Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
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Chapter 15, Problem 15.9P

Vapor sulfur hexafluoride SF6 at pressures of about 1600 kPa is used as a dielectric in large primary circuit breakers for electric transmission systems. As liquids. SF6 and H2O are essentially immiscible, and one must therefore specify a low enough moisture content in the vapor SF6 so that if condensation occurs in cold weather, a liquid water phase will not form first in the system. For a preliminary determination, assume the vapor phase can be treated as an ideal gas and prepare the phase diagram [like Fig. 12.18(a)] for H 2 O / S F 6 ( 2 ) at 1600 kPa in the composition range up to 1000 parts per million of water (mole basis). The following approximate equations for vapor pressure are adequate:

I n P 1 s a t / k P a = 19.1478 5363.70 T / K

I n P 2 s a t / k P a = 14.6511 2048.97 T / K

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