Structural formula for methyl thiopropanoate has to be drawn. Concept Introduction: General structure of thioester can be represented as shown below, From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid . The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

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Answer 1

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 16, Problem 16.138EP

(a)

Interpretation Introduction

Interpretation:

Structural formula for methyl thiopropanoate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

(b)

Interpretation Introduction

Interpretation:

Structural formula for methyl thiopropionate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

(c)

Interpretation Introduction

Interpretation:

Structural formula for ethyl thioacetate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

(d)

Interpretation Introduction

Interpretation:

Structural formula for ethyl thioethanoate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

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You are trying to decide if there is a single reagent you can add that will make the following synthesis possible without any other major side products: xi 1. ☑ 2. H₂O хе i Draw the missing reagent X you think will make this synthesis work in the drawing area below. If there is no reagent that will make your desired product in good yield or without complications, just check the box under the drawing area and leave it blank. Click and drag to start drawing a structure. There is no reagent that will make this synthesis work without complications. : ☐ S ☐

Predict the major products of this organic reaction: H OH 1. LiAlH4 2. H₂O ? Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry. Click and drag to start drawing a structure. G C टे

For each reaction below, decide if the first stable organic product that forms in solution will create a new C-C bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. NH2 CI MgCl ? Will the first product that forms in this reaction create a new CC bond? Yes No MgBr ? Will the first product that forms in this reaction create a new CC bond? Yes No G टे

Answer 2

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 16, Problem 16.138EP

(a)

Interpretation Introduction

Interpretation:

Structural formula for methyl thiopropanoate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

(b)

Interpretation Introduction

Interpretation:

Structural formula for methyl thiopropionate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

(c)

Interpretation Introduction

Interpretation:

Structural formula for ethyl thioacetate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

(d)

Interpretation Introduction

Interpretation:

Structural formula for ethyl thioethanoate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

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Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 16, Problem 16.138EP

(a)

Interpretation Introduction

Interpretation:

Structural formula for methyl thiopropanoate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

(b)

Interpretation Introduction

Interpretation:

Structural formula for methyl thiopropionate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

(c)

Interpretation Introduction

Interpretation:

Structural formula for ethyl thioacetate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

(d)

Interpretation Introduction

Interpretation:

Structural formula for ethyl thioethanoate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

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Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 16, Problem 16.138EP

(a)

Interpretation Introduction

Interpretation:

Structural formula for methyl thiopropanoate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

(b)

Interpretation Introduction

Interpretation:

Structural formula for methyl thiopropionate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

(c)

Interpretation Introduction

Interpretation:

Structural formula for ethyl thioacetate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

(d)

Interpretation Introduction

Interpretation:

Structural formula for ethyl thioethanoate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

Expert Solution & Answer

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Answer 5

Chapter 16, Problem 16.138EP

(a)

Interpretation Introduction

Interpretation:

Structural formula for methyl thiopropanoate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

(b)

Interpretation Introduction

Interpretation:

Structural formula for methyl thiopropionate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

(c)

Interpretation Introduction

Interpretation:

Structural formula for ethyl thioacetate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

(d)

Interpretation Introduction

Interpretation:

Structural formula for ethyl thioethanoate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

Answer 6

Chapter 16, Problem 16.138EP

(a)

Interpretation Introduction

Interpretation:

Structural formula for methyl thiopropanoate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

Answer 7

Chapter 16, Problem 16.138EP

(a)

Interpretation Introduction

Interpretation:

Structural formula for methyl thiopropanoate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Structural formula for methyl thiopropionate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Structural formula for methyl thiopropionate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Structural formula for ethyl thioacetate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Structural formula for ethyl thioacetate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

Answer 12

(d)

Interpretation Introduction

Interpretation:

Structural formula for ethyl thioethanoate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Structural formula for ethyl thioethanoate has to be drawn.

Concept Introduction:

General structure of thioester can be represented as shown below,

From an IUPAC name, the structure of the thioester can be derived. IUPAC name of thioester consists of two parts. In an IUPAC name of thioester, the first part of the name is the alkyl part and the second part is the acid part. Alkyl group have come from the thiol and acyl part from carboxylic acid.

The same rule applies for deriving a structure from common name. The only difference is the acyl part name. The acyl part is named using the common name of thiocarboxylic acid.

Answer 14

Expert Solution & Answer

Answer 15

Expert Solution & Answer

Answer 16

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Answer 17

Ch. 16.1 - Prob. 1QQ Ch. 16.1 - Prob. 2QQ Ch. 16.1 - Prob. 3QQ Ch. 16.1 - Prob. 4QQ Ch. 16.1 - Prob. 5QQ Ch. 16.2 - Prob. 1QQ Ch. 16.2 - Prob. 2QQ Ch. 16.2 - Prob. 3QQ Ch. 16.2 - Prob. 4QQ Ch. 16.2 - Prob. 5QQ

Solution Summary: The author explains that the structure of methyl thiopropanoate can be drawn from an IUPAC name.

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Chapter 16 Solutions