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OWLv2 for Moore/Stanitski's Chemistry: The Molecular Science, 5th Edition, [Instant Access], 1 term (6 months)
5th Edition
ISBN: 9781285460420
Author: John W. Moore; Conrad L. Stanitski
Publisher: Cengage Learning US
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Chapter 15, Problem 59QRT
Interpretation Introduction
Interpretation:
The value of solubility product of
Concept Introduction:
Solubility is the maximum amount of a solute that can be dissolve given mass of solvent at a given temperature. The term soluble is used for a pair of substances that forms a homogenous mixture. The term insoluble is used for a pair that does not mix with each other. Solubility product expression is the product of initial concentrations of the ions generated by the sparingly soluble salt in solution. The formula of the solubility product is shown below.
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Chapter 15 Solutions
OWLv2 for Moore/Stanitski's Chemistry: The Molecular Science, 5th Edition, [Instant Access], 1 term (6 months)
Ch. 15.1 - Predict whether 1.0 L of each solution is a...Ch. 15.1 - Calculate the pH of blood containing 0.0020-M...Ch. 15.1 - Prob. 15.2ECh. 15.1 -
Calculate the ratio of [] to [] in blood at a...Ch. 15.1 - Use the data in Table 15.1 to select a conjugate...Ch. 15.1 -
Calculate the mole ratio of sodium acetate and...Ch. 15.1 - Calculate the pH of these buffers.
Ch. 15.1 - If an abnormally high CO2 concentration is present...Ch. 15.1 - Calculate the minimum mass (g) of KOH that would...Ch. 15.2 - For the titration of 50.0 mL of 0.100-M HCl with...
Ch. 15.2 - Draw the titration curve for the titration of 50.0...Ch. 15.2 - Use the Ka expression and value for acetic acid to...Ch. 15.2 - Explain why the curve for the titration of acetic...Ch. 15.4 - Write the Ksp expression for each of these...Ch. 15.4 - The Ksp of AgBr at 100 C is 5 1010. Calculate the...Ch. 15.4 - A saturated solution of silver oxalate. Ag2C2O4....Ch. 15.4 - Prob. 15.9CECh. 15.5 - Consider 0.0010-M solutions of these sparingly...Ch. 15.5 - Prob. 15.11PSPCh. 15.5 - Calculate the solubility of PbCl2 in (a) pure...Ch. 15.5 - Prob. 15.13PSPCh. 15.6 - (a) Determine whether AgCl precipitates from a...Ch. 15.6 - Prob. 15.15PSPCh. 15 - Prob. 1SPCh. 15 - Choose a weak-acid/weak-base conjugate pair from...Ch. 15 - Prob. 4SPCh. 15 - Define the term buffer capacity.Ch. 15 - What is the difference between the end point and...Ch. 15 - What are the characteristics of a good acid-base...Ch. 15 - A strong acid is titrated with a strong base, such...Ch. 15 - Repeat the description for Question 4, but use a...Ch. 15 - Use Le Chatelier’s principle to explain why PbCl2...Ch. 15 - Describe what a complex ion is and give an...Ch. 15 - Define the term “amphoteric”.
