The reason that metal oxideshow an acidic nature in a high oxidation state, while show a basic nature in a low oxidation state, is to be explained. Concept Introduction: Elements combine with oxygen atom(s) to form oxides. They, then, react with water toeither produce an acid or a base. In their lowest oxidation number, all alkali and alkaline earth metal oxides are basic in nature. Some metal oxides, in ahigh oxidation state, show acidic behavior. All nonmetal oxides are acidic in nature in their highest oxidation state. They are considerably neutral in their low oxidation state. In any case, nonmetal oxides do not show basic nature. Metallic oxides show acidic as well as basic natures, according to the reaction conditions. These are called amphoteric oxides.
The reason that metal oxideshow an acidic nature in a high oxidation state, while show a basic nature in a low oxidation state, is to be explained. Concept Introduction: Elements combine with oxygen atom(s) to form oxides. They, then, react with water toeither produce an acid or a base. In their lowest oxidation number, all alkali and alkaline earth metal oxides are basic in nature. Some metal oxides, in ahigh oxidation state, show acidic behavior. All nonmetal oxides are acidic in nature in their highest oxidation state. They are considerably neutral in their low oxidation state. In any case, nonmetal oxides do not show basic nature. Metallic oxides show acidic as well as basic natures, according to the reaction conditions. These are called amphoteric oxides.
Solution Summary: The author explains that metal oxides show an acidic nature in a high oxidation state, while they are stable and form ionic bonds with oxygen.
The reason that metal oxideshow an acidic nature in a high oxidation state, while show a basic nature in a low oxidation state, is to be explained.
Concept Introduction:
Elements combine with oxygen atom(s) to form oxides. They, then, react with water toeither produce an acid or a base.
In their lowest oxidation number, all alkali and alkaline earth metal oxides are basic in nature.
Some metal oxides, in ahigh oxidation state, show acidic behavior.
All nonmetal oxides are acidic in nature in their highest oxidation state. They are considerably neutral in their low oxidation state. In any case, nonmetal oxides do not show basic nature.
Metallic oxides show acidic as well as basic natures, according to the reaction conditions. These are called amphoteric oxides.
MISSED THIS? Read Section 19.9 (Pages 878-881); Watch IWE 19.10
Consider the following reaction:
CH3OH(g)
CO(g) + 2H2(g)
(Note that AG,CH3OH(g) = -162.3 kJ/mol and AG,co(g)=-137.2 kJ/mol.)
Part A
Calculate AG for this reaction at 25 °C under the following conditions:
PCH₂OH
Pco
PH2
0.815 atm
=
0.140 atm
0.170 atm
Express your answer in kilojoules to three significant figures.
Ο ΑΣΦ
AG = -150
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kJ
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Calculate the free energy change under nonstandard conditions (AGrxn) by using the following relationship:
AGrxn = AGrxn + RTInQ,
AGxn+RTInQ,
where AGxn is the standard free energy change, R is the ideal gas constant, T is the temperature in kelvins, a
is the reaction quotient.
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