Cyclooctatetraene reacts with potassium metal to form the stable cyclooctatetraene dianion, C 6 H 8 2- . Whether the reaction will take place readily or not is to be stated. The geometry expected for the cyclooctatetraene dianion is also to be given. Concept introduction: According to Huckel’s Rule a planar, cyclic conjugated system will be aromatic if it contains (4n+2)Ï€ electrons. Systems with 4nÏ€ electrons will be antiaromatic. If the product is more stable than the reactant the reaction will proceed readily. A planar geometry is expected for ions that are aromatic. To state: Whether the reaction in which cyclooctatetraene reacts with potassium metal to form the stable cyclooctatetraene dianion, C 6 H 8 2- will take place readily or not. To give: The geometry expected for the cyclooctatetraene dianion.

Question

10. (5pts) Provide the complete arrow pushing mechanism for the chemical transformation → depicted below Use proper curved arrow notation that explicitly illustrates all bonds being broken, and all bonds formed in the transformation. Also, be sure to include all lone pairs and formal charges on all atoms involved in the flow of electrons. CH3O II HA H CH3O-H H ①

Answer 1

Question

Definition Definition Rule that estimates whether a given organic planar ring structure will show an aromatic property. A cyclic ring molecule is said to follow Hückel’s rule if the л-electrons count in a molecule is [4n+2], where n stands for a positive numerical value. It is also called the [4n+2] rule. Hückel's rule, sometimes referred to as the aromaticity rule, is one but not the only criteria to judge a molecule for aromaticity.

Chapter 15.4, Problem 7P

Interpretation Introduction

Interpretation:

Cyclooctatetraene reacts with potassium metal to form the stable cyclooctatetraene dianion, C₆H₈^2-. Whether the reaction will take place readily or not is to be stated. The geometry expected for the cyclooctatetraene dianion is also to be given.

Concept introduction:

According to Huckel’s Rule a planar, cyclic conjugated system will be aromatic if it contains (4n+2)Ï€ electrons. Systems with 4nÏ€ electrons will be antiaromatic.

If the product is more stable than the reactant the reaction will proceed readily.

A planar geometry is expected for ions that are aromatic.

To state:

Whether the reaction in which cyclooctatetraene reacts with potassium metal to form the stable cyclooctatetraene dianion, C₆H₈^2- will take place readily or not.

To give:

The geometry expected for the cyclooctatetraene dianion.

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10. (5pts) Provide the complete arrow pushing mechanism for the chemical transformation → depicted below Use proper curved arrow notation that explicitly illustrates all bonds being broken, and all bonds formed in the transformation. Also, be sure to include all lone pairs and formal charges on all atoms involved in the flow of electrons. CH3O II HA H CH3O-H H ①

Do the Lone Pairs get added bc its valence e's are a total of 6 for oxygen and that completes it or due to other reasons. How do we know the particular indication of such.

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Answer 2

Question

Definition Definition Rule that estimates whether a given organic planar ring structure will show an aromatic property. A cyclic ring molecule is said to follow Hückel’s rule if the л-electrons count in a molecule is [4n+2], where n stands for a positive numerical value. It is also called the [4n+2] rule. Hückel's rule, sometimes referred to as the aromaticity rule, is one but not the only criteria to judge a molecule for aromaticity.

Chapter 15.4, Problem 7P

Interpretation Introduction

Interpretation:

Cyclooctatetraene reacts with potassium metal to form the stable cyclooctatetraene dianion, C₆H₈^2-. Whether the reaction will take place readily or not is to be stated. The geometry expected for the cyclooctatetraene dianion is also to be given.

Concept introduction:

According to Huckel’s Rule a planar, cyclic conjugated system will be aromatic if it contains (4n+2)Ï€ electrons. Systems with 4nÏ€ electrons will be antiaromatic.

If the product is more stable than the reactant the reaction will proceed readily.

A planar geometry is expected for ions that are aromatic.

To state:

Whether the reaction in which cyclooctatetraene reacts with potassium metal to form the stable cyclooctatetraene dianion, C₆H₈^2- will take place readily or not.

To give:

The geometry expected for the cyclooctatetraene dianion.

Expert Solution & Answer

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See solution

Check out sample textbook solution

Answer 3

Question

Definition Definition Rule that estimates whether a given organic planar ring structure will show an aromatic property. A cyclic ring molecule is said to follow Hückel’s rule if the л-electrons count in a molecule is [4n+2], where n stands for a positive numerical value. It is also called the [4n+2] rule. Hückel's rule, sometimes referred to as the aromaticity rule, is one but not the only criteria to judge a molecule for aromaticity.

Chapter 15.4, Problem 7P

Interpretation Introduction

Interpretation:

Cyclooctatetraene reacts with potassium metal to form the stable cyclooctatetraene dianion, C₆H₈^2-. Whether the reaction will take place readily or not is to be stated. The geometry expected for the cyclooctatetraene dianion is also to be given.

Concept introduction:

According to Huckel’s Rule a planar, cyclic conjugated system will be aromatic if it contains (4n+2)Ï€ electrons. Systems with 4nÏ€ electrons will be antiaromatic.

If the product is more stable than the reactant the reaction will proceed readily.

A planar geometry is expected for ions that are aromatic.

To state:

Whether the reaction in which cyclooctatetraene reacts with potassium metal to form the stable cyclooctatetraene dianion, C₆H₈^2- will take place readily or not.

To give:

The geometry expected for the cyclooctatetraene dianion.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 4

Question

Definition Definition Rule that estimates whether a given organic planar ring structure will show an aromatic property. A cyclic ring molecule is said to follow Hückel’s rule if the л-electrons count in a molecule is [4n+2], where n stands for a positive numerical value. It is also called the [4n+2] rule. Hückel's rule, sometimes referred to as the aromaticity rule, is one but not the only criteria to judge a molecule for aromaticity.

Chapter 15.4, Problem 7P

Interpretation Introduction