General Chemistry
General Chemistry
4th Edition
ISBN: 9781891389603
Author: Donald A. McQuarrie, Peter A. Rock, Ethan B. Gallogly
Publisher: University Science Books
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Chapter 15, Problem 15.32P

(a)

Interpretation Introduction

Interpretation:

The phase of carbon dioxide at 127°C and 8atm has to be determined.

Concept Introduction:

A plot of pressure against temperature that displays the stable range of a particular phase is known as phase diagram.

The phase diagram has three regions. Each region represents a particular stable phase like solid, liquid, or gas separated by boundary lines. Boundaries represent the equilibrium between two phases. The points of intersection at which the three boundary lines intersect is known as triple point. All three phases exist in equilibrium at triple point.

The vapor pressure at equilibrium for liquid increases as the temperature goes up to critical point where the abruptly vapor pressure curve terminates. The gas and the liquid phases become inseparable above critical temperature.

The phase diagram for CO2 differ from water in 2 ways that is the triple point of CO2 is different from water and also the melting curve of CO2 is up hill and towards slightly right in direction.

(b)

Interpretation Introduction

Interpretation:

The phase of carbon dioxide at 60°C and 40atm has to be determined.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The phase of carbon dioxide at 60°C and 40atm has to be determined.

Concept Introduction:

Refer to part (a).

(d)

Interpretation Introduction

Interpretation:

The phase of carbon dioxide at 60°C and 40atm has to be determined.

Concept Introduction:

Refer to part (a).

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