Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
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Chapter 15, Problem 15.23P

In Ex. 15.8, Henry's constant for adsorption k, identified as the intercept on a plot of n/P vs. n, was found from a polynomial curve-fit of n/P vs. n. An alternative procedure is based on a plot of I n P / n vs. n. Suppose that the adsorbate equation of state is a power series in n: z = 1 + Bn + Cn2+ - - -. Show how from a plot (or a polynomial curve-fit) of ln(P/n) vs. n one can extract values of k and B. [Hint:. Start with Eq. (15.39).]

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Introduction to Chemical Engineering Thermodynamics

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