
Concept explainers
(a)
Interpretation:
The change in entropy in the given set of reactions has to be explained.
Concept Introduction:
Entropy is a
During a phase transition, if the solid state is changed to liquid state or gaseous state there will be an in increase in entropy in the system. The solid state is having more orderly arrangement than the liquid and gaseous state. Gaseous state, having more possible arrangements of atoms will have the highest order of entropy.
(b)
Interpretation:
The change in entropy in the given set of reactions has to be explained.
Concept Introduction:
Entropy is a thermodynamic quantity, which is the measure of randomness in a system. The term entropy is useful in explaining the spontaneity of a process. For all spontaneous process in an isolated system there will be an increase in entropy. Let us consider the example of diffusion of gas molecule to understand the concept of entropy. When a perfume bottle is opened the fragrance is immediately spread into the surroundings. Inside the bottle the gas molecules are close to each other and entropy is less. Once the bottle is opened the gas molecules escapes into the surroundings and have more disorderly arrangements.
During a phase transition, if the solid state is changed to liquid state or gaseous state there will be an in increase in entropy in the system. The solid state is having more orderly arrangement than the liquid and gaseous state. Gaseous state, having more possible arrangements of atoms will have the highest order of entropy.
(c)
Interpretation:
The change in entropy in the given set of reactions has to be explained.
Concept Introduction:
Entropy is a thermodynamic quantity, which is the measure of randomness in a system. The term entropy is useful in explaining the spontaneity of a process. For all spontaneous process in an isolated system there will be an increase in entropy. Let us consider the example of diffusion of gas molecule to understand the concept of entropy. When a perfume bottle is opened the fragrance is immediately spread into the surroundings. Inside the bottle the gas molecules are close to each other and entropy is less. Once the bottle is opened the gas molecules escapes into the surroundings and have more disorderly arrangements.
During a phase transition, if the solid state is changed to liquid state or gaseous state there will be an in increase in entropy in the system. The solid state is having more orderly arrangement than the liquid and gaseous state. Gaseous state, having more possible arrangements of atoms will have the highest order of entropy.
(d)
Interpretation:
The change in entropy in the given set of reactions has to be explained.
Concept Introduction:
Entropy is a thermodynamic quantity, which is the measure of randomness in a system. The term entropy is useful in explaining the spontaneity of a process. For all spontaneous process in an isolated system there will be an increase in entropy. Let us consider the example of diffusion of gas molecule to understand the concept of entropy. When a perfume bottle is opened the fragrance is immediately spread into the surroundings. Inside the bottle the gas molecules are close to each other and entropy is less. Once the bottle is opened the gas molecules escapes into the surroundings and have more disorderly arrangements.
During a phase transition, if the solid state is changed to liquid state or gaseous state there will be an in increase in entropy in the system. The solid state is having more orderly arrangement than the liquid and gaseous state. Gaseous state, having more possible arrangements of atoms will have the highest order of entropy.
(e)
Interpretation:
The change in entropy in the given set of reactions has to be explained.
Concept Introduction:
Entropy is a thermodynamic quantity, which is the measure of randomness in a system. The term entropy is useful in explaining the spontaneity of a process. For all spontaneous process in an isolated system there will be an increase in entropy. Let us consider the example of diffusion of gas molecule to understand the concept of entropy. When a perfume bottle is opened the fragrance is immediately spread into the surroundings. Inside the bottle the gas molecules are close to each other and entropy is less. Once the bottle is opened the gas molecules escapes into the surroundings and have more disorderly arrangements.
During a phase transition, if the solid state is changed to liquid state or gaseous state there will be an in increase in entropy in the system. The solid state is having more orderly arrangement than the liquid and gaseous state. Gaseous state, having more possible arrangements of atoms will have the highest order of entropy.

Want to see the full answer?
Check out a sample textbook solution
Chapter 14 Solutions
EBK CHEMISTRY: ATOMS FIRST
- can you please give the answer for both these pictures. thankyouarrow_forwardPart 1. Draw monomer units of the following products and draw their reaction mechanism (with arrow pushing) | Bakelite like polymer Using: Resorcinol + NaOH + Formalinarrow_forwardQuestion 19 0/2 pts 3 Details You have a mixture of sodium chloride (NaCl) and potassium chloride (KCl) dissolved in water and want to separate out the Cl- ions by precipitating them out using silver ions (Ag+). The chemical equation for the net ionic reaction of NaCl and KCl with silver nitrate, AgNO3, is shown below. Ag+(aq) + Cl(aq) → AgCl(s) The total mass of the NaCl/KCl mixture is 1.299 g. Adding 50.42 mL of 0.381 M solution precipitates out all of the Cl-. What are the masses of NaCl and KCl in the mixture? Atomic masses: g: Mass of NaCl g: Mass of KCL Ag = 107.868 g mol- 1 Cl = 35.453 g mol- 1 K = 39.098 g mol- N = 14.007 g mol−1 Na = 22.99 g mol−1 0 = 15.999 g mol 1 Question Help: ✓ Message instructor Submit Questionarrow_forward
- Part 1. Draw monomer units of the following products and draw their reaction mechanism (with arrow pushing) Polyester fiber Using a) pthalic anhydride + anhydrous sodium acetate + ethylene glycol B)pthalic anhydride + anhydrous sodium acetate + glycerolarrow_forwardIdentify the missing starting materials/ reagents/ products in the following reactions. Show the stereochemistry clearly in the structures, if any. If there is a major product, draw the structures of the major product with stereochemistry clearly indicated where applicable. Show only the diastereomers (you do not have to draw the pairs of enantiomers). If you believe that multiple products are formed in approximately equal amounts (hence neither is the major product), draw the structures of the products, and show the detailed mechanism of these reactions to justify the formation of the multiple products. If you believe no product is formed, explain why briefly. (6 mark for each, except f and g, which are 10 mark each)arrow_forward3. What starting material would you use to synthesize 3-hydroxypentanoic acid using a NaBH4 reduction?arrow_forward
- 1. Give stereochemical (Fischer projection) formulas for all (but no extras) the stereoisomers that could theoretically form during the reduction of a. the carbonyl group of 2-methyl-3--pentanone b. both carbonyl groups of 2,4-pentanedione (careful!) 2. Predict the products of the reduction of O=CCH2CH2CH2C=O with a. LiAlH4 b. NaBH4 CH3 OHarrow_forwardWhich of the following compounds can be synthesized using one reaction from any alkene, as a major product? If it can be synthesized, propose a route, and you may use any other starting materials, reagents and solvents as needed. If you do not think that it can be synthesized as a major product from an alkene, explain in detail why.arrow_forwardDraw the stepwise mechanism (with arrow pushing)arrow_forward
- a) Explain why product 1 is the kinetic product and product 2 is the thermodynamic product. b) Draw the reaction coordinate diagram for the reaction pathway generating each product. c) State the Arrhenius Equation and explain the terms with their physical significance. d) State and explain which reaction pathway has a higher rate constant. What happens to the rate constant if the temperature has increased?arrow_forwardI just need help with A,F,G,Harrow_forwardQUESTION 1 Write the IUPAC names for the following compounds. (a) (b) 2 H₂C CH (c) Br (d) HO (e) COOHarrow_forward
- Introductory Chemistry: A FoundationChemistryISBN:9781337399425Author:Steven S. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningWorld of ChemistryChemistryISBN:9780618562763Author:Steven S. ZumdahlPublisher:Houghton Mifflin College Div
- Introductory Chemistry: An Active Learning Approa...ChemistryISBN:9781305079250Author:Mark S. Cracolice, Ed PetersPublisher:Cengage LearningGeneral Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage Learning




