General Chemistry
General Chemistry
4th Edition
ISBN: 9781891389603
Author: Donald A. McQuarrie, Peter A. Rock, Ethan B. Gallogly
Publisher: University Science Books
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Chapter 15, Problem 15.37P
Interpretation Introduction

Interpretation:

The unit cell length of silver has to be determined.

Concept Introduction:

A unit cell is smallest repeating unit of a crystal lattice. Unit cells are classified as primitive and non-primitive. Unit cells that have atoms at only corners are primitive and unit cells that have atoms at positions other than corners are non-primitive.

Unit cells that are non- primitive are of various types:

Face centered unit cell (fcc), body-centered unit cell (bcc), edge centered unit cell, end centered unit cell.

Contribution of an atom at a position is as follows:

  position in unitcellcontributionscenter of body1center of face1/2center of edge1/4corners1/8

The number of particles per unit cell, also denoted by Z is as follows:

UnitcellZscc1fcc4bcc2edge-centeredcubic4end-centeredcubic2

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