Study Guide with Student Solutions Manual for Seager/Slabaugh/Hansen's Chemistry for Today: General, Organic, and Biochemistry, 9th Edition
9th Edition
ISBN: 9781305968608
Author: Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher: Cengage Learning
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Textbook Question
Chapter 15, Problem 15.21E
Write an equation to illustrate the equilibrium that is present when propanoic acid is dissolved in water. What structure predominates when
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(c) The following data have been obtained for the hydrolysis of sucrose, C12H22O11, to
glucose, C6H12O6, and fructose C6H12O6, in acidic solution:
C12H22O11 + H2O → C6H12O6 + C6H12O6
[sucrose]/mol dm³
t/min
0
0.316
14
0.300
39
0.274
60
0.256
80
0.238
110
0.211
(i) Graphically prove the order of the reaction and determine the rate constant of the
reaction.
(ii) Determine the half-life, t½ for the hydrolysis of sucrose.
(III) adsorbent
(b) Adsorption of the hexacyanoferrate (III) ion, [Fe(CN)6] ³, on y-Al2O3 from aqueous
solution was examined. The adsorption was modelled using a modified Langmuir
isotherm, yielding the following values of Kat pH = 6.5:
(ii)
T/K
10-10 K
280
2.505
295
1.819
310
1.364
325
1.050
Determine the enthalpy of adsorption, AadsHⓇ.
If the reported value of entropy of adsorption, Aads Se = 146 J K-1 mol-1 under the above
conditions, determine Aads Gº.
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Chapter 15 Solutions
Study Guide with Student Solutions Manual for Seager/Slabaugh/Hansen's Chemistry for Today: General, Organic, and Biochemistry, 9th Edition
Ch. 15 - Prob. 15.1ECh. 15 - Prob. 15.2ECh. 15 - Prob. 15.3ECh. 15 - What carboxylic acid is present in sour milk and...Ch. 15 - Write the correct IUPAC name for each of the...Ch. 15 - Write the correct IUPAC name for each of the...Ch. 15 - Prob. 15.7ECh. 15 - Prob. 15.8ECh. 15 - Prob. 15.9ECh. 15 - Prob. 15.10E
Ch. 15 - Prob. 15.11ECh. 15 - Prob. 15.12ECh. 15 - Prob. 15.13ECh. 15 - Caproic acid, a six-carbon acid, has a solubility...Ch. 15 - Why are acetic acid, sodium acetate, and sodium...Ch. 15 - List the following compounds in order of...Ch. 15 - Prob. 15.17ECh. 15 - Prob. 15.18ECh. 15 - Prob. 15.19ECh. 15 - Prob. 15.20ECh. 15 - Write an equation to illustrate the equilibrium...Ch. 15 - Prob. 15.22ECh. 15 - Complete each of the following reactions: a. b.Ch. 15 - Prob. 15.24ECh. 15 - Write a balanced reaction for the reaction of...Ch. 15 - Prob. 15.26ECh. 15 - Give the IUPAC name for each of the following: a....Ch. 15 - Prob. 15.28ECh. 15 - Prob. 15.29ECh. 15 - Prob. 15.30ECh. 15 - Prob. 15.31ECh. 15 - Give the name of a carboxylic acid or carboxylate...Ch. 15 - Prob. 15.33ECh. 15 - Prob. 15.34ECh. 15 - Complete the following reactions: a. b. c.Ch. 15 - Prob. 15.36ECh. 15 - Using the alcohol CH3CH2OH, show three different...Ch. 15 - Prob. 15.38ECh. 15 - Prob. 15.39ECh. 15 - Prob. 15.40ECh. 15 - Prob. 15.41ECh. 15 - Prob. 15.42ECh. 15 - Prob. 15.43ECh. 15 - Prob. 15.44ECh. 15 - Give the IUPAC name for each of the following: a....Ch. 15 - Prob. 15.46ECh. 15 - Prob. 15.47ECh. 15 - Prob. 15.48ECh. 15 - Prob. 15.49ECh. 15 - Prob. 15.50ECh. 15 - Prob. 15.51ECh. 15 - Prob. 15.52ECh. 15 - Complete the following reactions: a. b.Ch. 15 - Prob. 15.54ECh. 15 - Prob. 15.55ECh. 15 - Dihydroxyacetone reacts with phosphoric acid to...Ch. 15 - Prob. 15.57ECh. 15 - Prob. 15.58ECh. 15 - Prob. 15.59ECh. 15 - Prob. 15.60ECh. 15 - How many mL of a 0.100M NaOH solution would be...Ch. 15 - Prob. 15.62ECh. 15 - Prob. 15.63ECh. 15 - Prob. 15.64ECh. 15 - Prob. 15.65ECh. 15 - Prob. 15.66ECh. 15 - Prob. 15.67ECh. 15 - Why is it safe for us to consume foods like...Ch. 15 - Prob. 15.69ECh. 15 - Prob. 15.70ECh. 15 - Prob. 15.71ECh. 15 - Prob. 15.72ECh. 15 - Identify the functional group designated by each...Ch. 15 - Prob. 15.74ECh. 15 - Fats belong to the class of organic compounds...
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