Chemical Principles
Chemical Principles
8th Edition
ISBN: 9781337247269
Author: Steven S. Zumdahl; Donald J. DeCoste
Publisher: Cengage Learning US
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Chapter 15, Problem 64E

(a)

Interpretation Introduction

Interpretation:

At which condition the rate = k’[Br2] should be predicted.

Concept Introduction:

Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by reduced amount of reactant in per unit time or increase the amount of product in per unit time.

(b)

Interpretation Introduction

Interpretation:

At which condition the rate = k”[H2][Br2]1/2 should be predicted.

Concept Introduction:

(c)

Interpretation Introduction

Interpretation:

The expression of k’ and k” in terms of rate constants should be predicted.

Concept Introduction:

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Organic compounds that contain large proportions of nitrogen and oxygen tend to be unstable and are easily decomposed. Hexanitroethane, C₂(NO2)6, decomposes according to the equation C₂(NO2)6→ 2NO2 + 4NO+2CO2 The reaction in CCl4 solvent is first order with respect to C₂(NO₂)6. At 73.8 °C, k = 0.000330 s¹ and at 103.0 °C, k=0.0189 s ¹. (a) What is the half-life of C₂(NO2)6 at 73.8 °C? i eTextbook and Media (b) What is the half-life of C₂(NO₂)6 at 103.0 °C? i seconds (c) If 0.100 mol of C₂(NO2)6 is dissolved in CCl4 at 73.8°C to give 1.00 L of solution, what will be the C₂(NO2)6 concentration after 50.0 minutes? i M (e) What is the rate constant at 154.8 °C? i seconds (d) What is the value of the activation energy of this reaction, expressed in kilojoules? kJ/mol 51
the reaction AB + B2 = 2AB2 is an elementary reaction. How many times must the pressure of the gaseous mixture be increased in order for its velocity to increase 1000 times?
Organic compounds that contain large proportions of nitrogen and oxygen tend to be unstable and are easily decomposed. Hexanitroethane, C2(NO2)6, decomposes according to the equation C2(NO2)6- 2NO, + 4NO + 2CO, The reaction in CCl, solvent is first order with respect to Cz{NO2)s At 63.7°C, k= 0.000254 s* and at 112.6°C, k = 0.0126s*. (a) What is the half-life of C2{NO2); at 63.7 °C? i seconds e Textbook and Media (b) What is the half-life of C2(NO2)s at 112.6 °C? seconds (c) IF0.100 mol of C2(NO2)6 is dissolved in CCI4 at 63.7°C to give 1.00 L of solution, what will be the C2(NO2), concentration after 50.0 minutes? i M (d) What is the value of the activation energy of this reaction, expressed in kilojoules? i kJ/mol (e) What is the rate constant at 159.4 °C?

