(a) Interpretation: The compound that possesses the higher boiling point is to be identified. Concept introduction: Boiling point is defined as the temperature at which a substance changes its liquid state to gaseous state. The boiling points of organic compounds depend on their structure. The boiling point of organic compounds is compared on the basis of dipole moment, hydrogen bonding, number of carbon atoms and branching.

Question

(c) The following data have been obtained for the hydrolysis of sucrose, C12H22O11, to glucose, C6H12O6, and fructose C6H12O6, in acidic solution: C12H22O11 + H2O → C6H12O6 + C6H12O6 [sucrose]/mol dm³ t/min 0 0.316 14 0.300 39 0.274 60 0.256 80 0.238 110 0.211 (i) Graphically prove the order of the reaction and determine the rate constant of the reaction. (ii) Determine the half-life, t½ for the hydrolysis of sucrose.

Answer 1

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 15, Problem 15.10E

Interpretation Introduction

(a)

Interpretation:

The compound that possesses the higher boiling point is to be identified.

Concept introduction:

Boiling point is defined as the temperature at which a substance changes its liquid state to gaseous state. The boiling points of organic compounds depend on their structure. The boiling point of organic compounds is compared on the basis of dipole moment, hydrogen bonding, number of carbon atoms and branching.

Interpretation Introduction

(b)

Interpretation:

The compound that possesses the higher boiling point is to be identified.

Concept introduction:

Boiling point is defined as the temperature at which a substance changes its liquid state to gaseous state. The boiling points of organic compounds depend on their structure. The boiling point of organic compounds is compared on the basis of dipole moment, hydrogen bonding, number of carbon atoms and branching.

Interpretation Introduction

(c)

Interpretation:

The compound that possesses the higher boiling point is to be identified.

Concept introduction:

Boiling point is defined as the temperature at which a substance changes its liquid state to gaseous state. The boiling points of organic compounds depend on their structure. The boiling point of organic compounds is compared on the basis of dipole moment, hydrogen bonding, number of carbon atoms and branching.

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(c) The following data have been obtained for the hydrolysis of sucrose, C12H22O11, to glucose, C6H12O6, and fructose C6H12O6, in acidic solution: C12H22O11 + H2O → C6H12O6 + C6H12O6 [sucrose]/mol dm³ t/min 0 0.316 14 0.300 39 0.274 60 0.256 80 0.238 110 0.211 (i) Graphically prove the order of the reaction and determine the rate constant of the reaction. (ii) Determine the half-life, t½ for the hydrolysis of sucrose.

(III) adsorbent (b) Adsorption of the hexacyanoferrate (III) ion, [Fe(CN)6] ³, on y-Al2O3 from aqueous solution was examined. The adsorption was modelled using a modified Langmuir isotherm, yielding the following values of Kat pH = 6.5: (ii) T/K 10-10 K 280 2.505 295 1.819 310 1.364 325 1.050 Determine the enthalpy of adsorption, AadsHⓇ. If the reported value of entropy of adsorption, Aads Se = 146 J K-1 mol-1 under the above conditions, determine Aads Gº.

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Answer 2

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 15, Problem 15.10E

Interpretation Introduction

(a)

Interpretation:

The compound that possesses the higher boiling point is to be identified.

Concept introduction:

Boiling point is defined as the temperature at which a substance changes its liquid state to gaseous state. The boiling points of organic compounds depend on their structure. The boiling point of organic compounds is compared on the basis of dipole moment, hydrogen bonding, number of carbon atoms and branching.

Interpretation Introduction

(b)

Interpretation:

The compound that possesses the higher boiling point is to be identified.

Concept introduction:

Boiling point is defined as the temperature at which a substance changes its liquid state to gaseous state. The boiling points of organic compounds depend on their structure. The boiling point of organic compounds is compared on the basis of dipole moment, hydrogen bonding, number of carbon atoms and branching.

Interpretation Introduction

(c)

Interpretation:

The compound that possesses the higher boiling point is to be identified.

Concept introduction:

Boiling point is defined as the temperature at which a substance changes its liquid state to gaseous state. The boiling points of organic compounds depend on their structure. The boiling point of organic compounds is compared on the basis of dipole moment, hydrogen bonding, number of carbon atoms and branching.

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Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 15, Problem 15.10E

Interpretation Introduction

(a)

Interpretation:

The compound that possesses the higher boiling point is to be identified.

Concept introduction:

Boiling point is defined as the temperature at which a substance changes its liquid state to gaseous state. The boiling points of organic compounds depend on their structure. The boiling point of organic compounds is compared on the basis of dipole moment, hydrogen bonding, number of carbon atoms and branching.

Interpretation Introduction

(b)

Interpretation:

The compound that possesses the higher boiling point is to be identified.

Concept introduction:

Boiling point is defined as the temperature at which a substance changes its liquid state to gaseous state. The boiling points of organic compounds depend on their structure. The boiling point of organic compounds is compared on the basis of dipole moment, hydrogen bonding, number of carbon atoms and branching.

Interpretation Introduction

(c)

Interpretation:

The compound that possesses the higher boiling point is to be identified.

Concept introduction:

Boiling point is defined as the temperature at which a substance changes its liquid state to gaseous state. The boiling points of organic compounds depend on their structure. The boiling point of organic compounds is compared on the basis of dipole moment, hydrogen bonding, number of carbon atoms and branching.