Ch. 15 - Distinguish between the ion product (Q) expression...Ch. 15 - Describe at least two ways that the solubility of...Ch. 15 - Briefly describe how a buffer solution can control...Ch. 15 - Identify each pair that could form a buffer. (a)...Ch. 15 - Identify each pair that could form a buffer. (a)...Ch. 15 - Many natural processes can be studied in the...Ch. 15 - Which of these combinations is the best to buffer...Ch. 15 - Without doing calculations, determine the pH of a...Ch. 15 - Without doing calculations, determine the pH of a...Ch. 15 - Select from Table 15.1 a conjugate acid-base pair...Ch. 15 - Select from Table 15.1 a conjugate acid-base pair...Ch. 15 - Calculate the mass of sodium acetate, NaCH3COO,...Ch. 15 - Calculate the mass in grams of ammonium chloride,...Ch. 15 - A buffer solution can be made from benzoic acid,...Ch. 15 - A buffer solution is prepared from 5.15 g NH4NO3...Ch. 15 - You dissolve 0.425 g NaOH in 2.00 L of a solution...Ch. 15 - A buffer solution is prepared by adding 0.125 mol...Ch. 15 - If added to 1 L of 0.20-M acetic acid, CH3COOH,...Ch. 15 - If added to 1 L of 0.20-M NaOH, which of these...Ch. 15 - Calculate the pH change when 10.0 mL of 0.100-M...Ch. 15 - Prob. 29QRTCh. 15 - Prob. 30QRTCh. 15 - Prob. 31QRTCh. 15 - The titration curves for two acids with the same...Ch. 15 - Explain why it is that the weaker the acid being...Ch. 15 - Prob. 34QRTCh. 15 - Consider all acid-base indicators discussed in...Ch. 15 - Which of the acid-base indicators discussed in...Ch. 15 - It required 22.6 mL of 0.0140-M Ba(OH)2 solution...Ch. 15 - It took 12.4 mL of 0.205-M H2SO4 solution to...Ch. 15 - Vitamin C is a monoprotic acid. To analyze a...Ch. 15 - An acid-base titration was used to find the...Ch. 15 - Calculate the volume of 0.150-M HCl required to...Ch. 15 - Calculate the volume of 0.225-M NaOH required to...Ch. 15 - Prob. 43QRTCh. 15 - Prob. 44QRTCh. 15 - Prob. 45QRTCh. 15 - Explain why rain with a pH of 6.7 is not...Ch. 15 - Identify two oxides that are key producers of acid...Ch. 15 - Prob. 48QRTCh. 15 - Prob. 49QRTCh. 15 - Prob. 50QRTCh. 15 - Prob. 51QRTCh. 15 - A saturated solution of silver arsenate, Ag3AsO4,...Ch. 15 - Prob. 53QRTCh. 15 - Prob. 54QRTCh. 15 - Prob. 55QRTCh. 15 - Prob. 56QRTCh. 15 - Prob. 57QRTCh. 15 - Prob. 58QRTCh. 15 - Prob. 59QRTCh. 15 - Prob. 60QRTCh. 15 - Prob. 61QRTCh. 15 - Prob. 62QRTCh. 15 - Prob. 63QRTCh. 15 - Prob. 64QRTCh. 15 - Predict what effect each would have on this...Ch. 15 - Prob. 66QRTCh. 15 - Prob. 67QRTCh. 15 - The solubility of Mg(OH)2 in water is...Ch. 15 - Prob. 69QRTCh. 15 - Prob. 70QRTCh. 15 - Prob. 71QRTCh. 15 - Prob. 72QRTCh. 15 - Write the chemical equation for the formation of...Ch. 15 - Prob. 74QRTCh. 15 - Prob. 75QRTCh. 15 - Prob. 76QRTCh. 15 - Prob. 77QRTCh. 15 - Prob. 78QRTCh. 15 - Prob. 79QRTCh. 15 - Prob. 80QRTCh. 15 - Prob. 81QRTCh. 15 - Solid sodium fluoride is slowly added to an...Ch. 15 - Prob. 83QRTCh. 15 - Prob. 84QRTCh. 15 - A buffer solution was prepared by adding 4.95 g...Ch. 15 - Prob. 86QRTCh. 15 - Prob. 87QRTCh. 15 - Prob. 88QRTCh. 15 - Prob. 89QRTCh. 15 - Which of these buffers involving a weak acid HA...Ch. 15 - Prob. 91QRTCh. 15 - Prob. 92QRTCh. 15 - When 40.00 mL of a weak monoprotic acid solution...Ch. 15 - Each of the solutions in the table has the same...Ch. 15 - Prob. 95QRTCh. 15 - Prob. 97QRTCh. 15 - The average normal concentration of Ca2+ in urine...Ch. 15 - Explain why even though an aqueous acetic acid...Ch. 15 - Prob. 100QRTCh. 15 - Prob. 101QRTCh. 15 - Prob. 102QRTCh. 15 - Prob. 103QRTCh. 15 - Prob. 104QRTCh. 15 - Apatite, Ca5(PO4)3OH, is the mineral in teeth.
