Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
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Chapter 15, Problem 15.7P

Pure liquid species 2 and 3 are for practical purposes immiscible in one another. Liquid species 1 is soluble in both liquid 2 and liquid 3. One mole each of liquids 1,2, and 3 are shaken together to form an equilibrium mixture of two liquid phases: an α -phase containing species 1 and 2, and a β -phase containing species 1 and 3. What are the mole fractions of species 1 in the a and β phases, if at the temperature of the experiment. the excess Gibbs energies of the phases are given by:

( G E ) a R T = 0.4 x 1 a x 2 a and ( G E ) β R T = 0.8 x 1 β x 2 β

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Introduction to Chemical Engineering Thermodynamics

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