Expert Solution & Answer

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Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 15, Problem 15.10E

Interpretation Introduction

(a)

Interpretation:

The compound that possesses the higher boiling point is to be identified.

Concept introduction:

Boiling point is defined as the temperature at which a substance changes its liquid state to gaseous state. The boiling points of organic compounds depend on their structure. The boiling point of organic compounds is compared on the basis of dipole moment, hydrogen bonding, number of carbon atoms and branching.

Interpretation Introduction

(b)

Interpretation:

The compound that possesses the higher boiling point is to be identified.

Concept introduction:

Boiling point is defined as the temperature at which a substance changes its liquid state to gaseous state. The boiling points of organic compounds depend on their structure. The boiling point of organic compounds is compared on the basis of dipole moment, hydrogen bonding, number of carbon atoms and branching.

Interpretation Introduction

(c)

Interpretation:

The compound that possesses the higher boiling point is to be identified.

Concept introduction:

Boiling point is defined as the temperature at which a substance changes its liquid state to gaseous state. The boiling points of organic compounds depend on their structure. The boiling point of organic compounds is compared on the basis of dipole moment, hydrogen bonding, number of carbon atoms and branching.

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Answer 5

Chapter 15, Problem 15.10E

Interpretation Introduction

(a)

Interpretation:

The compound that possesses the higher boiling point is to be identified.

Concept introduction:

Boiling point is defined as the temperature at which a substance changes its liquid state to gaseous state. The boiling points of organic compounds depend on their structure. The boiling point of organic compounds is compared on the basis of dipole moment, hydrogen bonding, number of carbon atoms and branching.

Interpretation Introduction

(b)

Interpretation:

The compound that possesses the higher boiling point is to be identified.

Concept introduction:

Boiling point is defined as the temperature at which a substance changes its liquid state to gaseous state. The boiling points of organic compounds depend on their structure. The boiling point of organic compounds is compared on the basis of dipole moment, hydrogen bonding, number of carbon atoms and branching.

Interpretation Introduction

(c)

Interpretation:

The compound that possesses the higher boiling point is to be identified.

Concept introduction:

Boiling point is defined as the temperature at which a substance changes its liquid state to gaseous state. The boiling points of organic compounds depend on their structure. The boiling point of organic compounds is compared on the basis of dipole moment, hydrogen bonding, number of carbon atoms and branching.

Answer 6

Chapter 15, Problem 15.10E

Interpretation Introduction

(a)

Interpretation:

The compound that possesses the higher boiling point is to be identified.

Concept introduction:

Boiling point is defined as the temperature at which a substance changes its liquid state to gaseous state. The boiling points of organic compounds depend on their structure. The boiling point of organic compounds is compared on the basis of dipole moment, hydrogen bonding, number of carbon atoms and branching.

Answer 7

Chapter 15, Problem 15.10E

Interpretation Introduction

(a)

Interpretation:

The compound that possesses the higher boiling point is to be identified.

Concept introduction:

Boiling point is defined as the temperature at which a substance changes its liquid state to gaseous state. The boiling points of organic compounds depend on their structure. The boiling point of organic compounds is compared on the basis of dipole moment, hydrogen bonding, number of carbon atoms and branching.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The compound that possesses the higher boiling point is to be identified.

Concept introduction:

Boiling point is defined as the temperature at which a substance changes its liquid state to gaseous state. The boiling points of organic compounds depend on their structure. The boiling point of organic compounds is compared on the basis of dipole moment, hydrogen bonding, number of carbon atoms and branching.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The compound that possesses the higher boiling point is to be identified.

Concept introduction:

Boiling point is defined as the temperature at which a substance changes its liquid state to gaseous state. The boiling points of organic compounds depend on their structure. The boiling point of organic compounds is compared on the basis of dipole moment, hydrogen bonding, number of carbon atoms and branching.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The compound that possesses the higher boiling point is to be identified.

Concept introduction:

Boiling point is defined as the temperature at which a substance changes its liquid state to gaseous state. The boiling points of organic compounds depend on their structure. The boiling point of organic compounds is compared on the basis of dipole moment, hydrogen bonding, number of carbon atoms and branching.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The compound that possesses the higher boiling point is to be identified.

Concept introduction:

Boiling point is defined as the temperature at which a substance changes its liquid state to gaseous state. The boiling points of organic compounds depend on their structure. The boiling point of organic compounds is compared on the basis of dipole moment, hydrogen bonding, number of carbon atoms and branching.

Answer 12

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Answer 23

Ch. 15 - Prob. 15.1E Ch. 15 - Prob. 15.2E Ch. 15 - Prob. 15.3E Ch. 15 - What carboxylic acid is present in sour milk and...Ch. 15 - Write the correct IUPAC name for each of the...Ch. 15 - Write the correct IUPAC name for each of the...Ch. 15 - Prob. 15.7E Ch. 15 - Prob. 15.8E Ch. 15 - Prob. 15.9E Ch. 15 - Prob. 15.10E

Solution Summary: The author explains that acetic acid has higher boiling point than 1- propanol, and propanoic acid is higher than butanone.

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Chapter 15 Solutions