On...Ch. 15 - Calculate the maximum concentration of Mg2+...Ch. 15 - Prob. 107QRTCh. 15 - Prob. 108QRTCh. 15 - The grid has six lettered boxes, each of which...Ch. 15 - Consider the nanoscale-level representations for...Ch. 15 - Consider the nanoscale-level representations for...Ch. 15 - Prob. 112QRTCh. 15 - Prob. 113QRTCh. 15 - Prob. 114QRTCh. 15 - Prob. 115QRTCh. 15 - You want to prepare a pH 4.50 buffer using sodium...Ch. 15 - Prob. 117QRTCh. 15 - Prob. 118QRTCh. 15 - Prob. 119QRTCh. 15 - Prob. 120QRTCh. 15 - Prob. 121QRTCh. 15 - Prob. 122QRTCh. 15 - You are given four different aqueous solutions and...Ch. 15 - Prob. 124QRTCh. 15 - Prob. 126QRTCh. 15 - Prob. 15.ACPCh. 15 - Prob. 15.BCP
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- Phosphate-buffered saline (PBS) is a solution commonly used in studies of animal tissues and cells. Its composition is 137 mM NaCl, 2.7 mM KCl, 10 mM Na₂HPO4 (pK₁ = 2.14), and 1.8 mM KH₂PO4 (pKa = 6.86). Calculate the pH and osmolarity of PBS. Give the osmolarity in units of osmoles per liter (osm/L). pH = = Enter numeric value osmolarity = osm/Larrow_forwardGroundwater containing 0.0001468 M of Mg2+ is at equilibrium. Use the solubility constant Ksp=1.35×10−11. Assuming no other ions are present, what is the equilibrium pH? Round the final answer to only 2 decimals places.arrow_forwardThe generic metal hydroxide M(OH)2 has Ksp = 8.45×10−12. (NOTE: In this particular problem, because of the magnitude of the Ksp and the stoichiometry of the compound, the contribution of OH− from water can be ignored. However, this may not always be the case.) What is the solubility of M(OH)2 in a 0.202 M solution of M(NO3)2?Express your answer with the appropriate units.arrow_forward
- Tooth enamel is composed of hydroxyapatite, whose simplest formula is Ca5(PO4)3OH, and whose corresponding Ksp = 6.8 * 10-27. As, fluoride in fluorinated water or in toothpaste reacts with hydroxyapatite to form fluoroapatite, Ca5(PO4)3F, whose Ksp = 1.0 * 10-60. Write the expression for the solubility-constant for hydroxyapatite and for fluoroapatite.arrow_forwardCa(OH)2 has a Ksp of 6.5 x 10-6. (a) If 0.370 g of Ca(OH)2is added to 500 mL of water and the mixture is allowedto come to equilibrium, will the solution be saturated?(b) If 50 mL of the solution from part (a) is added to eachof the beakers shown here, in which beakers, if any, will aprecipitate form? In those cases where a precipitate forms,what is its identity?arrow_forwardLead (II) chloride, PbCl2, has Ksp = 1.6 x 10–5. (a) Determine the solubility of PbCl2 expressed in mol/L; (b) How many grams of PbCl2 will dissolve in 250 mL of water? (c) Predict whether PbCl2 precipitate will be formed when 2.0 mL of 0.10 M Pb(NO3)2 is added to 3.0 mL of 0.10 M NaCl.arrow_forward
- Compare the two quantities based on the given condition: Consider a saturated aqueous solution of CaF2 Ca2+ [HF] + [F-] A. I = IIB. I < IIC. I > IID. The two quantities cannot be compared based on the given information.arrow_forwardWhat is the molar solubility of MgF2 in 0.36 M NaF? For MgF2, Ksp = 8.4 x 10–8. 7.1 x 10–4 1.0 x 10–7 1.4 x 10–4 2.3 x 10–7 6.5 x 10–7arrow_forwardWhat is the molar solubility of CaCO3 at 50°C in a solution pre- pared by dissolving 1.000 L of CO2 gas (at 20°C and 731 mm Hg) and 3.335 g of solid Ca(OH)2 in enough water to make 500.0 mL of solution at 50°C? Is the solubility of CaCO3 at 50°C larger or smaller than at 25 °C? Explain. You may assume that AH° and AS° are independent of temperature.arrow_forward
- A certain soft drink is bottled so that a bottle at 25OC contains CO2 gas at a pressure of 5.0 atm over the liquid. Assuming that the partial pressure of CO2 in the atmosphere is 4.0 x 10-4 atm, calculate the equilibrium concentrations of CO2 in the soda both before and after the bottle is opened. The Henry’s law constant for CO2 in aqueous solution is 3.1 x 10-2 mol/L atm at 25oC.arrow_forwardPhosphate-buffered saline (PBS) is a solution commonly used in studies of animal tissues and cells. Its composition is 137 mM NaCl, 2.7 mM KC1, 10 mM Na, HPO, (pK, = 2.14), and 1.8 mM KH₂PO, (pK, = 6.86). Calculate the pH and osmolarity of PBS. Give the osmolarity in units of osmoles per liter (osm/L). pH = 7.605 osmolarity 313.0 Incorrect osm/Larrow_forwardThe solubility-product constants, Ksp, at 25 °C for two compounds [iron(II) carbonate, FeCO3, and cadmium(II) carbonate, CdCO3] are given by the table Substance Ksp FeCO3 2.10 x 10-11 CdCO3 1.80 × 10-14 Part A A solution of Na2CO3 is added dropwise to a solution that contains 1.02x10-2 MFe²+ and 1.48x10-2 M Cd²+. What concentration of CO3²- is need to initiate precipitation? Neglect any volume changes during the addition. Express your answer with the appropriate units. ► View Available Hint(s) [CO3²- ] = Submit μA Value Part B Complete previous part(s) Part C Complete previous part(s) Units ?arrow_forward
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY