Physical Chemistry
Physical Chemistry
2nd Edition
ISBN: 9781285969770
Author: Ball
Publisher: Cengage
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Chapter 16, Problem 16.54E
Interpretation Introduction

Interpretation:

The changes in the nuclear energy levels of 35Cl nucleus are to be calculated.

Concept introduction:

The change in the nuclear energy levels of an element is calculated by the formula shown below.

ΔEmag=gNμNMIB

Where,

gN is the g factor of a nucleus.

μN is the nuclear magneton.

MI is the quantum number for the z component of nuclear angular momentum.

B is the applied magnetic field.

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The SN 1 mechanism starts with the rate-determining step which is the dissociation of the alkyl halide into a carbocation and a halide ion. The next step is the rapid reaction of the carbocation intermediate with the nucleophile; this step completes the nucleophilic substitution stage. The step that follows the nucleophilic substitution is a fast acid-base reaction. The nucleophile now acts as a base to remove the proton from the oxonium ion from the previous step, to give the observed product. Draw a curved arrow mechanism for the reaction, adding steps as necessary. Be sure to include all nonzero formal charges. Cl: Add/Remove step G Click and drag to start drawing a structure.
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