Connect  One Semester Access Card for General, Organic, & Biological Chemistry
Connect One Semester Access Card for General, Organic, & Biological Chemistry
4th Edition
ISBN: 9781260194654
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Chapter 15, Problem 43P
Interpretation Introduction

Interpretation:

Fischer projection for the given ball and stick model needs to be determined.

Concept Introduction:

Fischer Projection is a method of drawing 3-D structures of organic molecules in 2D nature. In this method, all non-terminal bonds are depicted as horizontal or vertical lines.

For a simple molecule consists of one chiral center with four different groups attached (e.g. CHClBrI), the Fischer projection method uses a cross formula to draw the two bonds in the plane. In the Fischer projection, both horizontal bonds come forward (drawn on wedges) and both vertical bonds go behind (on dashed lines).

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Draw a Lewis structure for each of the following molecules and assign charges where appropriate. The order in which the atoms are connected is given in parentheses. a. CIFCIF b. BrCNBrCN 0 c. SOCI2 × (CISCIO) SOC₁₂ (CISCI) You can draw both an octet and a valence shell expanded structure. Considering the following structural information, which is the better one: The measured S-OS-O bond length in SOC12SOCl2 is 1.43 Å. For comparison, that in SO2SO2 is 1.43 Å [Exercise 1-9, part (b)], that in CHзSOHCH3 SOH d. CH3NH2CH3NH2 (methanesulfenic acid) is 1.66 A. e. CH3OCH3 CH3 OCH3 NH2 f. N2H2× (HNNH) N2 H2 (HNNH) g. CH2COCH₂ CO h. HN3× (HNNN) HN3 (HNNN) i. N20 × (NNO) N2O (NNO)

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Connect One Semester Access Card for General, Organic, & Biological Chemistry

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