Chapter 15 Solutions

Chemical Principles

Ch. 15 - Consider the general reaction aA+bBcC and the...Ch. 15 - Prob. 12ECh. 15 - Prob. 13ECh. 15 - Prob. 14ECh. 15 - Prob. 15ECh. 15 - The hydroxyl radical (OH) is an important...Ch. 15 - Prob. 17ECh. 15 - The reaction 2NO(g)+Cl2(g)2NOCl(g) was studied at...Ch. 15 - Prob. 19ECh. 15 - The following data were obtained for the gas-phase...Ch. 15 - Prob. 21ECh. 15 - Prob. 22ECh. 15 - Prob. 23ECh. 15 - Prob. 24ECh. 15 - Prob. 25ECh. 15 - Prob. 26ECh. 15 - Prob. 27ECh. 15 - Prob. 28ECh. 15 - If the half-life for a reaction is 20. seconds,...Ch. 15 - A certain reaction has the following general form:...Ch. 15 - Prob. 31ECh. 15 - Prob. 32ECh. 15 - The decomposition of hydrogen peroxide was studied...Ch. 15 - Prob. 34ECh. 15 - Prob. 35ECh. 15 - Prob. 36ECh. 15 - At 500K in the presence of a copper surface,...Ch. 15 - Experimental data for the reaction A2B+C have been...Ch. 15 - The reaction NO(g)+O3(g)NO2(g)+O2(g) was studied...Ch. 15 - Determine the forms of the integrated and the...Ch. 15 - Prob. 41ECh. 15 - Prob. 42ECh. 15 - Prob. 43ECh. 15 - Prob. 44ECh. 15 - Prob. 45ECh. 15 - Prob. 46ECh. 15 - Prob. 47ECh. 15 - Prob. 48ECh. 15 - Prob. 49ECh. 15 - Prob. 50ECh. 15 - Prob. 51ECh. 15 - Prob. 52ECh. 15 - Prob. 53ECh. 15 - Prob. 54ECh. 15 - Prob. 55ECh. 15 - Define each of the following. elementary step...Ch. 15 - Define what is meant by unimolecular and...Ch. 15 - What two requirements must be met to call a...Ch. 15 - Prob. 59ECh. 15 - Prob. 60ECh. 15 - A proposed mechanism for a reaction is...Ch. 15 - Is the mechanism NO+Cl2k1NOCl2NOCl2+NOk22NOCl...Ch. 15 - The reaction 2NO(g)+O2(g)2NO2(g) exhibits the rate...Ch. 15 - Prob. 64ECh. 15 - The reaction...Ch. 15 - Prob. 66ECh. 15 - Prob. 67ECh. 15 - Prob. 68ECh. 15 - The following mechanism is proposed for the...Ch. 15 - The following mechanism has been proposed to...Ch. 15 - Consider the hypothetical reaction BE+F which is...Ch. 15 - How is the rate of a reaction affected by each of...Ch. 15 - The central idea of the collision model is that...Ch. 15 - Prob. 74ECh. 15 - Prob. 75ECh. 15 - Consider the following potential energy plots Rank...Ch. 15 - Prob. 77ECh. 15 - Prob. 78ECh. 15 - Prob. 79ECh. 15 - Prob. 80ECh. 15 - Prob. 81ECh. 15 - Chemists commonly use a rule of thumb that an...Ch. 15 - Prob. 83ECh. 15 - Prob. 84ECh. 15 - Prob. 85ECh. 15 - Prob. 86ECh. 15 - For the following reaction profiles, indicate the...Ch. 15 - Prob. 88ECh. 15 - Prob. 89ECh. 15 - Prob. 90ECh. 15 - Prob. 91ECh. 15 - Prob. 92ECh. 15 - The decomposition of NH3 to N2 and H2 was studied...Ch. 15 - One pathway for the destruction of ozone in the...Ch. 15 - Prob. 95ECh. 15 - Prob. 96ECh. 15 - Prob. 97ECh. 15 - Prob. 98ECh. 15 - Prob. 99ECh. 15 - Prob. 100AECh. 15 - Prob. 101AECh. 15 - Prob. 102AECh. 15 - Prob. 103AECh. 15 - Prob. 104AECh. 15 - Prob. 105AECh. 15 - Prob. 106AECh. 15 - Prob. 107AECh. 15 - Prob. 108AECh. 15 - Prob. 109AECh. 15 - The decomposition of NO2(g) occurs by the...Ch. 15 - Prob. 111AECh. 15 - Prob. 112AECh. 15 - Prob. 113AECh. 15 - Prob. 114AECh. 15 - Prob. 115AECh. 15 - Prob. 116AECh. 15 - The compound NO2Cl is thought to decompose to NO2...Ch. 15 - Prob. 118AECh. 15 - Prob. 119AECh. 15 - Prob. 120AECh. 15 - Prob. 121AECh. 15 - Prob. 122AECh. 15 - Prob. 123AECh. 15 - Prob. 124AECh. 15 - Prob. 125AECh. 15 - Prob. 126AECh. 15 - Consider the following reaction: CH3X+YCH3Y+X At...Ch. 15 - The following data were collected in two studies...Ch. 15 - Prob. 129CPCh. 15 - For the reaction 2A+Bproducts afriend proposes the...Ch. 15 - Consider the hypothetical reaction A+B+2C2D+3E In...Ch. 15 - A reaction represented by the equation...Ch. 15 - Prob. 133CPCh. 15 - You are studying the kinetics of the reaction...Ch. 15 - Prob. 135CPCh. 15 - Prob. 136MP
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Kinetics: Initial Rates and Integrated Rate Laws; Author: Professor Dave Explains;https://www.youtube.com/watch?v=wYqQCojggyM;License: Standard YouTube License, CC-BY