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Concept explainers
(a)
Interpretation:
Whether lactose is dextrorotatory or levorotatory compound should be determined.
Concept Introduction:
Chiral or optically active molecules can rotate plane-polarized light either clockwise or counter clockwise. If plane-polarized light is rotated clockwise then it is known as dextrorotatory and for counter clockwise rotation it is known as levorotatory.
(b)
Interpretation:
Specific rotation of the enantiomer of lactose should be determined.
Concept Introduction:
Enantiomers rotate the plane-polarized light in opposite directions by same angle.
(c)
Interpretation:
The amount of lactose enantiomer dissolved in water should be determined.
Concept Introduction:
Physical properties of enantiomers are similar except the direction of optical activity. Solubility, melting point, boiling points are similar.
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Chapter 15 Solutions
EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM
- Show reaction mechanism. don't give Ai generated solutionarrow_forward7. Draw the Lewis structures and molecular orbital diagrams for CO and NO. What are their bond orders? Are the molecular orbital diagrams similar to their Lewis structures? Explain. CO Lewis Structure NO Lewis Structure CO Bond Order NO Bond Order NO Molecular Orbital Diagram CO Molecular Orbital Diagramarrow_forward5. The existence of compounds of the noble gases was once a great surprise and stimulated a great deal of theoretical work. Label the molecular orbital diagram for XeF (include atom chemical symbol, atomic orbitals, and molecular orbitals) and deduce its ground state electron configuration. Is XeF likely to have a shorter bond length than XeF+? Bond Order XeF XeF+arrow_forward
- 6. Draw the molecular orbital diagram shown to determine which of the following is paramagnetic. B22+ B22+, B2, C22, B22 and N22+ Molecular Orbital Diagram B2 C22- B22- N22+ Which molecule is paramagnetic?arrow_forward3. Put the following species in order of increasing bond length by using molecular orbital diagrams and calculating their bond orders: F2, F2, F2+ Molecular Orbital Diagram F2 F2 F2+ Bond Order Shortest bond: Longest bondarrow_forward3. Put the following species in order of increasing bond length by using molecular orbital diagrams and calculating their bond orders: F2, F2, F2+ Molecular Orbital Diagram F2 F2 F2+ Bond Orderarrow_forward
- 4. The superoxide ion, Oz, plays an important role in the ageing processes that take place in organisms. Judge whether Oz is likely to have larger or smaller dissociation energy than 02. Molecular Orbital Diagram 02 02 Does O2 have larger or smaller dissociation energy?: Bond Orderarrow_forward1. How many molecular orbitals can be built from the valence shell orbitals in O2?arrow_forwardSho reaction mechanism. Don't give Ai generated solutionarrow_forward
- Introduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage Learning
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