(a)
Interpretation:
The compound that has higher solubility in water among the given pair has to be identified.
Concept Introduction:
Carbonyl groups are the one which contain a double bond between carbon and oxygen atom.
Aldehydes contain a carbonyl group that contains a hydrogen atom and a carbon atom bonded to it. Aldehyde that has one and two carbon atoms are gas at room temperature. The physical state of aldehyde that contains three carbon atoms to eleven carbon atoms that are not branched is liquid at room temperature. Aldehydes that contain more than eleven carbon atoms are solid at room temperature.
Ketones contain a carbonyl group that contains two carbon atoms bonded to it. For a compound to be ketone, a minimum of three carbon atom is required. Ketones that contain three carbon atoms to eight carbon atoms which have the carbonyl group at the second carbon atom are liquid at room temperature.
Solubility of aldehydes and ketones depend upon the length of the carbon chain. Those contain less than six carbon atoms are soluble in both water and organic solvents. Aldehydes and ketones that contain six or more carbon atoms are not soluble in water but soluble in organic solvents only. Solubility of smaller ketones and aldehydes are result of the hydrogen bond formation between the lone pairs of oxygen atom and the hydrogen atom in the water molecule.
(b)
Interpretation:
The compound that has higher solubility in water among the given pair has to be identified.
Concept Introduction:
Carbonyl groups are the one which contain a double bond between carbon and oxygen atom. Aldehydes and ketones possess this carbonyl functional group in it. The structural representation of a carbonyl group can be given as shown below,
Aldehydes contain a carbonyl group that contains a hydrogen atom and a carbon atom bonded to it. Aldehyde that has one and two carbon atoms are gas at room temperature. The physical state of aldehyde that contains three carbon atoms to eleven carbon atoms that are not branched is liquid at room temperature. Aldehydes that contain more than eleven carbon atoms are solid at room temperature.
Ketones contain a carbonyl group that contains two carbon atoms bonded to it. For a compound to be ketone, a minimum of three carbon atom is required. Ketones that contain three carbon atoms to eight carbon atoms which have the carbonyl group at the second carbon atom are liquid at room temperature.
Solubility of aldehydes and ketones depend upon the length of the carbon chain. Those contain less than six carbon atoms are soluble in both water and organic solvents. Aldehydes and ketones that contain six or more carbon atoms are not soluble in water but soluble in organic solvents only. Solubility of smaller ketones and aldehydes are result of the hydrogen bond formation between the lone pairs of oxygen atom and the hydrogen atom in the water molecule.
Want to see the full answer?
Check out a sample textbook solutionChapter 15 Solutions
General, Organic, And Biological Chemistry, Hybrid (with Owlv2 Quick Prep For General Chemistry Printed Access Card)
- The emission data in cps displayed in Table 1 is reported to two decimal places by the chemist. However, the instrument output is shown in Table 2. Table 2. Iron emission from ICP-AES Sample Blank Standard Emission, cps 579.503252562 9308340.13122 Unknown Sample 343.232365741 Did the chemist make the correct choice in how they choose to display the data up in Table 1? Choose the best explanation from the choices below. No. Since the instrument calculates 12 digits for all values, they should all be kept and not truncated. Doing so would eliminate significant information. No. Since the instrument calculates 5 decimal places for the standard, all of the values should be limited to the same number. The other decimal places are not significant for the blank and unknown sample. Yes. The way Saman made the standards was limited by the 250-mL volumetric flask. This glassware can report values to 2 decimal places, and this establishes our number of significant figures. Yes. Instrumental data…arrow_forwardSteps and explanation pleasearrow_forwardSteps and explanation to undertand concepts.arrow_forward
- Nonearrow_forward7. Draw a curved arrow mechanism for the following reaction. HO cat. HCI OH in dioxane with 4A molecular sievesarrow_forwardTry: Convert the given 3D perspective structure to Newman projection about C2 - C3 bond (C2 carbon in the front). Also, show Newman projection of other possible staggered conformers and circle the most stable conformation. Use the template shown. F H3C Br Harrow_forward
- Nonearrow_forward16. Consider the probability distribution p(x) = ax", 0 ≤ x ≤ 1 for a positive integer n. A. Derive an expression for the constant a, to normalize p(x). B. Compute the average (x) as a function of n. C. Compute σ2 = (x²) - (x)², the variance of x, as a function of n.arrow_forward451. Use the diffusion model from lecture that showed the likelihood of mixing occurring in a lattice model with eight lattice sites: Case Left Right A B C Permeable Barrier → and show that with 2V lattice sites on each side of the permeable barrier and a total of 2V white particles and 2V black particles, that perfect de-mixing (all one color on each side of the barrier) becomes increasingly unlikely as V increases.arrow_forward
- Chemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage LearningChemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningOrganic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning
- Organic And Biological ChemistryChemistryISBN:9781305081079Author:STOKER, H. Stephen (howard Stephen)Publisher:Cengage Learning,General, Organic, and Biological ChemistryChemistryISBN:9781285853918Author:H. Stephen StokerPublisher:Cengage LearningIntroductory Chemistry: An Active Learning Approa...ChemistryISBN:9781305079250Author:Mark S. Cracolice, Ed PetersPublisher:Cengage Learning