Physical Chemistry
Physical Chemistry
2nd Edition
ISBN: 9781285969770
Author: Ball
Publisher: Cengage
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Chapter 16, Problem 16.11E
Interpretation Introduction

(a)

Interpretation:

The individual transitions that are allowed for D1P1 transition are to be stated.

Concept introduction:

The change in energy (ΔE) of the state depends on the strength of the magnetic field (B) and the z-component quantum number (ML) in the presence of magnetic field. The expression for the change in energy (ΔE) is written below.

ΔE=μBMLB

The value of (ML) can be positive, negative or zero. Hence, the change in energy (ΔE) can be positive, negative or zero. The change in energy (ΔE) of the state is equal to the amount of splitting.

Interpretation Introduction

(b)

Interpretation:

The unique spectral lines having different energy which are allowed for D1P1 transition are to be stated.

Concept introduction:

The change in energy (ΔE) of the state depends on the strength of the magnetic field (B) and the z-component quantum number (ML) in the presence of magnetic field. The expression for the change in energy (ΔE) is written below.

ΔE=μBMLB

The value of (ML) can be positive, negative or zero. Hence, the change in energy (ΔE) can be positive, negative or zero. The change in energy (ΔE) of the state is equal to the amount of splitting.

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