(a) Interpretation: The given Fischer projection needs to be represented using wedges and dashed wedges. Concept introduction: For a molecule with chiral center, the Fischer projection formula is written to describe the stereo arrangement of atoms in two dimensions. For large molecules with more than 1 stereocenters are also represent their stereochemistry using the Fischer Projection. The carbon chain of the molecule containing the chiral carbon center is represented as vertical line with chiral carbon at the center. Two other groups are then horizontally arranged around the chiral carbon atom. The wedge and dashed bonds are used to represent the 3D structure of the molecule.

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Answer 1

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Chapter 15.6, Problem 15.16P

Interpretation Introduction

(a)

Interpretation:

The given Fischer projection needs to be represented using wedges and dashed wedges.

Concept introduction:

For a molecule with chiral center, the Fischer projection formula is written to describe the stereo arrangement of atoms in two dimensions. For large molecules with more than 1 stereocenters are also represent their stereochemistry using the Fischer Projection. The carbon chain of the molecule containing the chiral carbon center is represented as vertical line with chiral carbon at the center. Two other groups are then horizontally arranged around the chiral carbon atom.

The wedge and dashed bonds are used to represent the 3D structure of the molecule.

Interpretation Introduction

(b)

Interpretation:

The given Fischer projection needs to be represented using wedges and dashed wedges.

Concept introduction:

For a molecule with chiral center, the Fischer projection formula is written to describe the stereo arrangement of atoms in two dimensions. For large molecules with more than 1 stereocenters are also represent their stereochemistry using the Fischer Projection. The carbon chain of the molecule containing the chiral carbon center is represented as vertical line with chiral carbon at the center. Two other groups are then horizontally arranged around the chiral carbon atom.

The wedge and dashed bonds are used to represent the 3D structure of the molecule.

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3. Consider the compounds below and determine if they are aromatic, antiaromatic, or non-aromatic. In case of aromatic or anti-aromatic, please indicate number of I electrons in the respective systems. (Hint: 1. Not all lone pair electrons were explicitly drawn and you should be able to tell that the bonding electrons and lone pair electrons should reside in which hybridized atomic orbital 2. You should consider ring strain- flexibility and steric repulsion that facilitates adoption of aromaticity or avoidance of anti- aromaticity) H H N N: NH2 N Aromaticity (Circle) Aromatic Aromatic Aromatic Aromatic Aromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic aromatic TT electrons Me H Me Aromaticity (Circle) Aromatic Aromatic Aromatic Aromatic Aromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic aromatic πT electrons H HH…

A chemistry graduate student is studying the rate of this reaction: 2 HI (g) →H2(g) +12(g) She fills a reaction vessel with HI and measures its concentration as the reaction proceeds: time (minutes) [IH] 0 0.800M 1.0 0.301 M 2.0 0.185 M 3.0 0.134M 4.0 0.105 M Use this data to answer the following questions. Write the rate law for this reaction. rate = 0 Calculate the value of the rate constant k. k = Round your answer to 2 significant digits. Also be sure your answer has the correct unit symbol.

Answer 2

Question

Chapter 15.6, Problem 15.16P

Interpretation Introduction

(a)

Interpretation:

The given Fischer projection needs to be represented using wedges and dashed wedges.

Concept introduction:

For a molecule with chiral center, the Fischer projection formula is written to describe the stereo arrangement of atoms in two dimensions. For large molecules with more than 1 stereocenters are also represent their stereochemistry using the Fischer Projection. The carbon chain of the molecule containing the chiral carbon center is represented as vertical line with chiral carbon at the center. Two other groups are then horizontally arranged around the chiral carbon atom.

The wedge and dashed bonds are used to represent the 3D structure of the molecule.

Interpretation Introduction

(b)

Interpretation:

The given Fischer projection needs to be represented using wedges and dashed wedges.

Concept introduction:

For a molecule with chiral center, the Fischer projection formula is written to describe the stereo arrangement of atoms in two dimensions. For large molecules with more than 1 stereocenters are also represent their stereochemistry using the Fischer Projection. The carbon chain of the molecule containing the chiral carbon center is represented as vertical line with chiral carbon at the center. Two other groups are then horizontally arranged around the chiral carbon atom.

The wedge and dashed bonds are used to represent the 3D structure of the molecule.

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Answer 3

Question

Chapter 15.6, Problem 15.16P

Interpretation Introduction

(a)

Interpretation:

The given Fischer projection needs to be represented using wedges and dashed wedges.

Concept introduction:

For a molecule with chiral center, the Fischer projection formula is written to describe the stereo arrangement of atoms in two dimensions. For large molecules with more than 1 stereocenters are also represent their stereochemistry using the Fischer Projection. The carbon chain of the molecule containing the chiral carbon center is represented as vertical line with chiral carbon at the center. Two other groups are then horizontally arranged around the chiral carbon atom.

The wedge and dashed bonds are used to represent the 3D structure of the molecule.

Interpretation Introduction

(b)

Interpretation:

The given Fischer projection needs to be represented using wedges and dashed wedges.

Concept introduction:

For a molecule with chiral center, the Fischer projection formula is written to describe the stereo arrangement of atoms in two dimensions. For large molecules with more than 1 stereocenters are also represent their stereochemistry using the Fischer Projection. The carbon chain of the molecule containing the chiral carbon center is represented as vertical line with chiral carbon at the center. Two other groups are then horizontally arranged around the chiral carbon atom.

The wedge and dashed bonds are used to represent the 3D structure of the molecule.

