The orbital picture of indole, an aromatic heterocycle which has a benzene ring fused to a pyrrole ring is to be drawn. The number of Ï€ electrons in indole is to be given. The electronic relationship of indole with that of naphthalene is to be stated. Concept introduction: The orbital picture of a compound shows the Ïƒ bonds in a molecule along with the unhybridized p orbitals on each atom in the ring containing the electrons involved in delocalization. To draw: The orbital picture of indole, an aromatic heterocycle which has a benzene ring fused to a pyrrole ring. To give: The number of Ï€ electrons in indole. To state: The electronic relationship of indole with that of naphthalene.

Question

Using reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NOCI (g) 2NO (g) + Cl2 (g) AGº =41. kJ Now suppose a reaction vessel is filled with 4.50 atm of nitrosyl chloride (NOCI) and 6.38 atm of chlorine (C12) at 212. °C. Answer the following questions about this system: ? rise Under these conditions, will the pressure of NOCI tend to rise or fall? x10 fall Is it possible to reverse this tendency by adding NO? In other words, if you said the pressure of NOCI will tend to rise, can that be changed to a tendency to fall by adding NO? Similarly, if you said the pressure of NOCI will tend to fall, can that be changed to a tendency to rise by adding NO? yes no If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO needed to reverse it. Round your answer to 2 significant digits. 0.035 atm ✓ G 00. 18 Ar

Answer 1

Question

Chapter 15.SE, Problem 37AP

Interpretation Introduction

Interpretation:

The orbital picture of indole, an aromatic heterocycle which has a benzene ring fused to a pyrrole ring is to be drawn.

The number of Ï€ electrons in indole is to be given.

The electronic relationship of indole with that of naphthalene is to be stated.

Concept introduction:

The orbital picture of a compound shows the Ïƒ bonds in a molecule along with the unhybridized p orbitals on each atom in the ring containing the electrons involved in delocalization.

To draw:

The orbital picture of indole, an aromatic heterocycle which has a benzene ring fused to a pyrrole ring.

To give:

The number of Ï€ electrons in indole.

To state:

The electronic relationship of indole with that of naphthalene.

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Using reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NOCI (g) 2NO (g) + Cl2 (g) AGº =41. kJ Now suppose a reaction vessel is filled with 4.50 atm of nitrosyl chloride (NOCI) and 6.38 atm of chlorine (C12) at 212. °C. Answer the following questions about this system: ? rise Under these conditions, will the pressure of NOCI tend to rise or fall? x10 fall Is it possible to reverse this tendency by adding NO? In other words, if you said the pressure of NOCI will tend to rise, can that be changed to a tendency to fall by adding NO? Similarly, if you said the pressure of NOCI will tend to fall, can that be changed to a tendency to rise by adding NO? yes no If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO needed to reverse it. Round your answer to 2 significant digits. 0.035 atm ✓ G 00. 18 Ar

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