General Chemistry
General Chemistry
4th Edition
ISBN: 9781891389603
Author: Donald A. McQuarrie, Peter A. Rock, Ethan B. Gallogly
Publisher: University Science Books
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Chapter 15, Problem 15.13P
Interpretation Introduction

Interpretation:

Molecules among Cl2, F2, ClF and NF3 that have polar interactions have to be determined.

Concept Introduction:

Molecules of liquid and solid are held together by a force of attraction. The value of enthalpy of vaporization and sublimation reflects the magnitude of force between the molecules. Greater the value of ΔHvap or ΔHsub, greater will be the force of attraction between the molecules.

Molecules that have a dipole moment are polar in nature. Polarity or dipole moment is result of electronegativity differences among elements. Dipole moment is shown by an arrow with tail towards electropositive element and arrow head towards electronegative atom.

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