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Answer 4

Question

Chapter 15.6, Problem 15.16P

Interpretation Introduction

(a)

Interpretation:

The given Fischer projection needs to be represented using wedges and dashed wedges.

Concept introduction:

For a molecule with chiral center, the Fischer projection formula is written to describe the stereo arrangement of atoms in two dimensions. For large molecules with more than 1 stereocenters are also represent their stereochemistry using the Fischer Projection. The carbon chain of the molecule containing the chiral carbon center is represented as vertical line with chiral carbon at the center. Two other groups are then horizontally arranged around the chiral carbon atom.

The wedge and dashed bonds are used to represent the 3D structure of the molecule.

Interpretation Introduction

(b)

Interpretation:

The given Fischer projection needs to be represented using wedges and dashed wedges.

Concept introduction:

For a molecule with chiral center, the Fischer projection formula is written to describe the stereo arrangement of atoms in two dimensions. For large molecules with more than 1 stereocenters are also represent their stereochemistry using the Fischer Projection. The carbon chain of the molecule containing the chiral carbon center is represented as vertical line with chiral carbon at the center. Two other groups are then horizontally arranged around the chiral carbon atom.

The wedge and dashed bonds are used to represent the 3D structure of the molecule.

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Answer 5

Chapter 15.6, Problem 15.16P

Interpretation Introduction

(a)

Interpretation:

The given Fischer projection needs to be represented using wedges and dashed wedges.

Concept introduction:

For a molecule with chiral center, the Fischer projection formula is written to describe the stereo arrangement of atoms in two dimensions. For large molecules with more than 1 stereocenters are also represent their stereochemistry using the Fischer Projection. The carbon chain of the molecule containing the chiral carbon center is represented as vertical line with chiral carbon at the center. Two other groups are then horizontally arranged around the chiral carbon atom.

The wedge and dashed bonds are used to represent the 3D structure of the molecule.

Interpretation Introduction

(b)

Interpretation:

The given Fischer projection needs to be represented using wedges and dashed wedges.

Concept introduction:

For a molecule with chiral center, the Fischer projection formula is written to describe the stereo arrangement of atoms in two dimensions. For large molecules with more than 1 stereocenters are also represent their stereochemistry using the Fischer Projection. The carbon chain of the molecule containing the chiral carbon center is represented as vertical line with chiral carbon at the center. Two other groups are then horizontally arranged around the chiral carbon atom.

The wedge and dashed bonds are used to represent the 3D structure of the molecule.

Answer 6

Chapter 15.6, Problem 15.16P

Interpretation Introduction

(a)

Interpretation:

The given Fischer projection needs to be represented using wedges and dashed wedges.

Concept introduction:

For a molecule with chiral center, the Fischer projection formula is written to describe the stereo arrangement of atoms in two dimensions. For large molecules with more than 1 stereocenters are also represent their stereochemistry using the Fischer Projection. The carbon chain of the molecule containing the chiral carbon center is represented as vertical line with chiral carbon at the center. Two other groups are then horizontally arranged around the chiral carbon atom.

The wedge and dashed bonds are used to represent the 3D structure of the molecule.

Answer 7

Chapter 15.6, Problem 15.16P

Interpretation Introduction

(a)

Interpretation:

The given Fischer projection needs to be represented using wedges and dashed wedges.

Concept introduction:

For a molecule with chiral center, the Fischer projection formula is written to describe the stereo arrangement of atoms in two dimensions. For large molecules with more than 1 stereocenters are also represent their stereochemistry using the Fischer Projection. The carbon chain of the molecule containing the chiral carbon center is represented as vertical line with chiral carbon at the center. Two other groups are then horizontally arranged around the chiral carbon atom.

The wedge and dashed bonds are used to represent the 3D structure of the molecule.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The given Fischer projection needs to be represented using wedges and dashed wedges.

Concept introduction:

For a molecule with chiral center, the Fischer projection formula is written to describe the stereo arrangement of atoms in two dimensions. For large molecules with more than 1 stereocenters are also represent their stereochemistry using the Fischer Projection. The carbon chain of the molecule containing the chiral carbon center is represented as vertical line with chiral carbon at the center. Two other groups are then horizontally arranged around the chiral carbon atom.

The wedge and dashed bonds are used to represent the 3D structure of the molecule.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The given Fischer projection needs to be represented using wedges and dashed wedges.

Concept introduction:

For a molecule with chiral center, the Fischer projection formula is written to describe the stereo arrangement of atoms in two dimensions. For large molecules with more than 1 stereocenters are also represent their stereochemistry using the Fischer Projection. The carbon chain of the molecule containing the chiral carbon center is represented as vertical line with chiral carbon at the center. Two other groups are then horizontally arranged around the chiral carbon atom.

The wedge and dashed bonds are used to represent the 3D structure of the molecule.

Answer 10

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Answer 12

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Answer 13

Ch. 15.1 - Prob. 15.1P Ch. 15.1 - For trans-2-hexene: (a) draw a stereoisomer; (b)...Ch. 15.2 - Prob. 15.3P Ch. 15.2 - Prob. 15.4P Ch. 15.3 - Prob. 15.5P Ch. 15.3 - Prob. 15.6P Ch. 15.3 - Prob. 15.7P Ch. 15.3 - Prob. 15.8P Ch. 15.3 - Prob. 15.9P Ch. 15.3 - Prob. 15.10P

Solution Summary: The author explains that the Fischer projection formula is written to describe the stereo arrangement of atoms in two dimensions.

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