned.
Concept Introduction:
For naming an acid chloride, it can be structurally viewed in a way that contains one acyl group with a chlorine atom bonded to the carbonyl group
Rules to obtain IUPAC name and common name for an acid chloride:
- IUPAC name for acid chloride can be obtained from the parent carboxylic acid name. In the parent carboxylic acid name, the ending “-oic acid” is replaced by “-oyl chloride”.
- Common name for acid chloride can be obtained from the parent carboxylic acid name. In the parent carboxylic acid name, the ending “-ic acid” is replaced by “-yl chloride”.
(c)
Interpretation:
IUPAC name for the given compound has to be assigned.
Concept Introduction:
For naming an acid chloride, it can be structurally viewed in a way that contains one acyl group with a chlorine atom bonded to the carbonyl group
Rules to obtain IUPAC name and common name for an acid chloride:
- IUPAC name for acid chloride can be obtained from the parent carboxylic acid name. In the parent carboxylic acid name, the ending “-oic acid” is replaced by “-oyl chloride”.
- Common name for acid chloride can be obtained from the parent carboxylic acid name. In the parent carboxylic acid name, the ending “-ic acid” is replaced by “-yl chloride”.
(d)
Interpretation:
IUPAC name for the given compound has to be assigned.
Concept Introduction:
For naming an acid anhydride, it can be structurally viewed in a way that contains two carbonyl groups that is joined by a single oxygen atom. This can also be said as two acyl group joined by a single oxygen atom.
Rules to obtain IUPAC name and common name for an acid anhydride:
- IUPAC name and common name for Symmetric anhydride is obtained by replacing the acid present in the name of parent carboxylic acid with the word anhydride.
- IUPAC name and common name for mixed anhydride is obtained by using the names of the parent carboxylic acids arranged in alphabetical order that is followed by the word anhydride.

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Chapter 16 Solutions
EBK GENERAL, ORGANIC, AND BIOLOGICAL CH
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